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Home My WebLink AboutPAR2014-00053 MSDS for BLD2014-00132 - PAR Letters / Memos - 9/29/2014 MATERIAL SAFETY DATA SHEET CryoPen,Inc. 2010 E.Continental Blvd • Suite D • Southlake TX • 76092 - (M7)246-35 r�1U'L D I N O SECTION 1:PRODUCT AND COMPANY IDENTIFICATION Product Name: EVERCLEAR(grain alcohol)/CryoPerO Reservoir Solution Manufacturer: David Sherman Corporation 5050 Kemper Avenue St.Louis,Missouri 63139 Information Phone Number: (314)772-2626 Fax: Emergency Phone Number(Chemtrec): (800)424-9300 North America (703)527-3887 International Shipments MSDS Date of Preparation: 12/31/02 Product Use:Beverage for Human Consum tion/C oPen®Reservoir Solution SECTION 2:COMPOSITIONANFORMATION ON INGREDIENTS Chemical Name CAS Number Vol % Ethanol(ethyl alcohol) 64-17-5 95 SECTION 3:HAZARDS IDENTIFICATION Clear liquid with a pleasant odor. EMERGENCY OVERVIEW WARNING!Flammable liquid and vapor.May cause eye,skin,and respiratory irritation. Ingestion or inhalation of vapors may cause inebriation,euphoria,dizziness,drowsiness,nausea,and other symptoms of central nervous system depression.Ingestion of large amounts may result in narcosis,anesthesia,coma,respiratory failure and death.Chronic overexposure may result in dependency and effects on the nervous system,heart,liver,gastrointestinal system and pancreas. SECTION 4: FIRST AID MEASURES Eye: Rinse thoroughly with water,holding the eye lids open to be sure the material is washed out. Get medical attention if irritation persists. Skin:Remove contaminated clothing. Wash contact area thoroughly with soap and water. Get medical attention if irritation or symptoms of exposure develop.Launder clothing before re-use. Inhalation: Remove victim to fresh air. Give artificial respiration if needed.If breathing is difficult,oxygen should be administered by qualified personnel. Get immediate medical attention. Ingestion: This product is intended for ingestion in moderation In cases of suspected poisoning or overdose,call a poison control center or hospital emergency department immediately and follow their instructions. Keep the victim calm and warm. SECTION 5: FIRE FIGHTING MEASURES DV Ir-ITT JL%-L-�CJCJJL VLb Flash Point: 13°C(550fl closed cup Flammable Limits: LEL: 3.3 vol% SEP 2 9 2014 Autoignition Temperature: 363°C(685 F) UEL: 19 vol% Extinguishing Media:Use water fog or spray,alcohol foam,carbon dioxide or dry chemical. 426 W. CEDAR ST. OM-CT2-02-R2 revised 03.23.11 Page 1 of 4 Special Fire Fighting Procedures: Wear NIOSH approved,positive pressure,self-contained breathing apparatus and full protective clothing.Cool fire exposed containers with water. Unusual Fire Hazards: Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back.Vapors may form explosive mixtures with air in confined areas. Hazardous Decomposition Products: Oxides of carbon SECTION 6:ACCIDENTAL RELEASE MEASURES Spill: Remove all ignition sources such as open flames,spark producing equipment,pilot lights,etc.Wear appropriate protective clothing to prevent eye and skin contact including impervious gloves,safety goggles and respirator if needed. Ventilate area. Cover with and inert absorbent material and collect into an appropriate container for disposal.Report spills and releases as required to appropriate authorities. SECTION 7:HANDLING AND STORAGE Handling: Avoid breathing vapors,aerosols and mists.Use with adequate ventilation. Avoid contact with the eyes. Avoid prolonged skin contact.Wear impervious gloves,chemical safety goggles and protective clothing when needed to minimize contact.Wash thoroughly after handling.Do not eat,drink or smoke in the work area.Keep product away from heat,sparks,flames and all other sources of ignition.No smoking in storage or use areas.Keep containers closed when not in use. Do not consume in excessive quantities.Not intended for consumption unless mixed with non-alcoholic beverages. Storage: Store in a cool,dry,well-ventilated location away from incompatible materials. Keep containers closed when not in use. SECTION 8:EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Name Exposure Limits Ethanol 1000 ppm OSHA PEL-TWA 1000 ppm ACGIH TLV-TWA Ventilation: Use with adequate general or local exhaust ventilation to maintain exposure levels below the occupational exposure limits.Use explosion proof electrical equipment and wiring where required. Respiratory Protection: If needed,a NIOSH approved respirator supplied air respirator may be used. Respirator selection and use should be based on contaminant type,form and concentration.Follow OSHA 1910.134,ANSI Z88.2 and good Industrial Hygiene practice. Skin Protection: Impervious gloves such as butyl or nitrile rubber are recommended when needed to avoid prolonged skin contact. Eye Protection: Chemical safety goggles recommended if eye contact is likely. Other Protective Equipment: Impervious clothing is recommended if needed to avoid prolonged skin contact and contamination of personal clothing. An eye wash facility and safety shower should be available in the work area. SECTION 9:PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor: Clear liquid with a pleasant odor. pH: Not available Specific Gravity: 0.789 Boiling Point: 78.5°C Melting Point: -114°C Vapor Pressure: 40 mmHg @ 19°C Water Solubility: Soluble Vapor Density: 1.59 Evaporation Rate: 3.3 (BuAc=1) OM-CT2-02-R2 revised 03.23.11 Page 2 of 4 Octanol/Water Partition Coefficient: -0.31 log Kow SECTION 10:STABILITY AND REACTIVITY Stability: Stable: X Unstable: Incompatibility/Conditions to Avoid: Strong oxidizing agents,ruthenium oxide,uranium hexafluoride,iodine heptafluoride,disulfuryl difluoride,acetyl chloride,mercuric nitrate,potassium dioxide,bromine peptafluoride,acetyl bromide,platinum and sodium.Keep away from heat,sparks,flames and other sources of ignition. Hazardous Decomposition Products: Combustion will produce oxides of carbon. Hazardous Polymerization: May Occur: Will not occur: X SECTION 11:TOXICOLOGICAL INFORMATION Potential Health Effects: Eye: May cause mild eye irritation. Corneal injury is unlikely. Skin: May cause irritation with prolonged or repeated exposure with dryness and scaliness. Inhalation: Inhalation of vapors,mists,or aerosols may cause nose and throat irritation and effects similar to those under ingestion. Ingestion: Swallowing causes dose related central nervous system depression with effects ranging from changes in mood,inebriation and euphoria to dizziness,drowsiness,nausea,vomiting and hypothermia. Ingestion of large amounts may result in narcosis,anesthesia,cardiac effects,electrolytic imbalance,acidosis,coma,respiratory failure and death Chronic Hazards: Chronic exposure may cause physical dependency,malnutrition,neurological effects(amnesia, dementia,somnolence),heart effects,liver damage,gastrointestinal bleeding and pancreatitis. Ingestion of ethanol during pregnancy may cause fetal alcohol syndrome in the child consisting of central nervous system dysfunction,slow growth and facial abnormalities. Carcinogen Status: None of the components of this product are specifically listed as carcinogens by OSHA,IARC or NTP,however,the consumption of alcoholic beverages is considered known to be carcinogenic to humans by NTP and IARC. Medical Conditions Aggravated by Exposure:Pre-existing liver disease.Ethanol potentiates the effects of numerous sedative and depressant drugs. Acute Toxicity Values: Ethanol:Oral rat LD50-7060 mg/kg Inhalation rat LC50-20,000 ppm/10 hr Skin rabbit LDLo-20 gm/kg SECTION 12:ECOLOGICAL INFORMATION Ethanol is expected to readily biodegrade in the aquatic environment.Bioconcentration is not expected. SECTION 13:DISPOSAL INFORMATION Dispose in accordance with all local,state and federal regulations. OM-CT2-02-R2 revised 03.23.11 Page 3 of 4 r— SECTION 14: TRANSPORT INFORMATION DOT Shipping Name: Ethanol DOT Hazard Class: 3,PG II UN Number:UN1170 DOT Labels Required(49CFR172.101): Flammable Liquid Hazardous Substance(49CFR172.101): None Reportable Quantity:N/A IATA Shipping Name:Ethanol IATA Hazard Class: 3,PG II UN Number:UN 1170 IATA Hazard Labels Required:Flammable Liquid SECTION 15:REGULATORY INFORMATION U.S.FEDERAL REGULATIONS: CERCLA 103 Reportable Quantity: Not applicable SARA TITLE III: Hazard Category for Section 311/312: Acute Health,Chronic Health,Fire Hazard Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances(TPQ): None EPA Toxic Substances Control Act(TSCA)Status: All of the components of this product are listed on the TSCA inventory. STATE REGULATIONS: California Proposition 65: Alcoholic beverages,when associated with alcohol abuse is listed as known to cause cancer. Ethyl alcohol in alcoholic beverages is listed as a developmental toxin INTERNATIONAL REGULATIONS: Canadian Environmental Protection Act: All of the components of this product are listed on the Canadian Domestic Substances List(DSL). European Inventory of Commercial Chemical Substances: All of the components of this product are listed on the EINECS inventory. European Community Labeling: RI 1 Highly Flammable S 16 Keep away from sources of ignition—NO SMOKING. S2 Keep out of reach of children. S7 Kee container tightly closed. SECTION 16:OTHER INFORMATION HMIS Ratings: Health-0 Flammability-3 Reactivity-0 NFPA Ratings: Health-0 Flammability-3 Reactivity-0 OM-CT2-02-R2 revised 03.23.11 Page 4 of 4 Spectrum Group Hazardous Material Identification Division of United Industries System-(HMIS) P. O.BOX 142642 HEALTH-1 REACTIVITY-0 St. Louis,MO 63114-0642 FLAMMABILITY-0 PERSONAL- Material Safety Data Sheet Complies with OSHA's Hazard Communication Standard,29 CFR 1910.1200 I Trade Name: Spectracide®Triazicide Once &Done! Insect Killer Spray for Lawn &Landscape Product Type: Ready-to-use insecticide .Product Item Number: 10525 Formula Code Number: 21-0712 Manufacturer Emergency Telephone Numbers EPA Registration Number 1-800-633-2873 i Cheulsico For Chemical Emergency: 1-800-917-5438 For Information: Division of United Industries Corporation Prepared by: C-A_Duckworth 9688-i95_8845 8494 Chapin Industrial Drive Date Prepared: November22, St.Louis,MO 63114 2005 II Hazards Ingredient/Identity Information III Physical and Chemical Characteristics OSHA PEL ACGIH TLV Appearance 8 Odor: Water-thin,translucent,water-white liquid with a Chemical slight odor. NE NE Boiling Point: 220°F Lambda-cyholothrin 0•�2 NA Melting Point: CAS#91465-08-6 I Ph 5.0-6.0 Specific Gravity: 1.0(H20=11 Vapor Density: Greater than 1 (Air=1) I %Volatile(by vol.): 95% Solubility in Water: >99% Evaporation Rate: Less than 1 (Butyl Acetate=1) IV Fire and Explosive Hazards Data V ReactivityData >200DF Stability: Stable Flash Point: Polymerization: Will not occur Flammable Limits: NA Autoignition Temperature: NA Conditions to Avoid: None Fire Extinguishing Media: Water fog,Carbon dioxide,Dry chemical IncoHazardous m ble Decn NA Decomposition Decomposition Temperature: NA NA special Fire-Fighting Procedures: Use.procedures for elimination of or Byproducts: orignal fire source. Unusual Fire&Explosion Hazards: None. Also see Section V. V7I Precautions for Safe Handling and Use VI Health-Hazard Data Skin Contact: Harmful if absorbed through skin. Avoid contact with skin, Steps to be Taken in Case Material is Released or Spilled: eyes-or clothing. Wash hands thoroughly with soap and water offer Avoid contact with liquid.Soak up-with absorbent material- handling and before eating,drinking,-chewing-gum or using tobacco. Waste Disposal: ntainer in trash or recycle if available. If partially empty Remove and wash contaminated clothing. Place empty co call 1-800-CLEANUP for disposal instructions. Never place unused product I First Aid: Takeoff contaminated clothing. Rinse skin immediately with down and indoor or outdoor drain. plenty of water for 15-20 minutes. Call a poison Control Center or doctor Handling E Storage Precautions: for treatment advice. Store in a cool,dry area away from heat-or open flame. Special.Notes: Have theproduct label with you when calling a Poison Control Center or doctor. Health conditions Aggravated by Exposure_ None known Ingredients listed by NTP,OSHA,or IARC as Carcinogens or3otential Carcinogens: None -V1II Control Measures IX Transportation Data Rand and follow labefdi<ections. They are your best eca9tions to protectuide to using ls 1MDGNNotot RRegullated by IIMDG(I megulated by DOT it duquolt tity exception) product effectively,and give necessary safety p IATA: Not Regulated by IATA(limited quantity exception) your health. are not to be construed as warranty or representation for which we The information and statements herein are believed to be reliable but assume legal responsibility. Users-should undertake sufficient verification and testing to determine the suitability for their own particular -purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. 12.ECOLOGICAL INFORMATION Ecotoxicity: Not available. BOD5_and COD: Not available. Pr,oducts-of-Biodegradation: Possibly hazardous-short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are more toxic. Special Remarks on the Products of Biodegradation: Not available. 13.DISPOSAL CONSIDERATIONS Whatever cannot be saved for recovery or recycling should be-managed in an appropriate and approved-waste disposal facility. Dispose of container and unused contents-in accordance--with federal, state and local requirements 14.TRANSPORT INFORMATION DOT Classification: Not a DOT controlled material(United States): ldentiffcation: Not applicable. -Special Provisions-forTransport: Not applicable. 15.REGULATORY INFORMATION Federal and State Regulations: TSCA 8(b)inventory: Clove oil, Rosemary oil Other Regulations: Not available.. Other Classifications: -:NHMIS(Canada): Not controlled under WHMIS(Canada). DSCIL(EEC): R36/38- Irritating to eyes and skin_ HMIS(U.S.A-): Heall:KHazard:2 Fire Hazard: 1 Reactivity:_0 Personal Protection: h National Fire Protection Association(U.S.A.): Health: 2 Flammability: 1 Reactivity:0 Specific hazard- Protective Equipment: -Gloves. Lab coat. Splash goggles. 16.O-THER INFORMATION MANUFACTURER DISCLAIMER:Information given herein is offered in good faith as accurate,but without guarantee.Canditions of use and suitability of the product for particular uses are-beyond our control;all risks of use of the product are therefore assumed by the user.Nothing is intended as a recommendation-for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers andusers. ---------------- 8.EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls: Provide exh aust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal tot e work-station location. Personal Protection: Splash goggles.Labs coat. Gloves. Personal Protection in Case of a Large Spill: aratus should Splash goggles. Full suit.Vapor respirator. Boots Veote protective clothing might not be sufficient; consult be used to avoid inhalation of the product. SuggestedP a specialist beforehandling this product. Exposure Limits. Not available. 9.PITYSICA111 AND CHEMICAL PROPERTIES Physical state and appearance: Liquid. Critical Temperature: Not available. Odor: Characteristic. Specific Gravity: 0.995(Water= 1) Taste: Characteristic. Vapor Pressure: Not available. Vapor Density: Not available. Molecular Weight: Not available. Volatility: Not available. Color:White to Transparent White. Odor Threshold: Not available. Bo(1% Point: Not a Not applicable. Water/Oil Dist.Coeff.: Not available. Boiling Point: Not available. Melting Point: Not available. lonicity(in Water): Not available. Dispersion Properties: See solubility in water, methanol. Solubility: Soluble in methanol. Solubility in cold water. io.ST-ABILITY AND REACTIVITY Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability:-Not available. Incompatibility with various substances: Not available. Corrosivity: Non-corrosive in presence of glass. Special Remarks on Reactivity: Not available. Special Remarks on Corrosivity: Not available. PolymerizatiomNo. 11.TOXICOLOGICAL INFORMATION Routes of Entry: Eye contact. Inhalation. Ingestion: Toxicity to Animals:Acute oral toxicity(LD50): 5000-mg/kg[Rat). Chronic Effects on Humans: Not available. Other Toxic Effects on-Humans: Hazardous_in case-of skin contact firritant), of ingestion,of inhalation. Special Remarks on-Toxicity to Animals: Not available. Special-Remarks on Chronic Effects on Humans: Not available. Special Remarks on other Toxic-Effects on Humans: Not available. 4.FIRST AID MEASURES NFPA Ratings: Health:2 Flammability: I Reactivity-0 EYES:Immediately flush eyes with plenty-of water-for several minutes,lifting lower and upper eyelids occasionally. Seek medical attention if irritation persists. C _ SKIN:Remove contaminated clothing including shoes-and_wash affected skin with soap and water.Seek medical attention if irritation develops and persists.Wash contaminated-clothing and shoes before reuse. INGESTION:Do NOT induce vomiting. Seek medical attention if ill effects occur. INHALATION:Remove from fiuther exposure.-Seek medical attention if ill effects occur. 5.FIRE FIGHTING MEASURES Flammability of the Product: May-be-combustible at high-temperature. Auto-ignition Temperature: Not available. Flash Points: Not available. Flammable Limits: Not available. Products of Combustion._Not available.- Fire Hazards in Presence of Various Substances: Not available. Explosion Hazards in Presence of Various-Substances: Risks of explosion of-the-product in presence of mechanical impact: Not available. Risks of explosion of the product in-presence of static discharge: Not available. Fire Fighting-Media and Instructions: SMALL FIRE:Use DRY chemical powder. LARGE FIRE: Use water spray,fog or foam. Do not use water jet. Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards:Not available. 6.ACCIDENTAL RELEASE MEASURES- Small Spill:Absorb with an inert material and-put the spilled-material in an appropriate waste disposal. Large-Spill: Absorb with an inert material and put the spilled material-in an appropriate waste disposal.Finish cleaning by spreading water on the contaminated surface and allow to-evacuate through-the sanitary system 7.-HANDLING AND STORAGE Precautions: Keep away from heat. Keep-away from sources-of ignition. Empty-containers pose-a fire risk,evaporate the residue under a fume hood:Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/vapor/spray.Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory-equipment If ingested, seek medical advice immediately and show the container or the label.Avoid contact with-skin and eyes Storage: Keep container dry. Keep in a cool place. Ground all equipment containing-material. Keep container tightly closed. Keep in-a cool-,well-ventilated place.Combustible materials should be stored away from extreme heat and away fromstrong oxidizing agents. MATERIAL SAFETY DATA SHEET Date issued:8/5/10 Date Revised: Revision No:1 Sierra Natural Science Inc 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION . -PRODUCT NAME:SNS-203 Concentrated Natural Pesticide GENERAL USE:Concentrated Natural Pesticide Soil Drench and Spray for use to control and repel Fungus Gnats, Root Aphids,Thrips,Shore Flies and White Flies PRODUCT FORMULATIONNAME:SNS-203 Concentrate CHEMICAL FAMILY:Botanical Extract-OIL GENERIC NAME:Compounded aqueous solution of Botanical extracts/oils with surfactant MANUFACTURER 1A HR.-EMERGENCY TELEPHONE Sierra Natural Science Inc. NUMBERS-For Chemical Emergency ONLY(spill, leak-fire,-exposure or accident),call CREMTREC at PO Box 2230 1=800-424-9300 Pollock Pines, CA . 95726 Non-Emergency Customer Service: 1-877-626-5505 COMMENTS:To the best of our knowledge,this Material Safety Data Sheet conforms to the requirements of US OSHA 29 CFR 1910.1200,91/155/EEC and Canadian Hazardous Products Act 2.COMPOSITION/INFORMATION ON INGREDIENTS Wt% CAS# Hazardous Cheuu— cal Name 1:50% 8000-34-8 No Clove Oil 0.53% 8000-25-7 No Rosemary Oil 6% 9007-48-1 No Polyglyceryl Oleate 0. No Laurie Acid 0.11% 143-07-7 Water Balance to: 11D0% 7732-18-5 No COMMENTS: Product composition ranges shown are typical values for health,safety and environmental use and are not intended as specifications. S.HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Potential Acute Health Effects: Hazardous in case of skin contact(irritant), of eye contact(irritant), of ingestion,of inhalation. Potential Chronic Health Effects: Hazardous in case of skin contact(irritant), of eye contact(irritant),of ingestion, of inhalation. CARCINOGENIC EFFECTS: Not available. MUTAGENiC EFFECTS:Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. c 4F-T-DATA Health Rating: 2—Moderate Flammability Rating: 1--Sliet- Reactivity Rating: 0—None Contact Rating: 1--Slight Lab Protective Equipment: Goggles:Protective Clothing;Vetrt-Hood;Proper Gloves li FoeTnvironmenta ION 12 - ECOLOGICAL INFORMATION p l hazard is anticipated provided that the material is handled and disposed of with due care and attention. i SECTION 13 - DISPOSAL CONSIDERATIONS Waste disposal: Rinse container and dispose in household garbage SECTION 14 - TRANSPORT INFORMATION N UN-No.: IMDG class: NR 11MO: NR Packaging group: i IATA: NR Packaging group: Correct technical name: Not-Restricted ADR/RID: N/R SECTION 15 - REGULATORY INFORMATION a ILabeling according to EEC directives: R-phrases: S-phrases: SECTION 16 - OTHER INFORMATiON Emergency telephone number I 604 533 9572 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO ACCURATE. HOWEVER,NO WARRANTY"IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. Rev, Date: 9/20/06 3 SECTION 6 -ACCIDENTAL RELEASE MEASURES In case of accidental spill or release: Wear appropriate protective clothing. If Iotal regulations permit,-mop up with-plentyter-anand aarangerun oremoval by a�sposaltly with running water. Otherwise transfer to container company. Wash site of spillage thoroughly-with detergent and water. r NDLING-AND STORAGE ling: Storage:ner no circumstances eat-or drink while Protect from iectStore at room perature sunl sunlight moisture C) handling this material. Wash hands and-face after working-with Keep container well closed material. Keep away from children SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION As appropriate to quantity handled: Protective gloves: Respiratory-protection: Rubber or plastic Not applicable Eye protection: —Goggles/face-shield SECTION 9 —PHYSICAL/CHElV11CAL PROPERTIES Water reactivity: Appearance and odor: -Non YellowSeed oil odor Boiling point: N/A > Solubility in water. Melting point: 120° C Miscible in any proportion rTION 10--STABILITY AND REACTIVITY bility:able SECTION 11 -TOXICOLOGICAL INFORMATION- In case of-ingestion: nts:nausea, vomitting, gastro-intestinal-distress,-abdominal After ingestion of large amo: discomfort may occur. Seek medical advice. - Further data: LD50 (oral rat): N/A _ No evidence-of carcinogenic ro erties. No evidence of muta enic or terato epic effects 2 Evo6utionary Extractions, Inc. Natural Product Carrier SM-90 Health & Safety Data Sheets SECTION 1 - IDENTIFICATION OF PREPARATION Product name: Item ID: SM-90 SMI-90 Application: Hydroponic Solutions :t- Evolutionary Extractions, Inc. iManufacturer Identification: ry 19292 50th Ave i Surre . BC V3S 8E5 Canada SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS !Chemical characterimation: Chemical composition: .i pH 9.2 Natural plant. oils a Solute in water SECTION 3 - HAZARD IDENTIFICATION N/A SECTION 4 - FIRST AID MEASURES Eye contact: Skin contact: Irrigate thoroughly with water. If discomfort Wash off throughly with water & soap persists, obtain medical attention. Ingestion: Inhalation: Wash out mouth thoroughly with water. N/A In severe cases obtain medical attention. IDo not induce vomiting SECTION 5 - FIRE FIGHTING MEASURES Special risks: Fire extinguisher: N/A N/A Special fire fighting precautions: C None - 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE: VENTILATION: Local mechanical exhaust ventilation at-the-point of use. RESPIRATORY PROTECTION: NIOSH-A-pproved dust and-vaporrespirator or mask in the absence of adequate environmental controls at the point of use. PROTECTIVE CLOTHING: Long-sleeved shirt,trousers,safety shoes-and gloves. EYE PROTECTION: Chemical goggles_ OTHER PROTECTIVE MEASURES: An eyewash and safety shower should�e nearby and ready for use. -3 - to Avoid: Water-of crystallization from applicable components driven-off- at approximately 235'Fahrenheit/ 113'-Celsius. Materials to Avoid: Solutions can be corrosive to metals. Avoid strong oxidizing and reducing agents. Hazardtius Decomposition Products: None. 5- ENVIRONMENTAL AND-DISPOSAL INFORMATION ACTION TO TAKE FOR SPILLS OR LEAKS: Wear protective equipment, including rubber boots,rubber gloves,rubber apron and chemical goggles. For small -spills,sweep up and dispose of in DOT-approved waste containers. Comply with all applicable-- regulations on spill reporting, and handling and disposal-of waste. 6. FELZST-AID: IF INHALED: Remove to fresh air. IN CASE OF EYE-CONTACT: Flush eyes with lots of running water. JN CASE OF SKIN CONTACT: Nash skin with-lots of soap and water. Remove contaminated clothing and shoes. Get medical attention if irritation persists. IF SWALLOWED: Do not induce vomiting. Consult a physician. 7.-IDEA-L--TH HAZARD INFOR-WATION: PRIMARY ROUTES OF EXPOSURE: Skin or eye contact, swallowed. SIGNS AND SYMPTOMS OF EXPOSURE: Eye-Contact: May moderately irritate eyes. Skin Contact: May irritate damp skin. - wallowe& Swallowing may result in abdominal discomfort. CHRONIC EFFEC-TS OF EXPOSURE: No specific information available_- MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None known. -2- NISDS SUES T S TM PRODUCT NAME: SILICA BLAST 1. INGREDIENTS: Major ingredients comprise silicates of sodium and potassium. 2. PHYSICAL DATA: Physical Form: Liquid;Ph 9-10 Bailing Point: 100DC Vap Press: N/A Vap-Density, N/A Sol-in Water: Very-soluble Evaporation Rate: N/A Appearance: Slightly-viscous liquid Odor. Odorless 3. FIRE AND-EXPLOSION HAZARD DATA: Flash Point: N/A Method Used: N/A FLAMMABLE LIMITS: LFL: N/A UFL N/A EXTINGUISHING MEDIA: This product is not combustible. Use any appropriate medium for extinguishing surrounding fires. 4. REACTIVffY DATA: STABILIT-Y-' Stable. POLYMEFdZATION: WilYnot occur. - 1 - SPECIAL PROTECTION INFORMATION/CONTROL MEASURES Local exhaust/ventilation: Normal Mechanical: n/a Respiratory protection: None requiredl. Protective gloves: Water resistanrrecommended Eye protection: Safety glasses-with side shields or chemical gogg�es Other protective clothing or equipment: Not required Work hygienic practices: Normal PHYSICAL HAZARDS(RFAC-TIMY DATA) Stability: Stable Incompatibility None Hazardous Decomposition Products: Oxides of Nitrogen and Sulfur Hazardous Polymerization: Will not occur HEALTEI HAZARDS -- Acute: Law toxicity Chronic: Low toxicity Signs and symptoms of exposure: May dry Gut sensitive skin after prolonged contact Medical conditions aggravated by exposure: None Chemical listed as carcinogen Or potential carcinogen: No National Toxicity Program: No LARC Monographs: No OSHA: No Emergency&First Aid procedures: No Routes of entry: Inhalation: None Eyes: Rinse-thoroughly with water for 30 minutes,consult physician Skin: Staining—wash with soap and water Ingestion: Consistent with-nitrate toxicity. Large amounts delay absorption of ingested nitrate by giving milk or activated charcoal and then remove by gastric Iavage or emesis(induce vomiting). Maintain blood pressure. Consult physician. SPECIAL PRECAUTIONS&SPILL/LEAK PROCEDURES Precautions for handling&storage: Keep container tightly sealed-will stratify at 32 deg F. May be thawed and remixed. -Other Precautions: Area of-spillmay become slippery. Steps for releasedor spilled: No special requirements known. Waste disposal-methods: Dispose of materiaa-1 in accordance with local,state and federal laws_and regulations. No special requirementw=known,- PURE BLEND TEA MATERUL SAFETY DATA SHEET EMERGENCY ASSISTANCE f= For emergency assistance involving PUREBLEND TEA,call Botanicare at 480-777- 2000,or 877-753-0404. For product and=sales information contact Butanicare at the same numbers. PRODUCT INFORMATION Product Name: PURE BLEND TEA with seaweed,blood-meal, seabird guano, earthworm castings, fishmeal, citric acid,and leonardite ore. PHYSICAL &CHEMICAL CHARACTERISTICS Physical Form: Liquid Y q Boiling Point,-degrees(F): >210 @a 1 amt Specific Gravity(H2O=1): 1.187 Weight per-gallon:- 9 pounds Vapor Pressure--(mm hg). 17mm @58 deg F Vapor Density .62 Solubility in-Water: 95% Percent Volatile(%): n/a Evaporation Rate: .08 Appearance&Odor:- Medium brown liquid Pungent odor Melting Point: None FIRE&E3MLOSION DATA Flash Pit: None Method: 4xrm closed carp Auto Ignition-Temp: lone Special Fire Procedures: Self-contained-air to protect from oxides of Nitrogen and.Sulfur Extinguisher-Media: None,product-decomposes-w/o-flame Unusual Fire Explosion Hazards: None r 8. I NCI ING PRECAUTIONS: EXPOSURE GUIDELINE: VENTILATION:- Local mechanical-exhaust zntilatiQn at the point of use. -RESPIRATORY PROTECTION:-N-10SH-Approved dust and vapor respirator or mask in the absence of adequate environmental controls at the point of use. PROTECTIVE CLOTHING: Long-sleeved shirt,trousers,safety-shoes and gloves. EYE PROTECTION: Chemical goggles. OTHER PROTECT E-MEEASURES: An eyewash and safety shower should be nearby and ready for-use. -3 - Conditions to-Avoid: Water of crystallization from applicable components driven off at approximately 235'Fahrenheit/ 113°-Celsius. Materials to Avoid: Solutions can be corrosive to metals. Avoid strong oxidizing and reducing agents. Hazardous Decomposition Products: None. 5. -ENVIRONMENTAL.AND DISPOSAL.INFORMATION: ACTION-TO TAKE FOR SPILLS OR LEAKS: Wear protective equipment, including-rubber boots,rubber gloves,-rubber apron and-chemical geggless. For small spills,sweep up and dispose of in DOT-approved waste containers. Comply with all applicable governmental regulations on spill reporting,and handling and disposal of waste. 6. FIRST AID: IF INHALED: Remove to fresh air. IN CASE OF EYE CONTACT: Flush eyes with lots of running water. IN CASE OF-SKIN Cf7NTACT: Wash skin with lot's of soap and water. Remove contaminated clothing and shoes. Get medical-attention if irritation persists. IF SWALLOWED--_ Do not induce vomiting. Consult-a physician. 7. HEALTH HAZARI)INFORMATION-- PRIMARY ROUTES OF EXPOSURE: Skin or eye contact,swallowed. SIGNS AND SYMPTOMS OF EXPOSURE: Eye Contact: May moderately irritate eyes. Skin Contact: May irritate damp skin. Swallowed: Swallowing may result in abdominal discomfort. CHRONIC EFFECTS OF EXPOSURE: No specific-information-available. MEDICAL CONDITIONS AGGR-AYATED BY EXPOSURE: None known. -2- Botanicare 6858 W. Chicago St #3 Chandler, AZ 85226 MSDS SHEETS 877.753.0404 TM PRODUCT NAME: PURE BLEND PRO GROW PRO SOIL &PRO BLOOM 1. INGREDIENTS: Dolomite,potassium carbonate, fish meal, seaweed extract, magnesium sulfate,humic acid. 2. PHYSICAL DATA: Physical Form: Liquid Boiling Point: 100°C Vap Press: N/A Vap Density: N/A Sol in Water: Appreciable Evaporation Rate: N/A Appearance: Dark, coffee-colored liquid Odor: Slight organic odor 3. FIRE AND EXPLOSION I3AZARD DATA: Flash Point: N/A Method Used: N/A FLAMMABLE LIMITS: LFL: N/A UFL: N/A EXTINGUISHING MEDIA: This product is not combustible. Use any-appropriatte medium for extinguishing surrounding fires. 4. REACTIVITY DATA: STABILITY: Stable. POLYMERIZATION: Will notoccur. - 1 - ADR(Europe): TDG(Canada): DSCL(Europe): 1. OTHER FNFORMATiON Currentissue Date: November 3(,2005 Previous-Issue-Date: N/A Prepared-by: Sherry Brock (920)623-2140- Disclaimer;Columbus-Chemical Industries,Inc—{"Columbus")believes that the information herein is-factual but is not intended to-be all tclusive.The information-relates only to the-specific-material designated and does not relate-to its use in combination with other materials or its use as to any particular process.Because-safety standards and regulations are subject to change and becauseColumbus has no continuing control over the-material,those-handling,storing or using the material should satisfy themselves that they have current information regarding-the-particular way the material is-handled,stored or used and that the-same is done in accordance withJederal, state and-local law.COLUMBUS-MAKES-NO WARRANTY,EXPRESS OR IMPLIED,INCLUDING-(%AITHOUT LIMITATION) WARRANTIES WITH RESPECT-TO THE COMPLETENESS OR CONTINUING-ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT-TO FITNESS-FOR-ANY PARTICULAR USE. Created on 1 I/30/2005 4:22:00 PM Page 7 of 7 Federal and State-Regulations: Illinois toxic substances disclosure to employee act: Phosphoric acid Illinois chemical safety act: Phosphoric acid New York release reporting list: Phosphoric acid Rhode Island RTK-hazardous substances:Phosphoric acid Pennsylvania RTK: Phosphoric acid Minnesota: Phosphoric acid- Massachusetts RTK: Phosphoric acid Massachusetts spill list: Phosphoric-acid New Jersey: Phosphoric acid- New Jersey spill list: Phosphoric acid Louisiana spill-reporting:Phosphoric acid California Director's list of hazardous substances: Phosphoric acid SARA 302/304/311/312 extremely hazardous substances: Phosphoric Acid SARA 313-toxic chemical notification and release reporting: Phosphoric Acid CERCLA: Hazardous Substances: Phosphoric Acid, 5000lbs. California Proposition 65: No wHMIS Canada: Class E-corrosive liquid, DSCL(EEC): R34—Causes burns. RMIS(U.S.A.) Feactivityt 0 National Fire Protection Association(U.S.A.) Flammability Health eactivity Y4 Specific hazard Protective Equipment: 0 () Created on 11/30/2005 4:22:00-PM Page 6 of 7 12. ECOLOGICAL INFORMATION Ecotoxicity(aquatic and terrestrial): DL50 12 hours@ pH of 3—3-5 DL50(12 hours):-pH 4.6(Daphnia Magna) Persistence and Degradability: Not Available Bioaccumulative Potential: Not Available Mobility in Soil: Not Available Other Adverse Effects: Not Available 13. DISPOSAL CONSIDERATIONS RCRA: Haz ardous waste?Yes RCRA ID number: D002 Waste Residues: Carefully dilute with water, neutralize-per spill procedures in section 6. Neutralized material may be flushed to sewer(REGULATIONS PERMITTING!)or disposed of through a licensed contractor. Users should review their operations in terms of the applicable federaltnation or local regulations and consult with appropriate regulatory-agencies before discharging or disposing of waste material. Product containers: Containers, if thoroughly cleaned, preferably by rinsing-three times-and-handling the rinse water as waste residues, may be disposed of or recycled as-non-hazardous waste. Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies before discharging or disposing of waste material. The information offered in section 13 is for the product as shipped.Use and/or alterations to the product rnay significantly change the characteristics of the material and alter the-waste-classification and proper disposal methods. 14. TRANSPORTATION INFORMATION DOT: UN1-805, Phosphoric Acid solution,8, pg III TDG: UN1805, Phosphoric Acid liquid, 8, pg III PIN: Not Available IDMG: UN1805, 8, pg III Marine Pollutant: No IATA/ICAO: UN1805, 8, pg III RID/ADR: Class 8,-item 17(c), corrosive,-UN1805 15. REGULATORY INFORMATION i TSCA Inventory Status:All ingredients are listed on the TSCA inventory. Created on 11/30/2005 4:22:00 PM Page 5 of 7 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, colorless,viscous liquid Physical state: Liquid Acidic Odor Odor Threshold: Not Available Specific Gravity: 1.6900 pf' 1 Melting Point/Freezing Point: 42°C (108°F) Boiling Point/Range: 213°C(415°F) Flammability: Not Flammable(See section 5) Flash point: Not Flammable(See section 5) Evaporation Rate(Butyl Acetate=1): Not Available Explosive Limits: Not Explosive(See section 5) Vapor Pressure{at 20°C): 0:03 mmHg- Vapor Density(air=1): 3.4 Solubility: Completely soluble in water Partition coefficient/n-octanol/water: Not Available %Volatile: -Not Available Autoignition Temperature: See section 5 10. STABILITY AND REACTIVITY -Stability: Stable Conditions to avoid: Incompatible materials. Incompatibility: Bases, combustible material, metals. Hazardous decomposition products: -Phosphorus oxides. Hazardous-polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Acute Effects: See section 4 for symptoms of exposure and effects. Likely routes of exposure are skin,eyes and-inhalation. Target organs: Blood,liver, skin, eyes and bone marrow. Acute Toxicity Data: Phosphoric acid LD50[oral, rat], 1530 mg/kg LC50[rabbit]; 1.689 mg/L(1 hour) LD50 Dermal(rabbit); 2740 mg/kg- Chronic Effects:May affect liver, conjunctivitis, dermatitis, pulmonary edema. Teratogenicity: Negative ,Mutagenicity: Negative Embryotoxicity: Negative Synergistic Products/Effects: Not Available Created on 11/30/2005 4:22:00 PM Page-^ of 7 container for disposal. Clean surfaces thoroughly with water to remove residual contamination. Any release to the environment may be subject to federal/national or local reporting requirements. Dispose of all waste or cleanup materials in accordance with local regulations. Containers, even when empty, will retain residue and vapors. 7. HANDLING AND STORAGE Normal handling: See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Storage: Store in cool,dry well ventilated area. Keep away from incompatible materials(see section 10 for incompatibilities). Drains for storage or use areas for this material should have retention basins for pH adjustment and dilution of spills. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure controls: (consult local authorities for acceptable exposure limits) Chemical name Regulatory List Value and type Phosphoric Acid UK OES 1 mg/m3 STEL 3 mg/m3(10 minutes) USA OSHA PEL 1 mg/m3 STEL 3 mg/m3(15 minutes) USA ACGIH TLV 1 mg/m3 STEL 3 mg/m3(15 minutes) USA OSHA_PEL 1 mg/m3 STEL 3 mg/m3(15 minutes) USA NIOSH REL 1 mg/m' STEL 3 mg/m3(15 minutes) Mexico PEL 1 mg/m3 STEL 3 mg/m3(15 minutes) OSHA IDLH 1000 my/m3 France VME 1 mg/m France VLE (STEL) 3 mg/m3(15 minutes) TWA:Time Weighted-Average over 8 hours of work. TLV:Threshold limit Value over 8 hours of work. REL Recommended Exposure Limit STEL: Short Term Exposure Limit during x minutes. IDLH: Immediately-Dangerous to Life or Health Ventilation._ Provide local exhaust, preferably mechanical. Respiratory protection: If necessary use an approved respirator with acid vapor cartridges. Eye protection: Wear chemical-safety-glasses with-a face shield for splash-protection. Mein and body protection. Wear neoprene or rubber gloves,apron and other protective clothing appropriate to the risk of exposure. Other-Recommendations: Provide eyewash stations,quick-drench showers and washing facilities accessible to areas of-use and handling. Have supplies and equipment for neutralization and running water available. Created on-11/30/2005 4:22:00 PM Page 3 of 7 Q Material Safety- Data Sheet [Ph--Co)sphoric Acia� 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Phosphoric Acid Synonyms/Generic Names: Orthophosphoric Acid. Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Columbus, WI. 53925 For More Information Call: 920-623-2140 IN CASE OF EMERGENCY CALL: CHEMTREC (Monday—Friday 8:004:.30) (24 Hours/Day, 7-Days/Week) 800-424-9300 2. COMPOSITION/INFORMA T ION ON INGREDIENTS EINECS#/ Classification* Weight% Component CAS# -ELINCS# 85% Phosphoric Acid 7664-38-2 231-633-2 C; R34, x" *Symbol and R phrase according to-EC Annex1 **Subject to-the reporting requirements o -SARA-Title Ill Section 313 3. HAZARDS-IDENTIFICATION Clear, colorless solution with caustic odor. R34—Causes burns. S1/2, S26, S45 Routes of Entry: Skin,eyes, inhalation and ingestion.: e 1 of 7 Pa Created on 11/30/2005 4:22:00 PM g ingredients found on carcinogen lists: INGREDIENT NAME NTP STATUS IARC STATUS OSHA LIST ACGIH Phosphoric Acid Not Listed Not Listed Not Listed Not Listed 4. FIRST AID INFORMATION Inhalation: Inhalation of mists can cause corrosive action on-mucous membranes. Symptoms include burning, choking, coughing, wheezing, laryngitis, shortness of breath, headache or nausea. Move casualty tuo fresh air and-keep at rest. Get medical attention if symptoms persist. Eyes: Symptoms include eye burns,watering eyes.-Rinse with plenty of water for a minimum of 15 minutes and seek medical attention_immediafely. Skin: Symptoms include burning,itching, redness, inflammation and/or swelling of exposed tissues. immediately flush with plenty of water for at least 15 minutes-while removing contaminated clothing and wash using soap. Get medical attention if necessary. Ingestion: Do Not Induce Vomiting! Causes corrosive burns of the mouth, gullet and gastrointestinal tract if swallowed. Symptoms include burning, choking, nausea, vomiting and severe pain.Wash out mouth with water and give a glass of water or milk. Get medical attention immediately. 5. FIRE-FIGHTING--MEASURES FLAMMABLE PROPERTIES: Flash Point: Not Flammable Flash Point method: Not Applicable Autoignition Temperature: Not-Applicable Upper Fiame Limit(volume %in air): Not Applicable Lower Flame Limit(volume in air): Not Applicable Extinguishing Media: Product is not flammable. Use appropriate media for adjacent fire. Cool containers with water,keep away from common metals. Special fire fighting procedures: Wear self-contained;approved breathing apparatus and full protective clothing, including eye protection and boots. -Hazardous combustion products: Emits toxic fumes under fire conditions.-(See-also Stability and Reactivity section). Unusual fire and explosion hazards: Material can react with metals to produce flammable hydrogen gas. Forms flammable gases with-aldehydes, cyanides mercaptins, and sulfides. 6. ACCIDENTAL-RELEASE MEASURES Personal precautions: See section 8 for recommendations on the use of personal protective equipment. Environmental precautions: Cleanup personnel need personal protection from inhalation and skin/eye contact Evacuate-and ventilate the area. Prevent spillage from entering drains. Cautiously add water to spi!!,taking care to-avoid-splashing-and spattering. Neutralize diluted spill with soda ash or lime. Absorb .neutralized spill with vermiculite or other inert absorbent material, then place in a suitable Created on 11/30/2005 4:22:00 PM Page 2 of 7 MSDS Ref.No.: 043206027-1 ORTHOO Season-Long MAX Weed&Grass Killer Plus Preventer Concentrate 16. OTHER INFORMATION NFPA: Health: 2 Flammability: 1 Reactivity: 0 HMIS: Health: 2 Flammability: 1 Reactivity:0 Hazard Rating:O=Least;1-Slight;2=Moderate;3=High;4=Severe EPA FIFRA Comment: Use of this product is regulated by the U.S.Environmental Protection Agency(EPA)through the approved product label.It is_a violation of Federal law to use this product in a manner inconsistent with its labeling. General comment: This document contains health,safety,and environmental information useful to emergency response-agencies,health care providers,manufacturers,and workers/employees.It does not replace the precautionary language,use directions,or the storage and disposal information found on the product label. Additional Information:This information contained herein is,to the best of Scott's knowledge and belief,accurate and reliable as of the date of preparation of this document.However,no warranty or guarantee,express or implied,is made as to the accuracy or reliability,and Scotts shall not be_ liable for any loss or damage arising out of the use thereof.No authorization is given or implied to use any patented invention without a license.In addition,Scotts shall not be liable for any damage or injury resulting from abnormal use,from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. Page 4 of 4 Revision date: ORTHOO Season-Long MAX Weed&Grass Killer Plus Preventer MSDS Ref.No.: 043206027-1 Concentrate 11.TOXICOLOGICAL INFORMATION Acute toxicit.- LD50/oral:>5.0 9/kg,rat LDSUldermal_>5.0 g/kg,rabbit LC50/inhalation:>2.7 mg/L, (vapor),rat Eye effects:Mild-eye irritation,rabbit Skin effects:Moderate skin irritation,rabbit Sensitization:No sensitization,guinea pig Chronic toxicity Carcinogenic effects:The.table below indicates whether each agency has listed any indgredient as a carcinogen. Components NTP: IARC_ OSHA: Oxynuorfen Not listed -Not listed Not listed Di uat dibromide I Not listed Not listed- Not listed Glyphosate Not listed Not listed- Not listed Other Ingredients Not listed Not listed Not listed Ingestion: Ingestion may cause irritation to mucous membranes. Inhalation: May cause irritation of respiratory tract. Target organ effects: irritation. i2. ECOLOGICAL INFORMATION 1 Ecotoxicity effects: No data is available on the product itself. Persistence and-degradability: Inherently biodegradable. Bioaccumulative potential: Not determined. Mobility: Water contaminating. Aquatic toxicity_ Toxic.#o aquatic invertebrates. Additional ecological information: Do not-apply to water.Do not contaminate water by cleaning of equipment or disposal of wastes. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: If partially filled,call the local solid wasteagency or 1-800-CLEANUP for disposal instructions.Do not -place product down any indoor or outdoor drain: Contaminated packaging: Do not re-use empty containers.If empty,place in trash or offer for recycling if available. 14. TRANSPORT INFORMATION- The description shown may not apply to all situations.Consult 49 CFR,or appropriate dangerous goods regulations for additional description requirements(e.g.technical name)and mode-spec or quantity-specific shipping requirements. DOT Proper shipping name:- Not DOT regulated 1S.REGULATORY INFORMATION -Components CAS-No CERCLA/SARA-313 CERCLA/SARA 302 Dxynuorfen 42874-03-3 Not Listed Not Listed iquat dibromide- - 85-00-7 1000 lb final RQ Not Listed 454 kg final RQ_ Slyphosate 1071-83-6 -Not Listed Not Listed ther Ingredients - No CAS# Not Listed Not Listed General Information- Contact local authorities for disposal of large quantities of product 16.OTHER INFORMATION Revision date: Page 3 of 4 MSDS Ref.No.: 043206027-1 ORTHOO-Season.-Long MAX Weed&GrassXiller Plus-Preventer Concentrate- FIRE FIGHTING MEASURES Flammable properties: Non-flammable. Suitable extinguishing media: Water spray,carbon dioxide,dry chemical,chemical foam. .Explosion potential: Unlikely. Hazardous combustion products: Toxic-fumes may be produced. Fire fighting procedures: Select appropriate method to surround and extinguish fire.Flood with water to coal containers. Special protective equipment for As in any fire,wear self-contained breathing apparatus pressure-demand,MSHA/NIOSH(approved or firefighters: equivalent)and full protective gear. ACCIDENTAL- RELEASE MEASURES Personal precautions: Wear personal protective equipment Environmental precautions: Prevent product from entering drains Methods for containment: Control spill with-dykes and-absorb with inert absorbant material Methods for cleaning up: Detergent and water. . HANDLING-AND STORAGE Handling:Avoid container breakage.Avoid inhalation or contact with skin,eyes,or clothing. Storage:Store in original container in a safe place.Avoid contamination of feed and foodstuffs.Do not put concentrate or dilute into food or drink containers.Protect from freezing. EXPOSURE CONTROLS J PERSONAL PROTECTION Com onents ACGIH: OSHA: uorfen Not Listed Not Listed iquat rfendibr ide 0.1 mg/m3 TWA Not Listed 0.5 m /m3 TWA I hosate Not Listed Not Listed ther Ingredients Not Listed Not Listed Engineering controls Use adequate ventilation to keepthe airborne concentrations of this material below the recommended exposure standard Personal Protective Equipment Eyelface protection: Eye/face protection is not required,but is recommended in manufacturing situations where contact may occur. Skin and body protection: Wear suitable-protective clothing if contact is anticipated during manufacturing. Respiratory protection: If airborne levels are high or product does not remain intact,use a combination of engineering controls (e.g.ventilation)and personal protection,e.g.,NIOSH/MSHA approved respirator for dusts,mists,and fumes. General hyglene considerations: Wash hands before breaks and immediately after handling the product.When using,do not eat,drink or smoke. PHYSICAL AND CHEMICAL-PROPERTIES Physical State: Liquid Color: Yellow Odor: Woody pH: 4.0-5.0 Solubility: Miscible Specific gravity: 1.045 Flash point: >210"F Method: ASTM D-93,D-56 10.STABILITY AND REACTIVITY Chemically Stable: Yes Conditions to avoid: Extreme heat.Do not freeze. Materials to avoid-- Strong-acids and oxidising agents. Hazardous-decomposition products: Toxicfumes and gases may be generated. Possibility of hazardous-reactions: Poses.litfieor no immediate hazard. 11.TOXICOLOGICAL INFORMATION Page 2 of 4 Revision date: MA TERIAL SAFETY DA TA- SHEET Date stamp: 26 May-2006 MSDS Ref.No.: 043206027-1 Revision Number: 0 1. PRODUCT AND COMPANY IDENTIFICATION Product name: ORTHOO Season-Long MAX Weed&Grass Killer Plus Preventer Concentrate Description: Herbicide Company 24-HOUR EMERGENCY TELEPHONE-NUMBERS: The Scotts Company,L.L.C. CHEMTREC(U.S.): 800-424-9300 14111 Scottslawn Road CHEMTREG(international):1-703-527-3887 Marysville,OH 43041 Non-Emergency Calls 1-937-644-0011 EPA Registration No.:239-2694 Formula No.:S11758 HAZARDS IDENTIFICATION Labelling Signal word: CAUTION Precautionary Statement Avoid contact with eyes,skin,and clothing.Causes moderate eye irritation.Wash with soap and water after handling.Keep out of reach of children. Potential health effects Eye contact: Irritating to eyes. Skin contact: irritating to skin. Ingestion: Harmful if swallowed.Ingestion may-cause gastrointestinal-irritation,nausea,-vomiting and diarrhoea. Inhalation: Inhalation of aerosols may cause irritation to mucous-membranes. Aggravated Medical Conditions: Inhalation may aggravate asthma.Pre-existing-dermatitis or sores. Principle routes of exposure: Skin,Eyes, Inhalation Target organ effects: Irritation. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS-No Weight% Oxyfluorfen 42874-03-3 1.5 Di uat dibromide 85-00-7 0.1 Glyphosate 1071-83-6 8 Other Ingredients No-CAS# 90.4- Comments:Contains petroleum distillates. 4. FIRST AID MEASURES Eye contact: Hold eye open and rins slowly and gently with water for 15-20 minutes. Remove contact lenses,if present after the first 5 minutes,then continue rinsing eye. Call a poison control center or doctor for treatment advice Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor-for treatment advice Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so be a poison control center or doctor. Do not give anything by mouth to-an unconscious person Inhalation: Move person to fresh-air.If person is not breathing,caIL911 or an ambutance_then give artificial respiration,preferabley by mouth-to-mouth,if possible. Call a poison control center or do-dar for further treatment advice Notes to physician: Do not induce-vomiting:contains petroleum distillates and/or aromatic solvents.Aspiration may cause pulmonary oedema and pneumonitis. FIRE-FIGHTING MEASURES Revision date: Page 1-of-4 SECTION VI HEALTH HAZARD DATA Routes of Entry: Inhalation? Yes Skin? Yes Ingestion? Yes Risks from Acute Exposure: Inhalation may cause allergic reaction. Ingestion may cause vomiting and diarrhea. Skin contact may cause skin irritation on sensitive skin. Risks- from Chronic Exposure: None known. Medical Conditions Generally Being Aggravated by Exposure: None known. Carcinogenicity: NIP?No OSHA Regulated? No FIRST AID Inflation: Move victim to fresh air. Consult a physician_. Ingestion: Induce vomiting. Consult a physician. Skin contact: Wash with soap and water. SECTION VII SPILL/LEAK/DISPOSAI.PROCEDURES SpilULeak Procedures: Spills should be contained with dikes and clay absorbent spread over spilled product. Place absorbed product in containers for suitable disposal. SECTION VIII SPECIAL PROTECTION PERSONAL PROTECTION EQUIPMENT Eyes/Face: Not normally required. Gloves: Not normally required. Respirator: Wear NIOSH approved respiratory protective equipment when mists o:vapors „ray be encountered when working with the product as a spray. WORKPLACE CONSIDERATIONS Maintain normal safe working environment. SECTION IX SPECIAL PRECAUTIONS Storage: Store in a cool dry place. SECTON X REGULATORY INFORMATION EPA: This product is exempt from EPA regulation as a pesticide. EPA: This material is not considered to meet any hazard category of SARA Title III. Transportation: The "Transportation of Dangerous Goods Act" classification for this product is: Not Regulated. DOT Classification:Non-Toxic,4--n-Corrosive, Non-Hazardous. Class 60. MATERIAL SAFETY DATA SHEET **Organocide ** Organic Insecticide Organic Laboratories, ►rnc Telephone: (561)286-5581 P.O. Box 1931 Facsimile: (561) 286-8113 Stuart, FL 34995 Emergency Tel: (561) 223-9260 Cherntrec Telephone (800)424-9300 Date Prepared: August 3, 1999 SECTION I MATERIAL INDENTIFICATION Product Name: Organocide Organic Insecticide SECTION II INGREDIENTS AND HAZARDS Blend of sesame oil and fish oil with emulsifiers. The specific mixture of ingredients is considered to be a trade secret and is withheld in accordance with the provisions of 1910.1200 of Title 29 of the code of Federal Regulations. Mixture is not considered a carcinogen by IAARC or NNTP. All components are TSCA listed. This mixture does not contain any toxic chemicals in quantities subject to reporting requirer:ents of SARA 1986, Section 313, Title III and 40 CFR 37 . SECTION III PHYSICAL DATA Appearance and Odor: Yellowish-Brown liquid with a slight fish odor. Boiling Point: N/A pH: 6.0-7.0 Specific Gravity: 0.95 Solubility in Water: Miscible SECTION IV FIRE Al`.'D EXPLOSION DATA Combustible: No Means of Extinction: N/A Hazardous combustion Products:--None Unusual Fire/Explosion Hazards: None SECTION V REACTIVITY DATA Material is stable. Hazardous polymerization cannot occur. Chemical Incompatibilities: None iia:zardous Decomposition Products: CO, Oz, hydrocarbons. 5. HANDLING AND STORAGE HANDLING:In case of spill,sweep or vacuum and dispose in compost area or garden. STORAGE:Store at ambient temperature in-a dry location.Keep out of reach of children and domestic animals.. 6. EXPOSURE CONTROLS/PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE:Eye protection recommended. SKIN: Gloves recommended. RESPIRATORY: Dust mask recommended. 7. PHYSICAL AND CHEMICAL PROPERTIES- PHYSICAL STATE: Loose particulate COLOR:Dark Brown BOILING POINT:N/A SOLUBILITY IN WATER:No 8. STA-BILITY AND REACTIVITY STABLE:Yes HAZARDOUS POLYMERIZATION:Will not occur. CONDITIONS TO AVOID:None known. POLYMERIZATION:Will not occur. INCOMPATIBLE MATERIALS:None known. THE-INFORMATION CONTAINED HEREIN IS BASED ONDATA CONSIDERED TO BE ACCURATE.HOWEVER,NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO RE OBTAINED FROM THE USE THEREOF. ALWAYS READ AND FOLLOW LABEL INSTRUCTIONS. MATERIAL SAFETY DATA SHEET 1.PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Ocean Forest PRODUCT DESCRIPTION: Potting Soil MANUFACTURER: United Compost and Organics DBA FoxFarm Soil and Fertilizer Co. - 1220 51h St. Arcata,CA.95518 707-826-1-991 2: HAZARDOUS INGREDIENTS IDENTIFICATION Chemical Name CAS# OHSA-PEL ACGH3 TLV Nuisance Dust N/A Respirable 5mg/m3 5mg/m3 Total 15mg/m3 10mg/m3 POTENTIAL HEALTH EFFECTS EYES:May cause eye-irritation SKIN:May cause irritation. SKIN ABSORPTION:NO INGESTION:Do not eat. INHALATION:Ycs. ACUTE TOXICITY:Yes CHRONIC:No MEDICAL CONDITIONS AGGRAVATED:Individuals with pulmonary and/or respiratory disease sbould-avoid exposure to dust. 3. FIRST AID MEASURES EYES:Flush eyes with water.Obtain medical attention if irritation persists. -SKIN: Wash with water and soap if irritation occurs.Seek medical attention-if-condition persists. INGESTION: Drink warm water or milk and induce vomiting.Consult a_pbysician. INHALATION:Move victim to fresh air.Give oxygen artificial respiration if necessary;seek medical attention. 4. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA:Water spray.Dry foam_ FIRE FIGHTING PROCEDURES:Avoid smoke inhalation. -AUTOIGNITION TEMPERATURE: N/A FLASHPOINT:N/A HAZARDOUS DECOMPOSITION PRODUCTS:N/A. 9/22/14 9:13 AM luring Nature-100%Organic Worm Castings S ; s d m COMM natural OCCUMO"trr .. _.w..__. his produ€t is made tom natural and c�r€,�ant�mat ai" .W _w._ ."_.- )�_W of dust _ " airy to wounds.iinhaL amounts t r r w pm .._..._« _ - health hazards d e xen n The pr _ __ �. _ __ �_ _ _i mat �ir substance such as sail etch sherd be W E $ x ..w iry ft1Y�d$d _m..,.. €he tn� t+ con-weed in this is .' � Ica M tdw a The a m4n its made a labile solely for r� ration .imes�art, and _ ,b �}gr�dyrrysr�r��a�tr�:.ryat��(c�a�t��t}��e�d,{- _� ..�,. .__...�. _. ..._..; 3.:_...._.a....._. ...�.. V3tiiil<(i.�reciii�/ents, weDf -.»..........-._...V-,..N-,•. r..,....},.,-,._ >.r.......,..-.. .._•.-. ...,...>.-•.. m......�........-.3.-...-.-..,. >z.. 3,. v-..... i e.r-+....,....4.... 1-.Y...........4..... )ack le:///Users/roberimackenzie/Desktop/msds%20sheLts/Nurturing%20Nature%20-%20100%25%20Organic%20Worm%20Castings.webarchive Page 2 of 2 Nurturing Nature-100%Organic Worm Castings 9/22/14 9:13 AM Material a!e Data Street Eranics Inc. W. a. "Wonder ... _-_ ._._....._.... Worm ram iiiianufacturves Warm- i t I f'itiom.. ..,__ 25 7 -112 X -:�.... _ .._.,.__....: ` _._._.... ff-rrr l: {r rtiixn ,atu .ca{ ....__..« �__.....__...__..s..__...._..._._.,J VdVµi _ Se IQI 2: Ii IZar€ tSfisgredienft This prodtid contains no hazafdous cfitT ejq s 1 Section 3: 'Phusical/Chemicai GhaLatledstic'i S "firm P'olft Sviecft firai�i I AI Yjpgq Pressure __.WI _.. ` ___. Volatile by Volume: _ NIA E _ .appearance and€fir:_ � BiaCk T .mod ododess ; Sotubii in latier. otute Pfi Levei. �wb_. =�If dw Rater_ 3 �WA Section 4._... Fke star Ex�iv ott ij€ zar s _... ..._ Ni ._.._._.�...._ _. e _e E r menIL- i WAI i@ Used: WA ! _ SpecW Free MHazard3. . E7EfEtIiSt ie( a'!._. .W __ $. .w.Y_ .• __�_ w {E. __ w.�w.__. ._ w._ wTM T- _.__r _.._ _ } Section§: 'Stabi# �eHazardous_Rol fm_erfzat urr fi irtcotnp fi"bali :M._.__ NIA ' j Hazardous Descri�itbri�: sectiert&: -.:�.....�.. �Health Hazards_._._...�_..�_...�._ .�._..r_.�:...��.�.�...r_.._�..._...,�..�_.._,.__...�._.,...__..__,.�.. .__..�..� �..�� _._ _ i ve€a t uwftes of�v7 ter seek trl call ad�!�Ee _._�. � t t s } � I 3 Slain Contact: li __. , se w��-h ene practices 3 3 • 9 fi f Sec#tc►n T: Spilts Leaks and-01s ai Use era3 a!O Section 8: _ - Special Handling Rracedtrres file:///Users/robertmackenzie/Desktop/msds%20sheets/Nurturing%20Nature%20-%20100%25%200rganic%20Worm%20Castings.webarchive -Page 1 of 2 MATERLA-L S-AFETY DATA SHEET IDENTITY AS IT APPEARS ON LA IEL:FI SImn Plant Products NUKE EM SECTION I—CONTACT INFORMATION hone: 503.256.2400 Manufacturer's Name: Flying Skull Plant Products- g Telephone:p Address: 9220 SE Stark Street Information: 503.256.2400 Portland;Oregon 97216 Date-Prepared: 10.20.11 SECTIONH—HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Hazard ous-Com Dnents(;peclfic,ChemiicalIden - None Common Name: None SECTION-III—P$YSICAL/CHEMICAL CHARACTERISTICS Boiling2120 -Specific-Gravity: 1.05- Vaporor Point:Pressure: Same as water -Melting Point: 30OF Vapor Density: Scene aswater Evaporation Rate: Same as water Solubility in water: Complete A arance/Odor: YdL----wNmAbem SECTION IV—FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Extinguish Media: N/A Special-Fire-Procedures: None -Fire/Explosion Hazards:None Flammable Limit: N/A LEL&UEL: N/A SECTION V—REACTIVITY DATA Unstable_Stable.XXX Conditions to avoid:>130"F/pW3.5/pF>9.5 Incompatibility/Materials to-avoid:Caustics,acids,strong bases Hazardous Pol erization May Occur Will Not Occur XXX Co�itions to avoid: N/A SECTION VI—HEALTH HAZARD Inhalation: None Eye: Mild Irritant Skin: Mildlaritant Ingestion:onograp xaphs:s:wd,•N/A ight Health Hazards: None Known -Carcinogenicity: None NTP: -N/A IAEC M OSHA Regulated:No Signs/Symptoms of Exposure: None Emergency First Aid Procedures: N/A Medical Conditions Generally Aggmated by Exposure: None Known SECTION VU—PRECAUTIONS FOR SAFE HANDLING/USE Material Released/Spilled: Avoid slipping,wash down with water aB 'Stor e: Store at room temperature Waste Disposal: Flush down any waste system flush with water. If i Other Precautions: In case of eye or skir-con rritation ersi contact physician. SECTION VIH—Control Measures- -Respiratory Protection: Not required- Work/Hygienic Practices:Normal-Good Special Ventilation: Not required Protective Gloves: gybber&V s raro=mnen&d -Eye Protection: Safety es recommended Other Protection: N/A Skin Protection: Standard rubber gloves and-similarly approved-type work clothes--recommended. Section 6: HEALTH HAZARD DATA Occupational Exposure Limit: N/A Threshold Limit Value: Not established OSHA Permissible Exposure Limit: Not established Health Hazard Determination: The components of this mixture have not-been-found to be carcinogenic.-Components of this--mixture-can be irritating to the.eyes.Their identity-is-proprietarT-and-therefore -considered a trade secret. Effects of Overexposure: Contact of product with eyes may result in mild irritation reaction. Emergency and First Aid Procedure: Inhalation: Remove person-from contaminated-area to-fresh air.If breathing is difficult, see physician Skin: In case ofeye or skin contact,flush with water. If irritation-persists, contact- physician. Eyes: In case of eye or skin contact,flush with water. If'irritation persists,contact physician. Ingestion: In case of eye or skin contact,flush-with water; If irritation_persists,contact physician. -Section 7: STORAGE,HANDLING, SPEEIAL PRECAUTIONS Storage and Handling: Store in tightly sealed-containers(prefemibly full) in cool dry area,away from Beat,flame and sunlight Special Precautions: None Required US Poison Control Centers: 1-800 222-1222 Manufactured for: NPKIndustnes 1-600-Skypark Dr.-Suite 215- Medford,OR 97504 Revised- 101 5110 +1.800_944-.4509- DISCLAIMER:The information in this Material Safety Data Sheet(MSDS)-is believed to be correct-as of-the date issued. By maldng the MSDS available,NPK LLG,DBA NPK Industries-does not make any express or implied warranty(including,-my warranty of merchantability or fitness for a particular purpose)regarding the MSDS,its accuracy or the product to which it relates.Anyone using this information agrees that NPK Industries shall not be held-liable(based on its-negligence-or otherwise) for any personal injury or other damage relating to,or arising from-such use,includinK-direct,incidental,or consequential damage and such user agrees to indemnify NPK Industries for any claims-arisino out if its use. Material Safety Data Sheet Section 1 : IDENTIFICATION Product Name:PM Wash—RTU -Product Type: Foliage Cleaner Chemical-Name: N/A- Formula: Proprietary Section 2: PHYSICAL DATA Flash-Point(closed-cup method)_ N/A Specific Gravity: 0.9927- Vapor Pressure: N/A Vapor Density: Greater than 1 Boiling Point/Melting Point: >200 Solubility in Water: Soluble. Appearance: Clear liquid Section 3: FIRE AND EXPLOSION HAZARD DATA Extinguishing Media: N/A FlashPoint: Non-flammable Special Fire-Fighting-Procedure: N/A UnusuaYFre andExplosion-Razards: None required .Stability: Stable- hazardous-Polymerizatian: Will not occur -Materials to Avoid: N/A Conditions to Avoid: Below 35OF Hazardous Decomposition Products: None Section 4: SPILL,LEAK AND DISPOSAL PROCEDURES Precautions if MatGcialis-Spilled-or Soak spills with direct sand,sawdust,vermiculite,-or Released: other suitable absorbent materials to prevent-slipping. Waste Disposal Methods: Dispose according to federal,state and local regulations Section 5: PROTECTION INFORMATION Ventilation: Not normally required Respiratory Protection: Not normally required,but if vapor concentration is high due to heat,use respirator Eye-Protection: Safety glasses and goggles recommended. Eight Garden&Home Insect Control RTU ID#4406 2 of 2 Section-VIH-Health-Hazard Data- PRODUCT LABEL BEARS ONLY THE"CAUTION'SIGNAL WORD. -FIRST AID.—IF SWALLOWED: Call-a physician of Poison Control Center immediately. Induce vomiting by giving victim 1 or 2 glasses-of water and couching back of throat with finger. Do not induce vomiting or give anything by mouth to an unconscious or-convulsing person. IF IN EYES: Rinse eyes for at least 15 minutes with plenty of water. Call a-physician if irritation persists. Get medical attention immediately. IF ON SKIN.Wash promptly with plenty of soap and-water. Wash contaminated clothing. IF INHALED:Remove victim-to fresh air. Apply artificial respiration if needed to-keep victim breathing-. NOTE TO PHYSICIAN: N/A CAUTION-May be harmful if swallowed or absorbed through the skin.Avoid breathing spray mist or vapors.Do not take internally. Avoid contact with skin,eyes-or clothing. Wash hands and face thoroughly after handling and-before eating. Section-X-Tratisportation D.O.T.SHIPPING NAME:-Misc.Lawn-&Garden Insecticide Class N.O.S. D.O.T.HAZARD CLASS:N.O.S_Non-hazardous D.O.T.LABELS REQUIRED:No I.D.Number:N.O.S. Note:The information contained herein is,offered only as a guide to the handling of this specific material. Since such information does not relate to the use of the material with any other material or in any process, any person using this information must-determine for himself its suitability for any particular application. The buyer and user assume all risk and-liability of use,storage and/or handling of this product not in accordance with the terms of the-product label. KEEP OUT OF REACH OF CHILDREI_`.r ABBREVIATION KEY N/A:NOT AVAILABLE OR APPLICABLE N/E:NOT ESTABLISHED TLV: THRESHOLD LIMIT VALUE TWA:TIME WEIGHTED AVGJ8 HOUR WORKDAY STEL:SHORT TERM EKPOSURE_LINfiT D.O.T.:DEPARTMENT OF TRANSPORTATION DISCLAIMER OF EXPRESSED AND E%4PLIED WARRANTIES Buyer-assumes all risks of use,storage and handling of this-material not in strict accordance with directions given herewith. Eight Garden&Horne Insect Control RTU,4-406 U.S.Department of Labor Material Safety Data Sheet Occupational Safety-and-Health Administration May be used to comply with (Non-Mandatory Form) OSHA's Hazard Communication Standard, Form Approved 29 CFR 1910.1200. Standard must be consulted -OMB No.1218-0072 for specific requirements. IDENTITY(As Used on Label and List) III#4406 Bonide Eight Garden&Home Insect Control RTU Date:March 10,1009 Section I Bonide Products,Inc. (800}424=9300 6301 Sutliff Rd. (315)736-8231 Oriskany,NY 13424 Section-II-Hazardous Ingredients/Identity OSHA PEL ACGIi1 1'LV -Other Limits %(Optional) Hazardous Components(specific Chemical Identity: Common e(s) TWA—N/E N/E STE—N/E 0.02 Permethrin [CAS NO:52645-53-11 TW-A-N/E STE—N/E 99 98 Aqueous/emulsion Diluent Section III-Physical/ChemicaTCimacteristies PHYSICAL FORM:Liquid COLOR:opaque/white BULK DENSITY:N/A VAPOR PRESSURE:N/E ODOR:Slight Insecticide type-odor. pH:5.5 to 7.0 EYE:N/E SPECIFIC GRAVITY:- 1.0 LD50 ORAL:*>4000 tng/kg LD3B DERMAL:*>2000 mg19- Section IV-Fire/Explosion-Hazards FLASH POINT: Aqueous base product. Will not-flash or burn.WiIL"steam"from water content FLATM[ABTLTTY: N/E EXrINGUISHING MEDIA for-cardboard shipping cartons: Water Fog; CO, or Chemical foam FIRE FIGHTING-COMMENTS: Foam/Fog system preferred. Remove closed case goods from path of fire Use og nozzles if water is used.Use air supplied or canister breathing masksfor protection against burning casesand cartons. UNUSUAL FIRE/EXPLOSION HAZARD- None.-Toxic vapor fromlieated product - Does not contain explosive ingredients. _Section V-Special Protection Information RESPIRATOR TYPE:None likely needed-during application. (Coarse spray droplets from Hoses End Sprayer) EYE PROTECTION: Protective eyewear is always advisable when applying pesticides. GLOVES:-Wear Rubber or neoprene Household type work gloves. OTHER PROTECTION:Body covering clothing:shoes plus socks. KEEP OUT OF REACH OF CHILDREN Section VII-Reactivity Data -S 31LITY:Stable POLYMERIZATION-Will Not Occur -CONDITIONS TO AVOID: Do-not allow products to freeze.If1`rozen wrnra to ambient temperature,thoroughly mix and-test spray a small leaf area of paint to assure that product will work properly. DECOMPOSITION:Product is a diluted water base Insecticide andnot-likely to have any hazardous decomposition. Section-VIH-Storage and-Handling STORAGE: Store product in it's original labeled container in a cool,dry,locked place outofreach of children. STORAGE TEMPERATURES:Ambient(Average-Warehouse)Temperatures. Do.not allow to-freeze. SHELF LIFE:2 to 3 years if stored properly. PRODUCT DISPOSAL: Do not contaminate water, food or feed by storage or disposal. -Excess product-may be disposed of.on site or at an approved disposal-facility or continue to use up-all-product as-directed forinsect control. CONTAINER DISPOSAL:Do not re-use empty container,wrap in=several layers of newspaper and discard-in trash. Eight Garden&Home Insect Control RTU,4-406 Eight Insect Control RTS ID# 2 of 2 Section-VII—FIRST AID PRODUCT LABEL BEARS ONLY THE"CAUTION"SIGNAL WORD. FIRST AID:IF SWALLOWED:Call a physician of Poison Control Center immediately. Do not induce vomiting or give anything by mouth to an unconscious or convulsing-person. EYES:Rinse eyes for at least 15 minutes with plenty of water. Call a physician if irritation persists. SKIN. Wash promptly and thoroughly with-plenty of soap and water-. Wash contaminated-clothing. Get medical -attention if irritation persists. INHALATION:Remove victim to fresh air. Apply artificial respiration if needed-to keep victim breathing. NOTE TO PHYSICMN: Permethrin is considered a mild irritant and moderately tonic. Treat symptomatically. CAUTION:May be-harmful if swallowed-or absorbedAhrough the skin. Avoid breathing spray mist or vapors. Do not take intemally. Avoid contact with-skin,eyes or clothing. Wash hands and face thoroughly after handling and before eating,drinking or smoking. Section X-Transportatiol- -D.O.T.SHIPPINGNAME:Misc.Lawn&Garden Insecticide Class N.O.S_ D.O.T.HAZARD CLASS:N.O.S.Non-hazardous D.O.-T.LABELS REQUIRED:No I.D.Number:N.O.S. Note:The information contained-herein is offered only as a guide to the handling of this specific material. Since such information does not relate to the use of the material with any other-.material or in any process,any person using this information must determine for himself its suitability for any particular application. The buyer and user assume all risk and liability of use,storage and/or handling of this product not in accordance with the terms of the product label. KEEP OUT OF REACH OF CHILDREN ABBREVIATION KEY N/A-.-NOT AVAILABLE OR APPLICABLE NB:NOT ESTABLISHED _TLV: THRESHOLD LIMIT VALUE TWA:TIME WEIGHTED AVG./S HOUR WORKDAY STEL:SHORT TERM EXPOSURE LMU D.O.T.:DEPARTMENT-OF TRANSPORTATION DISCLAMER OF EXPRESSED AND IMPLIED WARRANTIES -Buyer assumes all risks of use,storage and handling of this material-not in strict accordance-with directions given herewith. Eighdnsec tYardC=rdenRTSRT3 Materrial:Safety Data Sheet U.S.Department of Labor May used to comply with Occupational Safety-and Health Administration OSHA's Hazard Communication Standard, Form(Non Approve y Form) 29 CFR 1910.1200. Standard must be consulted Form Approved OMB No.121&0072 for specific requirements. IDENTITY(As Used on Label and List) ID#4407 Bonide Eight Insect Control Yard&Garden Ready to Spray Date:August 22,2007 Section I Bonide Products,Inc.- (800)424-9300 6301 Sutliff Rd. (315)736-8231 Oriskany,NY 13424 Section-H-Hazardous Ingredients/Identity Hazardous Components(Specific Chemical Identity: Common-Names) OSHA PEL ACGIH TLV Other Limits %-(Optional) Permethrin [CAS NO.52645-53-11 TWA—N/E STE—N/E 2.50 Aqueous/emulsion Diluents TWA-N/E STE--N/E 97.50 Section III—Physical/Chemical Characteristics PHYSICAL FORM:Liquid COLOR:opaque/white pH:6.5 to 7.0 ODOR Slight Insecticide type odor. SPECIFIC GRAVITY:-0.9975- LD,.DERMAL:*>2000 mg/kg- VAPOR PRESSURE:N/E LD„ORAL:*>4000 mg/kg -Section IV-Fire/Explosion Hazards FLASH POINT: Aqueous base product. Will not flash or bum. Wi1L"st 2&'from water content. FLAM14ABILITY: NIE EXTINGUISHING MEDIA for cardboard shipping cartons:Water Fog;CO,or,Chemical foam. FIREFIGHTING COMMENTS:Foam/Fog system preferred. Remove closed-case goods from path of fire. Usefog nozzles if water is used. Use air supplied.-or canister l r=eking masks for protection against burning cases and cartons. UNUSUAL FIRE/EXPLOSION-HAZARD,-None. Toxic vapor from heated product--Does not contain explosive ingredients. Section V—Reactivity Data STABILITY:Stable POLYMERIZATION:Will Not Occur CONDITIONS TO AVOID:Do not allow products to freeze,If frozen warm to ambient temperature,thoroughly mix and test spray a,small leaf area of paint to assure-that product will work properly. DECOMPOSITION:Productis a diluted water-base Insecticide and not likely to have any hazardous decomposition. Section VI-Storage and Handling STORAGE: Store product in its-original labelehcontainer in a cool,dry,locked place out of reach of children. -Keep away from-food,feed and feed stock. Always practice good hygiene when handling this or any pesticide or chemical. KEEP OUT OF REACH OF CHILDREN. ST ORAGE TEMPERATURES:Ambient(Average Warehouse)Temperatures. Do not allow to freeze. EYE PROTECTION: Safety glasses or-goggles. SKIN:Avoid contact. Wear Rubber or neoprene gloves. Body-covering clothing:shoes plus sacks. Wash thoroughly after handling;launder contaminated clothing separate from other laundry.- RESPIRATOR TYPE:None likely needed during-application. (Coarse spray-droplets from Hose-End Sprayer) For outside use only. Avoid mist orvapors,stay upwind-when applying. PRODUCT DISPOSAL: Do not contaminate water, food or feed by storage-or disposal. Excess product may-be disposed of on site-or at-an approved disposal facility or continue to-use up all product as directed for insect control. CONTAINER DISPOSAL:Do not re use empty-container;wrap in several layers of newspaper and discard in trash. Do not discard unused product into drains or the environment. EigbtlnsectYardGardenRTSRTS Section VI-HANDLING AND STORAGE. PERSONAL PROTECTIVE EQUIPMENT: EYES AND FACE:For Mist exposure,wear chemical protective gaggles,face shield or safety-glasses. -RESPIRATORY.Avoid breathing mist or vapor. Use only with adequate ventilation or protective equipment Apply with wind to back,avoid standing in mist or spray. GLOVES:Wear chemical-protective gloves-made of materials such-as rubber or neoprene.Thoroughly wash the outside-of gloves with soap and water prior to removal.Inspect regularly for leaks. PROTECTIVE CLOTHING:Depending-upon concentrations encountered,wear coveralls or long-sleeved uniform and head covering.Launder-all work clothing before reuse-(separately from household laundry). WORK HYGIENIC PRACTICES:Clean water should be available for-washing in case of eye or skin contamination. Wash skin prior to eating,drinking or using tobacco. Shower at the end of the workday. ENGINEERING CONTROLS:Use local exhaust-atall-process locations where dust may be emitted. Section VH—Reactivity Data STABILITY:Stable INCOMPATIBLE MATERIALS:None noted HAZARDOUS DECOMPOSITION PRODUCTS. None noted HAZARDOUS POLYMERIZATION:-VAII not occur. Section VHI-Ecological Data Do not apply directly to water,or to areas where surface water is present or-in areas below the mean high water mark.- Do not contaminate water by cleaning of equipment or disposal of water. -Section IV-Environmental and Disposal Information STORAGE AND-HANDLING: Store ina cool, dry place.and-avoid excess heat. Store in original containers only. Wash hands and other exposed skin surfaces prior to-smoking or.consuming food or beverages. Do notput concentrate or dilute material into food or drink containers. Do not contaminate.other pesticides, fertilizers,water,food or feed by improper storage or-disposal. SPILL OR LEAK: Isolate and post-spill area. -Keep material-out of streams and sewers. Contain and absorb-spilled material with a-solid absorbent such as sand, cat litter, commercial- clay or other suitable absorbent. Place in an approved-drum-and dispose of.material-following the methodoutlined below under"Waste Disposal"- WASTE DISPOSA . Because acceptable-methods of disposal may vary by location and because regulatory requirements may change,the appropriate regulatory agencies should be contacted prior-to disposal.. Steel-containers which contained these materials must be crushed and disposed of in a sanitary-landfill. Do-not-cut or weld steel containers. Section V-Special-Precautions In case of a large spill or leak,contain liquid with sand or other noncombustible material,then place in clean container for disposal. Wastes,including spills or rinsates,and leftover pesticide-that cannot be used according to label instructions must be disposed of according to applicable federal,state,or local procedures. NFPA HAZARD.RAT--ING: Health:0,Fire:0,Reactivity:0,Special:- DOT:Not regulated OTHER REGULATORY CLASSIFICATIONS:- SARA TITLE III: EHS—No,CERCLA Reportable—No,Toxic-chemicals-No NOTICE: This information is believed to be accurate and-reliable- However,-no guarantee-expressed or implied is made with repect to-the information contained herein. CEP OUT OF REACH OF CHILDREN ABBREVIATIONXEY N/A:NOT AVAILABLE OR APPLICABLE NEE.-MOT ESTABLISHED ND: Not Determined TLV: THRESHOLD LIMIT VALUE TWA:TIME-WEIGHTED AVG./&HOUR WORKDAY STEL:SHORT TERM-EXPOSURE LIMIT D-.O.T.:DEPARTMENT OF TRANSPORTATION DISCLAIMER OF-EXPRESSED AND Il"LIED WARRANTIES- Buyer assumes all risks of use,storage and handling of this-material not-in strict accordance with-directions given herewith. Bonide Citrus,Fruit&Nut ORCHARD SPRAY RTS ID#67702174(2) Page 2 of 2 Material Safety Data Sheet U_S.Department of Labor May be Safety comply with Occupational Safetyand Health Administration Y (Non-Mandatory Form) OSRA'sBazard communication Standard, Form Approved for-specific 29 CFR 1910.1200. Standard-must be consulted OMB No.1218-0072 requirements. IDENTTPY(As Used on Label and List) Bonide Citrus,Fruit&Nut ORCHARD Spray RTS ID#67702174(2.)Date:February 28,2o1 Section I $onide Products,Inc. (800)424-9300{Chemtrec) 6301 Sutliff Road (315)73b-8231 Oriskany,NY 13424 Section II-Iagredients/Identity Components(Common Names(s) OSHA PEL ACGIN TLV Other Limits %(Optional) 10. Sulfur CAS Reg.No.7778-19-9 % Pyrethrins CAS Reg.No..8003-34-7 0.25% Section VI-Physical and Chemical Properties APPEARANCE:Pale yellow,translucent solution ODOR Slight alcohol PHYSICAL STATE:Liquid BOILING POINT RANGE:>100°C MELTING POINT/FREEZE POINT:ND VAPOR PRESSURE:ND VAPOR DENSITY(Air--I): ND SPECIFIC GRAVITY: —L00 pH: --4.75 Section V—First Aid Measures EYES:-Flush-eyes with-plenty of water, Hold eye open and rinse slowly and gently-with water for 15-20 minutes. Remove contact lenses,if present,after the first 5 minutes,then continue rinsing eye. Call a-physician if irritation persists. SIGN:Wash thoroughly with soap-and water.INHALATION:Remove to fresh air. Seek medical attention if irritation persists. INGESTION:'Do not induce-vomiting. Drink 2-3 glasses of water. Contact physician for further treatment. Section IV—Health Hazard Data POTENTIAL HEALTH EFFECTS: Primary Route(s)of Entry:Eye,skin.contact,inhalation of mist. EYES:May cause mild,reversible eye irritation. SKIN:May cause mild skin irritation. Repeated exposure may cause mild sensitization. PROTECTIVE REQUIREMENTS: WORK CLOTHING: Wear long-sleeved coveralls or uniform,cap,safety shoes and neoprene or impervious gloves. or contact with mist, protective goggles and face shield EYE PROTECTION: Where potential of splashing exists, should be worn. A source of clean water for flushing the eyes should be nearby. Section 111—Fire/Explosion Hazard Data FLASH POINT:>325 degrees F EXTINGUISHING MEDIA:Carbon Dioxide,Dry Chemical,Foam or Water. FIRE FIGHTING COMMENTS: Isolate fire area. Evacuate downwind residents and all areas where fire seriously threatens the product containers. Wear full protective-clothing including rubber boots, neoprene gloves and self- contained breathing apparatus. Attempt=xo keep containers cool. Do no breathe-or contact smoke or vapors. Contain the-run-off,if possible,for proper disposal. Section VI-HANDLING AND STORAGE GENERAL-PROCED-URES: Store in a cool, dry,well-ventilated-place.Do-not use or store near heat,-open flame-or hot surfaces. Store in original-containers only. Keep out ofreach of children and animals. Do Not Freeze. Always practice good hygienewhen working with this or any chemical. 6. HEALTH HAZARD DATA ROUTES OF EXPOSURE: Ingestion, eyes,and skin. SYMPTOMS INGESTION: May cause gastric distress as evidences by nausea and diarrhea EYES: May cause pain,excessive watering,redness and stinging. SKIN: Prolonged exposure or repeated exposures may cause skin irritation and drying. FIRST AID EYES: Irrigate immediately-with water for at least 5-minutes. Consult-physician if irritation persists. SKIN: Wash off in flowing water or shower. INGESTION: No adverse effect anticipated by this route of exposure incidental to proper--industrial handling. For accidental ingestion of copious quantities by children,orappearance of systems noted in Section VI,contact-a-physician prior to taking any medical action. NOTE TO CARE AID ATTENDANTS:-Provide supportive care,consult and have available MSDS sheet and make said— information known and available to attending medical support persormel. 7. PRECAUTIONS FOR SAFE HANDLING AND USE ACTION TO TAKE FOR SPILLS/LEAKS: Contain spills by diking with dirt,sand or other absorbent material. Rope off area to prevent inadvertent spread of spill. Place leaking containers in overpak containers or transfer material to clearly marked new containers. Upon discovery of leak or spillage,notify-proper supervisory personnel and if situation wan-ants,notify the proper Local or State hazardous waste response units-prior to taking any action other than initial- emergency response. All-materials used to absorb leak or spill should be handled and-disposed of in-accordance to Local, State and Federal environment laws. Workers performing clean-up duties should be made-aware of any potential health hazards and must wear the correct protective clothing-and-devices needed to perform the duties in a-safe proper manner. PRODUCT DISPOSAL: Excess product that cannot be used without violating—label—1 instructions must be disposed of-in a manner that is in full compliance of Local,State and Federal laws. CONTAINER DISPOSAL: Check with Local and State-authorities for proper disposal prior to offering for recycling,- incineration or sanitary land fill. Containers sent to local land fills should be tripIc insed,punctured and crushed prior to disposal. HANDLING&STORAGE-Keep away from water.-Material will dissolve.in the presence of moisture. High humidity will cause product to cake. S. CONTROL MEASURES RESPIRATORY PROTECTION: Not required VENTILATION: No special requirements PROTECTIVE GLGVES: Chemical resistant rubber gloves EYE PROTECTION: Chemical protective eye wear. WORK/HYGIENIC PRACTICES: A-void-contact-with eyes,skin,clothing. Wash- thoroughly after handling. 9. REGULATORY STATUS -T his product does-not contain-material regulated under SARA Title 3-Section 313 GW MSPUBMSDS Meguoot Page 2-0f 2 Pages MATES AL SAFETY DATA SHEET M4NUFACPl1REDBP: EDP IDc. Box 618 2001 W Main Street Mendota IL 61342-0619 (800)255-4906 FAX{815)539-6981 L PRODUCT IDENTIFICATION PRODUCT-TIrADE NAME:-Mega-Root 747-7 DATE PREPARED: August 26,2003 CHEMICAL FAMILY:Blended Nitrogenous fertilizers FORMULA; NA,Formulated Mixture. National-Fire Protection Association Rating SYNONYMS: Water soluble fertilizer Rating level:4-Extreme,3-High 2-Moderate,1-Slight,0-Minium CAS NUMBER: NA,Formulated Mixture- Health 0 EPANUMBER: None required. Flammability 0Reactivity 0 2. INGREDIENT 3 AND HAZARDS HAZARD CLASSIFICATION: IRRITANT HAZARDOUS INGREDIMS CAS# LIMITS None 3. PHYSICAL DATA APPEARANCE: Brownish-Blackhydroscopic fine granular BULK DENSITY: 1.60 ODOR.,Bland SOLUBILITY IN WATER: -3.51bs per gallon SPECIFIC GRAVITY:-N/A pH: 7.2 in distilled water BOILING-POINT:N/A VOLATILES: None FREEZING POINT:N/A NA=NOT APPLICABLE A FIRE ANQ=EXPLOSION-DATA FLASH ToIlV'C F,COC: None -.>,LAMM,ABLE LIIVHTS:-.Not established -AUTO IGNITION TEMPERATURE:Not established- EXTINGUISHING MEDIA: Dry chemical,foam or carbon dioxide. FIRE&EXPLOSION HAZARD:Firefighter;should use self-container breathing apparatus to avoid exposure to smoke and vapor.. FIRE-&EXPLOSION HAZARD: None known. SPECIAL PROCEDURES: Keep away from water. Material will dissolve. 5. REACTIVITY DATA S-TABH;ITY: Product is stable. INCOMPATIBiLE - Avoid contact with strong oxidizing agents. -DECOMPOSITION PRODUCTS- Ammoniaand sulfur gases may under fire conditions. FIA ZARDOUS POL-,YMERIZATI011i.. Will not occur. Page 1 of 2-Pages G:MSPUB:TWP1=f MSDSTG 7A7-7 Mega Rom Spectrum Group Hazardous Material Identification Division of United Industries System-(HM1S) P.O.-Box 142642 St. Louis,-MO 63114-0642 HEALTH-1 REACTIVITY-0 Material-Safety Data Sheet FLAMMABILITY-0 PERSONAL— Complies with OSHA's Hazard Communication Standard,29 CFR 1910.1200 1 Trade Name: Spectracide®Triazicide Once &Done! Insect Killer Spray for Lawn &Landscape Product Type: Ready-to-use insecticide Product Item-Number: 10525 Formula Code Number: 21-0712 EPA Registration Number Manufacturer Emergency Telephone Numbers Chemsico For Chemical Emergency: 1-800-633-2873 l Division of United Industries Corporation For Information: 1-800-917-5438 9688-195-8845 8494 Chapin Industrial Drive Prepared by: C.A.Duckworth Date Prepared: November 22, St.Louis,MO 63114 2005 II Hazards Ingredient/Identity Information III Physical and Chemical Characteristics Chemical % OSHA PEL ACGIH TLV Appearance 8 Odor: Water-thin,translucent,water-white liquid with a I slight odor. Lambda-cyholothrin 0.002 NE NE Boiling Point: 220°F CAS#91465-08-6 Melting Point: NA Ph 5.0-6.0 Specific Gravity: 1.0(H20=1) Vapor Density: Greater than 1 (Air=1) %Volatile(by vol.): 95% Solubility in Water: >99% Evaporation Rate: Less than 1 (Butyl Acetate=1) IV Fire and Explosive Hazards Data V Reactivity Data Flash Point: >200°F Stability: Stable Flammable Limits: NA Polymerization: Will not occur Autoignition Temperatures NA Conditions to Avoid: None Fire Extinguishing-Media: Water fog,Carbon dioxide,Dry chemical I Incompatible Materials: NA Decomposition Temperature: NA Hazardous Decomposition Special Fire-Fighting Procedures: Use procedures for elimination of or Byproducts: NA original fire source. Unusual Fire&Explosion Hazards: None. Also see Section V. VI Health Hazard Data VH Precautions for Safe Handling and Use Skin Contact: Harmful if absorbed through skin. Avoid contact with skin, Steps to be Taken in Case Material is-Released or Spilled: eyes or clothing. Wash hands thoroughly with soap-and water after Avoid contact with liquid.Soak up with absorbent material. handling and before eating,drinking,chewing gum or using tobacco. Waste Disposal: Remove and wash contaminated clothing. Place empty container in trash or recycle if available. If partially empty First Aid: Take off contaminated clothing-Rinse skin immediately_with call 1-800-CLEANUP for disposal instructions. Never place unused product plenty of water for 15-20 minutes. Call a Poison Control Center or doctor down and indoor or outdoor drain. for treatment advice Handling 8 Storage Precautions: Store in a cool,dry area away from heat or open flame. Special Notes: Have the product lobeiwith you when calling a Poison Control Center or doctor. Health conditions Aggravated by Exposure: None known Ingredients listed by NTP,OSHA;or IARC as Carcinogens-or Potential Carcinogens: None VIH Control-Measures IX Transportation Data Read-and-follow label directions. They are your best guide to using this DOT: Not Regulated by DOT(limited quantity exception) product effectively,and-give necessary safet.-precoutions to protect IMDG:Not Regulated by IMDG(limited quantity exception) your heoith. IATA: Not Regulated by IATA(limited quantity exception) The information and statements herein are believed to be reliable but are not to be construed as warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own pyrficular purpose of any information orproducts referred-to-herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Section 7:Spill or Leak Procedures Environmental Hazard. ....... ..... .. :Do not apply directly to bodies of water. This product is toxic to bees exposedto direct treatment Steps to take if Spill Occurs..... ......:Ventilate the-area.Absorifliquid and scrub the area with-detergent and water.Avoid runoff into storm sewers and ditches leading to waterways. Waste Disposal Method.......... ... ...: Dispose of all waste according to local,state andfederal regulations. Mix with-water and dispose of in approved-landfill. Section&Special Protection Information Respiratory Protection.. .. .. . ........:No special requirements. Ventilation .. .. .. ........ .. .......:Adequate ventilation Eye Protection. ... .... .. .. ... .. ....:Safety goggles Protective Gloves..... .. .. ....... .. Rubber Section 9: Handling&Storage Condifions Storage Temperature(MinJMax.)... ..:60'F/95'F Shelf Life.... ............ .. .. ....:Stable under normal storage conditions up to two-years. Special Sensitivity..... ... .... ... .. :Keep-from freezing. Handling Precautions.. .... .... . ... .:Do area-not Wash oroughly with sop and-water aftget in ee handling. clothing. li ventilated Storage Precautions....... ..... .... Do not keep near-flame.Store in-a cool,-dry place. The information contained herein is provided in good faith and is believed to he correct and-equivalent to OSHA Form 174,as of the date hereof but is issued without guarantee.-Since-conditions of use are beyond our control,user assumes all responsibility and risk. MSDS -Material Safety Data Sheet Trade Name/Synonym ... .. .. .. . .......:Pure Neem Oil-Organic Leaf Polish Date Prepared..... .. .... .. ... .. ......:June i;2009 Chemical Name. .. .. .. ... ... . .. . .. .. .: 100%Cold Pressed-Neem Oil Formula . .. .... . .._. ..... .. ..... .. ..:Extracts of Neem Seeds Section-1: Maaufacturer or Supplier Dyna-Gm Nutrition Solutions-,2775 Giant Road,Ricimond,CA 94806,(800)396-2476-Emergency(51-0)233-0254 Section 2:Hazardous.ingredients Contains no-hazardous mixtures Section 3:Physical Data&Ingredients Physical State at-STP...._....:Liquid- pH .. . .... .. ..... ...:6.5-7.5 Appearance.... ... ... .... .:Brown Specific Gravity. ... ..:0.9-137 Odor.......... .......... . :Garlic Solubility in Water....:Slightly Soluble Boiling Point........... ... :>392°F Vapor-Pressure at 20°C:<1.33 EE-5 Pa Melt/Freeze Point... .......:55°F Vapor Density... .. ....:Greater-than air Exposure limits in air: Chemical or Common Name % CAS# ACGIH TLV:DHSA PEL: Neem Oil 100% 8002-65-1 Not Established Section-4:lire&Explosion Hazard Data Flash Point. .... ........... ..._....:>239°-F Extinguishing Media to Use..... ... ... Dry Chemicals;COz,Water or Water Based Foam Special Fire Fighting Procedures.. .. .. .:None Unusual Fire&Explosion Risk-.. .. ....:None Section 5:Reactivity Hazard-Data Stability..__.... . ..._. ......... .... :Stable Incompatibility ._......... .. .......:None Noted Hazardous Decomposition.... .... ...:None Hazardous Polymerization...... ......:None Section 6:Health Hazard Data Effects-of Over-Exposure: None-Noted. Health Hazards: Acute: May cause-mild irritation to eyesand skin. Chronic: Repeated skin exposure may cause mild sensitization. -Emergency First Aid- If-Swallowed..... .. .... ....: Under 1 ounce does not have any harmful=effects.For larger amounts, do not induce vomiting.Drink one or two glasses of water. Never give anything by mouth to as unconscious person.Calla physician. Skin Exposure............ ..: Wash-with soap and water.Get medical attentionif-irritation persists. Eye Exposure... ............: Flush eyes with water for 15 minutes.Call a physician. If inhaled. .. ._.. ... ........: Remove-ta fresh air:Get medical attention if irritation persists. TMATERUL SAFETY DATA SHEET (MSDS) -Health Hazards: No known acute health hazards.No known chronic health hazards. Nuisance dust may require use of dust mask and safety glasses.Gloves are recommended. Carcinogenicity: N/A Routes of Entry: Inhalation/Skin/Ingestion Signs and Symptoms of Exposure: None serious.Temporary skin irritation may result from prolonged exposure. Medical Conditions Aggravated by Exposure: None Known Emergency-and First Aid Procedures: Wash thoroughly with soap and water after handling. Ingestion can cause nausea or vomiting. If ingested,give large amounts of water and call a physician. mum Steps to be taken incase material is released or spilled: Shovel uplarge spills for use or disposal.Sweep up- small spills. Waste Disposal Method: Handle like any natural fertilizing material.Dispose of in accordance with local,state and federal regulations. Disposal in waterways or sensitive areas should be avoided. Precautions to be-taken in Handling and Storage: Store in a dry place. Other Precautions: Proper precautions are advised to prevent infection of open wounds,inhalation of excessive amounts of dust,eye irritation and ingestion. Colitrol Measures Section Vill Respiratory Protection{Specify): Standard respirator for dust. Local Exhaust Ventilation: Open windows and doors as needed. Mechanical Ventilation(General): Roof or wall exhausters as needed. Protective-Gloves: Ordinary work gloves or rubber gloves. Eye Protection: Safety glasses as needed. Other Protective Clothing or Equipment: Ordinary protective clothing. Work/Hygenic Practices: Wash thoroughly with soap and water after-handling. o er hygienic practices is advised to prevent Use of r U Yg proper possible health hazards from any naturally occuring substance such as fertilizers,soil,composts,etc. "Page L" MATERIAL SAFETY DATA SHEET (MSDS) section IF a• - Manufactured/Distributed By: Product Name: Down To Earth Distributors,Inc. Down To Earth Fish Bone Meal 3-16-0 150 Shelton McMurphey Blvd Eugene,OR 97401 Emergency Telephone:1-800-234-5932 -Date Prepared: Information Telephone: 1-800-234-5932 1129/2008 Section If s Hazardous Components:(Specific chemical identity,common-names)OSHA PEL/ACGIH TLV/Other Recommended/%(optional) No direct hazardous components are known. Down To Earth Fish Bone Meal 3-16-0 is comprised of clean,steamed fish bones. Formula: N/A Boiling Point- N/A Specific Gravity(H2O=1).- N/A Vapor Pressure(mm Hg): N/A Melting Point: N/A Vapor Density(Air=1): N/A Evaporation Rate(Butyl Acetate= 1): N/A Solubility in Water: N/A pH: N/A Appearance&Odor-: White to light gray fine powder. Mild to strong marine odor. Sectimi IN' Fire and Explosion Hazard Data:' Flash Point(Method Used): Non-Flammable Flammable Limits/LEL/UEL: N/A Extinguishing Media: Water Spray Special Fire Fighting Procedures: Use standard self contained breathing apparatus. Unusual-Fire and Explosion-Hazards: No acute hazard Data Stability: Stable Incompatibility(Materials To Avoid): None Known Hazardous Polymerization: Will Not Occur Hazardous Decompositions or-Byproducts: None-Known Conditions-to Avoid: -None Page 1 4 DOT PRIMARY/SECONDARY LABEL: N!A DOT PRIMARY/SECONDARY PLACARD: N/A DOT EMERGENCY RESPONSE GUIDE#: N/A SECTION 15-REGULATORY INFORMATION CERCLA REPORTABLE QUANTITY: Not listed SARA TITLE III STATUS: immediate Health 311i31-2 Hazard-Categories— 313 Toxic Chemicals— None known CALIFORNIA PROP 65: Not listed SECTION 16-OTHER INFORMATION HEALTH 2 HMIS FLAMMABILITY 0 HAZARD pHYSICAL HAZARD 1 RATINGS 4=Severe 3--Serious 2=Moderate 1=Slight O=Minimal DISCLAIMER: The information presented herein is based on available data from reliable sources and is correct to the best of Ambrand's knowledge. Ambrands makes no warranty, express or implied, regarding the accuracy of the data or the results obtained from the use of this product. Nothing herein may be construed as recommending any practice or any product in violation of any law or regulations. The user is solely responsible for determining the suitability of any material or product for a specific purpose and for adopting any appropriate safety precautions. REVISED DATE: September21,2012 REFERENCE:- Initial release 3 SECTION 11 -TOXICOLOGICAL INFORMATION ACUTE TOXICITY: Oral LD50 (rat) ->5,000 mg/kg Dermal L050(rat) -> 5,000 mg/kg (male) Inhalation LC50(rat) ->5.0 mg/L Eye Irritation(rabbit) -Mild Skin Irritation(rabbit) -Minimal Sensitization(guinea pig) -Non-sensitizer CARCINOGEN STATUS: OSHA-Not listed NTP-Not listed IARC-Not listed MUTAGENIC.DATA: No evidence of mutagenic effects during in vivo or in vitro studies. ADDITIONAL DATA: None SECTION 12-ECOLOGICAL INFORMATION ENVIRONMENTAL SUMMARY: Do not apply directly to water,to areas where surface water is-present or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing of equipment washwaters. FISH TOXICITY:(Glyphosate acid) 96 hour Lc50, Rainbow trout—8.2 mg/L 96 hour Lc5o, Bluegill—5.8 mg/L AVIAN TOXICITY: (Glyphosate acid) Oral-Ow, Bobwhite quail—>3,800 mg/Kg Oral LDw, Mallard duck—Unknown BEE: Non-toxic SECTION 13-DISPOSAL CONSIDERATIONS Do not contaminate water, food,or-feed by storage or disposal. WASTE:Wastes resulting from the use of this product that cannot be-used or chemically reprocessed should be disposed of in a landfill approved for pesticide disposal or in accordance with applicable Federal, state or local procedures.-Emptied container retains vapor and product residue. CONTAINER DISPOSAL: If empty: Do not reuse container. Place in trash or offer for recycling if availabie!f partly filled:Your local government may forbid pesticides in their landfills. Therefore,call your locat-solid waste agency for disposal instructions. Never place unused product-down any indoor-or outdoor drain. SECTION 14-TRANSPORT INFORMATION DOT SHIPPING DESCRIPTION: Not regulated by DOT DOT HAZARD CLASS: N/A UN NUMBER: N/A DOT PACKING GROUP: N/A r 2 SECTION 6-ACCIDENTAL RELEASE MEASURES Clean up spills -immediately, observing precautions in Section 8 of this document. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. SMALL SPILL: Absorb small spills on sand, vermiculite or other inert absorbent. Place contaminated material in appropriate container for disposal. LARGE SPILL: Dike large spills using-absorbent or impervious material such as clay or sand. Recover and contain as much free liquid as possible for-reuse. Allow absorbed material to solidify, and scrape up for disposal. After removal, scrub the area with detergent and water and neutralize with dilute alkaline solutions of soda ash, or lime. Wear appropriate personal protection equipment. (See Section 8 Exposure Controls, Personal Protection). SECTION 7-HANDLING AND STORAGE KEEP OUT OF REACH OF CHILDREN! HANDLING: Use only in a well-ventilated area.Wear appropriate safety equipment when handling. STORAGE: Store in original container with lid tightly closed. Keep away from food,feed and drinking water. SECTOION 8-EXPOSURE CONTROLS PERSONAL PROTECTION EXPOSURE LIMITS-(8 hour TWA,ppm): Refer-to Section 3. ENGINEERING'CONTROLS: Proper ventilation is required when handling or using this product to keep exposure to airborne contaminants below the exposure limit: Local mechanical exhaust-ventilation may be required. Facilities storing or utilizing this-material should be equipped with aneyewash facility and a safety shower. PERSONAL PROTECTIVE-EQUIPMENT: EYE PROTECTION-Safety-glasses CLOTHING—Long-sleeved shirt and-long pants, Shoes plus socks, GLOVES—Waterproof gloves. hands before eating,drinking, chewing gum,using tobacco or using USER SAFETY RECOMMENDATIONS:Wash the toilet. Remove clothing immediately if pesticide gets inside.Then wash thoroughly and put on clean clothing.- SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL DESCRIPTION: Clear liquid. ODOR: None SPECIFIC GRAVITY: 1.01 g/ml(8.5 Ib/gi) pH: 6.5—7.5 VAPOR PRESSURE: Unknown VAPOR DENSITY: Unknown WATER SOLUBILITY:Soluble SECTION-10-STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable, however-may decompose-if heated. CONDITIONS TO AVOID:Avoid temperatures above(115°F,46°C)and below 25°F(-5°C). INCOMPATIBILITY WITH OTHER MATERIALS:-Strong oxidizers or bases, mild and-galvanized steel. HAZARDOUS DECOMPOSITION-PRODUCTS: Carbon monoxide, Nitrogen oxides, phosphorous oxides. HAZARDOUS POLYMERIZATION: Product will not undergo polymerization. OnTACQU IRA r`ADCPIAIATC 1AK1UVn0fN1IC Al I f_0AnCC1 1 MATERIAL SAFETY DATA SHEET SECTION 1 -CHEMICAL PRODUCT AND COMPANY IDENTIFICATION COMPANY ADDRESS: EMERGENCY&PRODUCT INFORMATION TELEPHONE NUMBER: Ambrands (800)265-0761 2030 Powers Ferry Road, Ste 370 Atlanta, Georgia 30339 -PRODUCT NAME :AMDRO°-PowerFlex Weed&Grass Killer CHEMICAL NAME : Isopropylamine Salt of Glyphosate CHEMICAL FAMILY : Herbicide PRODUCTCODE : EPA Reg.No.42750-67-73342 SECTION 2-COMPOSITION.INFORMATION OF INGREDIENTS COMPONENT PERCENTAGE CAS NUMBER OSHA PEL ACIGH TLV isopropylamine Salt 25.0% 38641-94-0 NOT EST NOT EST of Glyphosate* Inert Ingredients 75.0% n/a n/a n/a SECTION 3--HAZARDS IDENTIFICATION SUMMARY (As defined by OSHA-Hazard Communication Standard,29 CFR 1910,1200) HEALTH HAZARDS: Slight eye irritant. PHYSICAL HAZARDS: May react with metals such as galvanized or mild steel to produce hydrogen gas which could form-a highly combustible gas mixture. ENVIRONMENTAL-HAZARDS: Moderately toxic to fish and aquatic pants. May be toxic to non-target plants. SECTION 4-FIRST AID MEASURES IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing-eye. Call a poison control center or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. -SECTION 5-FIREFIGHTING MEASURES FLASH POINT-(method).WiA_notflash. FLAMMABLE LIMITS: Not-Established- FIRE AND EXPLOSION HAZARD: May-decompose in fire due releasing irritating or toxic gases. EXTINGUISHING_MEDIA: Use water spray,foam or dry chemical. FIGHTING INSTRUCTIONS: -Evacuate area and fight fire upwind from a safe distance to avoid hazardous vapors and decomposition-products. Foam or dry=chemical extinguishing systems recommended to prevent environmental damage due-to water run-off. FIREFIGHTING EQUIPMENT: Self-contained breathing apparatus with full facepiece. Full firefighting turn-out gear (Bunker gear). HAZARDOUS COMBUSTION PRODUCTS:-Carbon monoxide, nitrogen oxides, phosphorus oxides. POTASSIUM CARBONATE (ANHYDROUS ALL GRADES) MSDS No.: M1252 Rev. Date: 2010-June-15 Rev. Num. 01 ECOLOGICAL HAZARDS: May increase pH of waterways and adversely effect aquatic life. PRECAUTIONARY STATEMENTS: Wash skin and contaminated clothing thoroughly after handling. Wear protective gloves, protective clothing,eye, and face protection. Do not eat, drink or smoke when using this product. Avoid release to the environment. xxxtxxxxxxx*frxxxx*xxxxxxxxr.txxxxxxxxxxxxxxxxxtxxxxtxtxxxxxxxc-i.xxxexxrxxxrr*xtre�rxxxxx+tx*c�xtxtkxrteeirxxex'txx+r*xir*xx�rexxaxtxx*xxx,�xirmx POTENTIAL HEALTH EFFECTS: Inhalation: Not acutely toxic by inhalation. Skin contact: Substance may cause slight skin irritation. Eye contact: May cause eye irritation, which if untreated, can be severe and permanent. Ingestion: Ingestion may cause irritation and burns from the mouth to the stomach.ingesting massive amounts may cause ulcerations, vomiting, and death from shock. Chronic Effects: Repeated or prolonged contact may result in dermatitis. See Section 11: TOXICOLOGICAL INFORMATION 3. COMPOSITIONANFORMATION ON INGREDIENTS Component Percentage CAS Number Potassium Carbonate 98.5- 100 584-08-7 4. FIRST AID MEASURES INHALATION: If adverse effects occur, remove to uncontaminated-area. Give artificial respiration if not breathing-If breathing is difficult, oxygen should be administered by qualified personnel. If respiration or pulse has stopped, have a trained person administer basic life support(Cardio-Pulmonary Resuscitation and/or Automatic External Defibrillator)and CALL FOR EMERGENCY SERVICES IMMEDIATELY. SKIN CONTACT: Immediately brush off excess chemical and flush with plenty of-soap-and water. Remove contaminated clothing,jewelry, and shoes immediately. Remove contaminated clothing and gloves, and decontaminate or discard before reuse. Discard footwear which cannot be decontaminated. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. EYE CONTACT: Immediately flush with plenty ofwater. After initial flushing,-remove any contact lenses and continue flushing for at least 15 minutes. Washing eyes within several seconds is essential-to achieve maximum effectiveness. GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: If swallowed, DO NOT INDUCE VOMITING, Rinse mouth. Give water. Never give anything-by-mouth to an unconscious or convulsive person. if vomiting occurs spontaneously,-keep airway-clear. GET-MEDICAL ATTENTION IMMEDIATELY. Laguna Clay Company www.Lag u naclay.corw 1-800-4Laguna info@Lagunaclay.com- Print date: 15-June-2010 2 of 7 Distributed by: Laguna Clay Company 14400 I omitas Ave City of Industry,CA 91746 1-800-41-aguna coMPMV info@lagunaclay.com CLAY www.lagunaciay.com SAFETY DATA SHEET POTASSIUMm CARBONATE (AN-HYDROUS ALL GRADES) MSDS No.:M125-2_ Rev. Date: 2010-June-15 Rev.Num. 01 1. CHEMICAL,PRODUCT AND COMPANY IDENTIFICATION Company Identification: Armand Products Company 469 North Harrison Street North Harrison Street, NJ 08543-5297 24 Hour Emergency Telephone 1-800-733-3665 or 1-972-404-3228 (U.S.); 32.3.575.55.55 (Europe), 1800-033-111 Number: (Australia) To Request an MSDS: MSDS@oxy.com or 1-972-404-3245 C-ustomer Service: 1-800-522-0540 or 1-609-683-590D Trade-Name: Potassium Carbonate Extra Fine; Potassium Carbonate Glass; Potassium Carbonate Dense Granular; Potassium Carbonate Fine Synonyms: Pearlash, Potash,PotCarb Product Use: Glass manufacture,-Photographic, Detergents/soaps, Fertilizer*, Rubber products, Pharmaceuticals. Potassium Silicates, Food processing, Gas Treatment, Agricultural Chemicals, Cement, Catalysts Notes: *In states where registered. Check with State Department of Agriculture 2. HAZARDS IDENTIFICATION ***#**#****#********3**#**#****fr#***#*#******************1F**#***#*tt*#*************#***R*******7c****tktk**fetk***#**#**#***#*********1!#******* EMERGENCY OVERVIEW: Color: White ,physical State: Granular powder Appearance: Free-flowing, Granular Signal Word: WARNING MAJOR HEALTH-HAZARDS: HARMFUL IF SWALLOWED. CAUSES SERIOUS EYE IRRITATION_ CAUSES SKIN IRRIT,ATION. AQUATIC TOXICITY: Harmful to aquatic life. Print date: 15-June-2010 1 of 7 POTASSIUM CARBONATE (ANHYDROUS ALL GRADES) MSDS No.: M1252 Rev. Date: 2010-June-15 Rev. Num. 01 Skin-and Body Protection:.Contaminated clothing should be removed, then discarded or laundered. Discard contaminated leather goods.Wear protective clothing to minimize skin contact. When potential for contact with wet material-exists, wear Tychem®or similar chemical protective suit. Hand Protection:Wear appropriate chemical resistant gloves. Protective Material Types: Butyl rubber, Natural rubber, Neoprene, Nithle Respiratory Protection: A NiOSH approved respirator with high efficiency particulate air(HEPA)cartridges may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits, or when symptoms have been observed that are indicative of overexposure. When an air purifying respirator is not adequate for spills and/or emergencies of unknown concentrations, an approved self-contained breathing apparatus operated in the pressure demand mode is required. A respiratory protection program that meets 29 CFR 1910.1-34 must be followed whenever workplace conditions warrant use of a respirator. 9. ITHYSICAL AND CHEMICAL PROPERTIES Physical State: Granular powder Appearance: Free-flowing, Granular Color: White Molecular Weight: 138.21 Molecular Formula: K2CO3 Melting Point/Range: 1636 °F (891 °C) Specific Gravity(water-1): 2.428 @ 19 (°C) Density: 1201 - 1330 g/L(granular); 560-625 g/L (ground) @ 20 °C Bulk Density: 75-83 Ib/ft3 (granular; 35-39 bl/fit3 (ground)@ 20 °C Water Snhjhility- ion% POTASSMd CARBONATE (ANHYLG GUS ALL R O ES) 1,&30S V,,fo.: 101252 Rev.Date: 2010-June-15 Rev. Rum. 01 FIRE-FIGHTING MEASURES Fire Lazard: Negligible fire hazard. Extinguishing Media: Use extinguishing medium as appropriate for surrounding fire. Fire Fighting: Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by- products. Stay upwind and keep out of low areas. Sensitivity to Mechanical impact: Not sensitive. Sensitivity to Static: Discharge: Not sensitive. Flash point: Noz flammable 6. ACCIDENTAL RELEASE MEASURES Occupational release: Wear appropriate personal protective equipment recommended in Section 8 of the SDS. Shovel dry material into suitable container. Flush spill area with water, if appropriate. Keep out of water supplies and sewers. Releases should be reported, if required, to appropriate agencies. 7. HANDLING AUTO STORAGE Storage Conditions: Store and handle in accordance with all current regulations and standards. Keep container tightly closed and properly labeled. Granular material is slightly hygroscopic, ground material is very hygroscopic. Store in a cool, dry area. Keep separated from incompatible substances (see section 10 of the Safety Data Sheet). Handling Procedures: Avoid breathing dust. When, using, do not eat, drink or smoke. Wash thoroughly after handling. Do not reuse containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Regulatory Exposure limit(s): None Recommended Exposure Limit: 2 mg/m3 recommended Time Weighted Average 8 hour(internal Occupational Exposure Limit) (Inhalable Particulate). ENGINEERING CONTROLS: Provide local exhaust ventilation where dust or mist may be generated. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT: Eye Protection: If eye contact is likely, wear chemical resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Laguna Clay Company www.Lagunaclay.com 1-800-4Laguna info a@Lagunaclay.cor Print date: 15-June-2010 3 of 7 POTASSIUM CARBONATE (ANHYDROUS ALL GRADES) MSDS No.: M1252 Rev. Bate: 2010-June-15 Rev. Nuen. 01 ECOLOGICAL HAZARDS: May increase pH of waterways and adversely-effect aquatic life. PRECAUTIONARY STATEMENTS: Wash skin and contaminated clothing thoroughly after handling.Wear protective gloves,protective clothing,eye, and face protection.Do not eat, drink or smoke when using this product.Avoid release to the environment. POTENTIAL HEALTH EFFECTS: Inhalation: Not acutely toxic by inhalation. Skin contact: Substance may cause slight skin imitation. Eye contact: May cause eye irritation,which if untreated,can be severe and permanent. Ingestion: Ingestion may cause irritation and burns from-the mouth to the=stomach. Ingesting massive amounts may cause ulcerations, vomiting, and death from shock. Chronic Effects, Repeated or prolonged contact may result in dermatitis. See Section 11: TOXICOLOGICAL INFORMATION 3. COMPOSITION/INFORMATION ON INGREDIENTS component Percentage CAS Number Potassium Carbonate 98.5- 100 584-08-7 4. FIRST AID MEASURES -INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult; oxygen should be administered by qualified personnel. if respiration or pulse has stopped, have a trained person administer basic life support(Cardio-pulmonary Resuscitation and/or Automatic External Defibriliator)and CALL FOR EMERGENCY SERVICES IMMEDIATELY. SKIN CONTACT: Immediately brush off excess chemical and flush with plenty of soap and water. Remove contaminated clothing,jewelry, and shoes immediately. Remove contaminated clothing and gloves, and decontaminate or discard before reuse. Discard footwear which cannot be decontaminated. IF IRRITATION OCCURS,GET MEDICAL ATTENTION. -YE CONTACT: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue -flushing for at least 15 minutes. Washing eyes within several seconds is-essential to achieve maximum effectiveness. GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: If swallowed, DO NOT INDUCE_VOMITING. Rinse mouth. Give water. Never give anything by mouth to-an unconscious or convulsive person. If vomiting occurs spontaneously, keep airway clear. GET MEDICAL ATTENTION iMMEDIATEL-Y. Laguna Clay Company rmw.Lagunaelay.com 1-800-41-agma info@Laguneciay.com Print date: 15-June-2010 2 of 7 Distributed by: Laguna Clay Company 14400 Lomitas Ave- City of Industry,CA 9f746 ® 1-800-41-aguna MPaNv in @lagunaciay om ciay omcv,Al V SAFELY DATA SHEEN POTASSIUM CARBONATE (AN-HYDROUS ALL GRACES) MSDS No.:M1252 Rev. Date: 2010-June-15 Rev.Num. 01 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Company Identification: Armand Products Company 469 North Harrison Street North Harrison Street, NJ 08543-5297 24 Hour Emergency Telephone 1-800-733-3665 or 1-972-404-3228(U.S.); 32-3.575.55.55(Europe);-1800-033-111 Number: (Australia) To Request an MSDS: MSDS@oxy.com or 1-972-404-3245 Customer Service: 1-800-522-0540 or 1-609-683-5900 Trade Name: Potassium Carbonate Extra Fine; Potassium Carbonate Glass; Potassium Carbonate Dense Granular; Potassium Carbonate Fine Synonyms: -Pearlash, Potash, PotCarb Product Use: Glass manufacture, Photographic, Detergents 1 soaps, Fertilizer*, Rubber products, Pharmaceuticals,-Potassium Silicates, Food processing, Gas Treatment, Agricultural Chemicals, Cement, Catalysts Notes: *ln states where registered. Check with State Department of Agriculture 2. HAZARDS IDENTIFICATION EMERGENCY'OVERVEEW Color: White Physical State: Granular powder Appearance: Free-flowing, Granular SWnal Word: WARNING MAJOR HEALTH HAZARDS: HARMFUL IF SWALLOWED. CAUSES SERIOUS EYE IRRITATION._CAUSES SKIN- IRRITATION. AQUATIC TOXICITY: Harmful to aquatic life. Print date: 15-June-2010 1 of 7 Material Safety Data-Sheet Date prepared: 21'February 2003 Date revised: 17 h April 2007 16. tether Information Recommendations/restrictions: It is important to follow the instructions detailed in the Product Data sheet. If this Droduct is for resale-,ensure that the purchaser receives a copy of this information. The information herein-is believed to be correct as of the date hereof but is provided without warranty of any kind. The recipient of our product is responsible for ensuring that, where applicable,existing laws and guidelines are observed. MiteX MSDS . 4 - Material Safety Data Sheet Date prepared: 21�' reFJraary 2003 Date revised: 17t''April 2007 13 Disposal Considerations Disposal must be in _accordance with local and national legislation. Dispose of through an authorised waste contractor to a licensed site. Provided care is taken to inhibit a-bome dust,normal factory disposal procedures may be employed using skips and tips, then landfill. Spillages may be swept up. The use of water is et recommended;surfaces coated with wet material would be a slipping hazard. 14. Transport information No special precautions,other than dry conditions,are necessary. 15. Regulatory information LABEL FOR SUPPLY: None RISK PHRASES: None. However,workers should be Informed of the presence of crystalline silica and be trained in the proper use and handling of this product as required under applicable regulations. SAFETY PHRASES: S22 Do not breathe dust S26 In case of contact with eyes,rinse immediately with plenty of water S36 Wear suitable protective clothing (susceptible persons and in dusty conditions) STATUTORY INSTRUMENTS: Health and Safety at Work Act 1974. Chemicals(Hazard information and Packaging for supply) Regulations 1994. Control of Substances Hazardous to Health Regs 1988(Si 1657). Environmental Protection Act 1990. CODES OF PRACTICE: Waste management: The duty of care. GUIDANCE MOTES: Health and Safety Executive:- Occupational exposure limits(EH 40/94) Classification, Packaging and Labelling of Dangerous Substances Regulations 1984 MiteX MSDS - 3 - Material Safety Data Sheet Date prepared: 211 February 2003 Date revised: 17tn April 2007 a. Exposure Controls Engineering measures: N/A Control Parameters: None Personal protection equipment: At high dust levels andior=workers=suffer from dermatitis or sensitive skin S36 Wear suitable protective clothing 9. Physical and chemical properties Appearance: Beige/Grey powder Odour. None PH --pH 4:5 Boiling point: N/A Melting point: >10000 C Flashpoint: N/A Explosive properties: Non-explosive Vapour pressure: NIA Density: 325 gA Solubility: Generally insoluble in common solvents 10. Stability and reactivity MiteX is chemically inert to all fluids with the exception of hydrofluoric acid. Conditions to avoid: None Materials to avoid: Hydrofluoric acid 11. Toxicological information Non toxic. Excessive exposure to dust may affect susceptible persons as follows: Skin contact: Mild irritation Eye contact: Mild irritation 12. Ecological information MiteX is an environmentally compatible material. mitex MSDS - 2 - Material Safety Data Sheet Date revised: 17'h April 2007 1� Identification of the Preparation: and the Company Substance or preparation trade name- MiteX Unique reference numbers(s): Company/undertaking narne&address: /Agil Hercules 2,Calleva Pa* Aldermaston, READING RG7 8DN,England Telephone: +44 118 9813333 Fax: +44 118 9810909 Emergency telephone number: +44 1488 608178 +44 118 9474407 2. Composition Substance: Kieselgur--Purified silicate mineral(E 551c) CAS Number: 61790-53-2 3. Hazards Identification None. However,MiteX does contain free silicates. Ensure that atmospheric dust levels are maintained such that the amount of respirable silicates in the atmosphere is<0.4 mg/M3. Long-term exposure to excessive levels of any mineral dust can lead to respiratory problems. 4. First aid measures Eye contact: S26 In case of contact with eyes,rinse immediately with plenty of water Inhalation: If strong inhalation of dust occurs it is recommended to clear the airways 5. Fire fighting measures Non-flammable 6. Accidental release measures Personal precautions: Wastes are not classified as hazardous Environmental precautions: None 7. Handling and storage Handling: Common care and ensure low dust levels. Storage: Store in clean dry conditions. Keep container closed and ensure label is intact and legible. 8. HANDLING PRECAUT110NS: EXPOSURE LIDELINE: ti'ENT'TLATION: Local mechanical exhaust ventilation at the point of use. RESPIRATORY PROTECTION: NIOSH-Approved dust and vapor respirator or mask in the absence of adequate environmental controls at the point of use. PROTECTIVE CLOTHING: Long-sleeved shirt,trousers,safety shoes and gloves. EYE PROTECTION: Chemical goggles. OTHER PROTECTIVE MEASURES: An eyewash and safety shower should be nearby and ready for use. Conditions to Avoid: Water-of crystallization from applicable-components driven off at approximately 235'Fahrenheit/ 113'Celsius. Materials to Avoid: Solutions can be corrosive to metals. Avoid strong oxidizingand reducing agents. Hazardous Decomposition Products: None. . ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS OR,LEAKS: Wear protective-equipment, including rubber boots,rubber gloves,rubber apron and chemical goggles. For small- spills,sweep up and dispose of in DOT-approved waste-containers. Comply with all applicable governmental regulations-on spill reporting, and handling and disposal of waste. 6. FIRST AID: IF INHALED: Remove-to mesh air. IN CASE OF EYE CONTACT: Flush eyes with a lot of running water. IN CASE OF SKIN CONTACT: Wash_skin.with lots of soap and water. Remove contaminated clothing and shoes. Get medical attention if irritation persists. IF SWALLOWED: Do notinduce vomiting. Consult-a physician. 7. HEALTH HAZARD INFORMATION: PRIMARY ROUTES OF EXPOSURE: Skin or ey-contact,swallowed. SIGNS AND SYMPTOMS OF EXPOSURE: Eye Contact: May moderately irritate eyes. Skin Contact: May irritate damp skin. Swallowed: Swallowing-may result in abdominal discomfort. CHRONIC EFFECTS OF EXPOSURE: No specific information available. MEDICAL CONDITIONS AGGRAVATED BY-EXPOSURE None known. MSS SHEETS PRODUCT NAME: LIQUID KAPUMA 1. INGRED ENTS: Dolomite,potassium carbonate:fish meal,seaweed extract, magnesium sulfate,humic acid(derived fro leonardite shale),water soluble vitamins. L PHYSICAL DATA: Physical Form: Liquid Boiling Point: i00°C Vap Press: N/A Vap Density: N/A Sol in Water: Appreciable Evaporation Rate: N/A Appearance: Dark,coffee-colored liquid Odor: Slight organic odor 3. FIRE AND EX PLOSION HAZARD DATA: Flash Point: N/A Method Used: N/A FLAMMABLE LIMITS: LFL: N/A UFL: N/A EXTINGUISHING MEDIA: This product-is not combustible. Use any appropriate -medium for extinguishing surrounding-fires. 4-REACT WI T'Y DATA: STABILITY: Stable. POLYMERIZA'I`ION: Will not occur. HYDRO-ORGANICS tfi,gq0LESALE,11W— MATERIAL DATA SAFETY SHEET REVISED=17109 EARTH JUICE PRODUCTS SEC'110N 1: GENERAL INFORMATION PRODUCT NUM3ER:F08302-F08308 PRODUCT NAME:EARTH;JUICE Hl BRIX 0-0-3 CHEMICAL NAME AND SYNONYMS:NA PRECAUTIONS:Avoid prolonged contact with eyes,skin.Will stain clothing. SECTION 11, HAZARDOUS INGREDIENTS Not Applicable This product is not n DOT hazardous material. SECTION III; PHYSICAL/CHEM!!,: L DATA BOILING POINT: VERY HIGH %VOLATILE BY VOLUME:NO DATA VAPOR DENSITYIN AIR: WATER VAPOR ONLY VAPOR PRESSURE(MM HG):LOW SOLUBILI^'!N WATER: SOLUBLE SPECIFIC GRAVITY(1-120-1):1.45 pH:2.25 TO 6.0 APPEARANCE AND ODOR:Dark broyvn syrupy liquid,sweet smell SEC T IOIV IY; FIRE Abig EXPLOSION DATA FLASH POINT(method used):Non flammable,non combustible FLAMMABLE LIMITS IN AIR:Non flammable,non combustible EXTINGUISHING MEDIA:NA UNUSUAL FIRE EXPLOSION HAZARDS:Fermentation occurs when diluted with water and is accelerated by heat. During fermentation,carbon monoxide with possible traces of ethanol or volatile fatty acids(e.g.,acetic,propionic,lactic,or butyric)is given off,which produces inhalation hazards and possible explosion,hazards.This material should be stored in a vented tank desiwned to contain a material with a specific gravity of 1.3 or greater. Material can ferment if excessive moisture contamination is allowed. SECTION V. REACTIVITY DATA STABILITY:Stable-Avoid excess moisture,heat or unventila�led containers HAZARDOUS POLYMERiZATION:NA HAZARDOUS DECOMPOSITION PRODUCTS:Carbon Monoxide,alcohol or fatty acid vapor INCOMPATIBILITY:Reads with concentrated nitric acid or concentrated sulphuric acid. Ferments when diluned with water. SECTION VI: HEALTH HAZARD DATA EFFECTS OF EMERGENCY AND FIRST AID PROCEDURES: EYES: Avoid contact with eyes.Flush eyes with water for 15 minutes.SKIN: Wash off.AAh soap water.Use nibber gloves wheri handling product. INHALATION:If vapor or mist causes irritation or distress,remove to fresh air. INGESTION: No Data RESPIRATORY PROTECTION:None SECTION /I,: SPILL.LEAK,LAND DISPOSAL PROCEDURES Contain spills.Absorb with commercial or other absorbent material and shovel into container for proper disposal.Prevent spill from entering a waterway or sewer.For large spills,dike and mop up or pump material into a container(metal or plastic)for proper disposal at an approved facility such as a municipal landfill or land application site. If solid crystals form as the material cools,add water to help with dean up.Prevent releases to land or water.If spill could potentiaily enter any waterway such as small creeks, contact local authorities. For navigable waterways,contact the US coast Guard National Response Center 800-4246802. Notify as appropriate,federal,state and local agencies. Results in high Biological Oxygen Demand(BOD)and potential oxygen depletion of aquatic systems.Discharges to a waterway of the U.S.are regulated by the Environmental Protection Agency. SECTION Vlll-, SPECIAL PRECAUTIONS Do not add water to container of concentrate. Avoid overheating or freezing. Other Precautions: Wash thoroughly after handling. NEITHER THIS DATASHEET NOR ANY STATEMENT CONTAINED.HEREIN GRANTS OR EXTENDS ANY LICENSE, EXPRESSED OR IMPLIED,IN CONNECTION WITH PATENTS ISSUED OR PENDING WHICH MAY BE THE PROPERTY OF THE MANUFACTURER OR OTHERS.THE INFORMATION'N THIS SHEET HAS BEEN ASSEMBLED BY THE MAt4UFACTURER BASED ON ITS OWN STUDIES AND ON THE WORK OF OTHERS.THE MANUFACTURER MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,AS TO THE ACCURACY,COMPLETENESS,OR ADEQUACY OF THE INFORMATION CONTAINED HEREIN.THE MANUFACTURER SHALL NOT BE LIABLE TO THE VENDEE,THE VENDEE'S EMLOY-EES,OR ANYONE-FOR ANY DIRECT,SPECIAL OR CONSEQUENTIAL DAMAGES ARISING OUT OF OR IN CONNECTION WITH THE ACCURACY, COMPLETENESS,ADEQUACY,OR FURNISHING OF SUCH INFORMATION. MHtrtrfMhlrtGliMlH�fYirtlhfkh�lMfMMfHM*dki#4Qfitv�H1#lMfcnii+ RAF�!litls'_YelfEAfG41h41Li646YMH114114fiilfK- Clean Water Act: None of the chemicals-in this product are listed as Hazardous Substances-under the CWA.None of the chemicals-in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA-. OSHA: None of the chemicals in this product are considered highly hazardous by-OSHA. STATE CAS#64-17-5 can be found-on the following state right to know lists: California,New Jersey,Pennsylvania, Minnesota, Massachusetts. CAS#7732-18-5 is not present on stateAsts from CA,PA,MN,MA,FL,-0r NJ. WARNING:This product contains Ethyl alcohol;a chemical known to the state-of California to cause birth defects-or other reproductive harm.California No Significant Risk Level:-None of the chemicals in this product are listed. Europeari International Regulations European Labeling in Accordance writh-EC-Directivees- Hazard Symbols: F Risk Phrases: R 11 Highly flammable.— Safety Phrases: S 16 Keep away from sources of-ignition-No smoking. S 33 Take precautionary measures against static- discharges. S 7 Keep container tightly-closed. S 9 Keep container in a well-ventilated place. WGK(Water Danger/Protection) CAS#64-17-5: 0 CAS#7732-18-5: No information available. Canada—DSL/NDSL CAS#64-17-5 Is-listed on Canada's DSL List. CAS#7732-18-5 is listed on Canada's DSL List. Canada-WHIMS This product has-a-WHMIS classification-of 82,D2A,D2B. Canadian Ingredient Disclosure list CAS#64-17-5 is listed on the Canadian Ingredient Disclosure List. Exposure Limits CAS#64-17-5: OEL-AUSTRALIA:TWA 1000=ppm(1900-mg/m3)OEL-BELGIUM:T WA 1000 ppm-(1880 mg/m3)OEL--CZECHOSLOVAKIA:TWA 1000 mg/m3;STEL 5000 mg/m3 OEL-DENMARK:TWA 1000 ppm(1900 mg/m3)OEL-1FINLAND:TWA 1000 ppm (1900 mg/m3);STEL 1250 ppm=(2400 mg/m3)OEL-FRANCE:TW -1000 ppm(190 -0 mg/m3);STEL5000-pp OEL-GERMANY:TWA 1000 ppm(1900 mg/m3)OEL-HUNG ARY:TWA 1000 mg/m3;STEL 3000 mg/m3 OEL-THE NETHERtANDS:TWA 1000 ppm 1900 mg/m3)OEL-THE PHILIPPINES:TWA-1000 ppm(1900 mg/nx3)-OELm-POLAND :TWA 1000 mg/m3 OEL-RUSSIA:STEL-1000 mg/m3OEL-SWEDEN:TWA 1000 ppm 1900 mg/m3)OEL-SWITZERLAND:TWA 1000 ppm(1900 mg/m3j OEL-THAILAND:T WA 1000 ppm(1900 mg/m3)OEL-TURKEY:TAiA 1000 ppm(1900 mg/m3)OEL-UN ITED KINGDOM:TWA 1000 ppm(1900 mg/m3)JAN9 DELIN-BULGARIA,COLOMBIA ,JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND,SINGAPORE,VIETNA M check ACGI TLV MSDS>Creation Date:4/17/2001 Revision*1 Date:4/17/2001 The Information,above-is believed to be accurate and represents the best-information currently available to us.However,we make no warranty of merchantability or any other warranty,express or implied,with respect to such Information,and we assume no l/abllity-resulting from its use. Users should make their own-investigations to-determine the suitability of the Information for. _their particular purposes.In-no event shall Rsher be liable for any-dalms,-Iosses,or damages of any third party or for lost pron"ts or any special,indirect,incidental,consequential or exemplary damages,howsoever arising,even if Rsher has been advised-of the possibility of such damages. gm/L_; Cytogenetic Analysis: Human, Fibroblast= 12000 ppm.;Cytogenetic Analysis: Human,Leukocyte= 1 pph/72H (Continuous).;-Sister Chromatid Exchange:_Human,Lymphocyte= 500 ppm/72H(Continuous). Other Studies:-Standard Draize Test(Skin, rabbit)=20 mg/24H (Moderate)S tandard Draize Test: Administration into the eye(-rabbit) =500 mg (Severe). LIM 300�OEM Ecotoxicity: Dish: Rainbow trout: LC50 = 1290.0-15300 mg/L;_96 Hr;Flow through @ 24-24.3°C Rainbow trout: LC50._ 11200-mg/L;24 Hr,Fingerling(Unspecified)ria: Phytobacterium phosphoreum: EC50=34900 mg/L; 5-30 min,, Microtox test When spilled on land it is apt to volatilize,biodegrade,and leach-into the ground water, but no data on the rates of these processes couldbe found.Its fate in ground wateris unknown.When released into water it will volatilize -and probably biodegrade.It-would not be expected to adsorb to sediment or bioconcentrate in fish. Environmental:When released—o-the atmosphere it will photodegrade in hours(polluted urban atmosphere)to an estimated range of 4 to 6 days in less polluted areas.Ralnout should be significant. Physical:No information available. Other: No information available. Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.Additionally,waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Serles:None listed. RCRA U-Series:None listed. Shipping Name: ETHANOL No infonnaflon available. Ha=Fd Class: 13 UN Number: UN1170 Packing Group: Ila US FEDERAL TSCA CAS#64-17-5 is listed on the TSCA inventory. CAS#7732-18-5 is listed on the TSCA inventory. Health&Safety Reporting List None of-the chemicals are on the Health&Safety Reporting List Chemlcal Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section-12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA CERCLA-Hazardous Substances and corresponding RQs None of the chemicals in this material have an RQ. SARA Section 302 Extremely Hazardous Substances None of the chemicals in this product have a TPQ. SARA Codes CAS#64-17-5: acute,-chronic,Flammable. Section 31.32 -No chemicals-are reportable under Section 313. Clean-Air Act: This material does not contain any hazardous air pollutants.This material does not contain any Class 1 Ozone depletors. This-material does not contain any Class 2 Ozone dep!etors. Clean-Water Act: w_ -, Physical State: Clear liquid Appearance:colorless Odor: Mild,rather pleasant,like wine or whis PH:Not available. Vapor Pressure:59.3 mm Hg @ 20 deg C Vapor Density:1.59 Evaporation Rate:Not available. Viscosity: 1.200 cP @ 20 deg C Boiling Point:78 deg C Freezing/Melting Point:114.1 deg C Decomposition TemperatureNot available. Solubility: Miscible. Specific Gravity/Density:0.790 @ 200C Molecular FOrmulaC2H5OH Molecular Weight:46.0414 Chemical Stability:Stable under normal temperatures and pressures. Conditions to Avoid:incompatible materials,ignition sources,excess heat,oxidizers. Incompatibilities wfth Other Materials:Strong oxidizing agents,acids,alkali metals, ammonia,hydrazine,peroxides, sodium,acid anhydrides,calcium hypochlorite,chromyl chloride,nitrosyl perchlorate,bromine pentafluoride,-perchioric acid, silver nitrate, mercuric nitrate,potassium-tert-butoxi-de,magnesium perchlorate,acid chlorides,platinum,uranium hexafluoride,silver oxide,iodine heptafluoride,acetyl bromide,disulfuryl difluorlde,tetrachlorosilane+water,acetyl chloride, permanganic acid, ruthenium(VIII)oxide,uranyl perchlorate,potassium dioxide. Hazardous Decomposition Products:Carbon monoxide,Irritating and toxic fumes and gases,carbon-dioxide. Hazardous Polymerization:Will not occur. r M RTECS*: CAS#64-17-5: KQ6300000 CAS#7732-18-5: ZC0110000 LD50/LC50: CAS#64-17-5: Draize test, rabbit,eye: 500 mg Severe; Draize test,rabbit,-eye: 500 mg/24H Mild; Draize test, rabbit,skin:20 mg/24H Moderate; Inhalation, mouse: LC50 =39 gm/m3/4H; Inhalation,rat: LC50= 20000 ppm/10H; Orel, mouse: LD50=3450 mg/kg; Oral, rabbit: LD50=6300 mg/kg; Oral,rat: LD50=9000 mg/kg; Oral, rat: LD50= 7060 mg/kg; CAS#7732-18-5: Oral, rat: LD50= >90 mL/kg; Carcinogenicity: CAS#64-17-5: ACGIH:A4-Not Classifiable as a Human Carcinogen CAS#7732-18-5: Not listed by ACGIH,IARC,NIOSH,NTP-,or OSHA. Epidemiology:Ethanol has been shown to produce fetotoxicity in-the embry o or fetus of laboratory_animals. Prenatal exposure to ethanol is associated with a distinct pattern-of co ngenital malformations that have coilecetively been termed the"fetal alcohol syndrome". Teratogenicity: Oral, Human-woman:TDLo=41 gm/kg (female 41 week(s)-after conception)Effects on Newborn- Apgar score(human only)and Effects on Newborn-other neonatal measures-or effects and Effects on Newborn-drug dependence. Reproductive Effects: Intrauterine, Human-woman:TDLo=-200 mg/kg(female 5-day(s)pre-mating)Fertility-female fertility index(e.g.#females pregnant per#sperm positive females; #females-pregnant per#-females mated). Neurotoxicity: No information available. Mutagenicity: DNA Inhibition: Human,Lymphocyte=220 mmol/L.; Cytogenetic Analysis: Human,Lymphocyte=i160 breathing is difficult,give oxygen Get medical aid. Do NOT use mouth-to-mouth resuscitation. Notes to Physicians Treat symptomatically and supportively. Persons with skin or eye disorders or liver,kidney, chronic respiratory diseases, or central and peripheral nervous sytem diseases may be at increased risk from exposure to this substance. Antidote: Replace fluid and electrolytes. General Information.Containers can build up pressure if exposed to heat andl fire.As in any fire,wear a se"-contained breathing apparatus In pressure-demand, MSHA./MIOSH(approved or equivalent),and full protective gear.Vapors may form an explosive mixture with air.Vapors can travel to a source of ignition and flash back.Will burn if Involved in a fire. Flammable Liquid.Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep`;re-exposed containers cool. Containers,may explode in the-heat of a fire. Extinguishing Media:For small fires,use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires,use water spray;fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.Water may be ineffective.DY NOT use straight streams of water. Flash Point: 16.6 deg C(61.88 deg F) Autoignition Temperature:363 deg C(685.40 deg F) Explosion Limits,Lower3.3 vol 9h Upper.,19.0 vol% MFPA Rating: (estimated)Health: 2; Flammability:3; Instability: 0 General information:Use proper personal protective equipment as indicated in Section 8. Spills;Leaks:Absorb spill with inert material (e.g.vermiculite,sand or earth),then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.A vapor suppressing foam may be used to reduce vapors. Handling:Wash thoroughly after handling.Use only in a well-ventilated area.Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment.Avoid contact with eyes,skin, and clothing. Empty containers retain product residue,(liquid and/or vapor),and can be dangerous.Keep container tightly closed. Avoid contact with heat, sparks and flame.Avoid ingestion and inhalation.Do not pressurize,cut,weld,braze,solder, drill, grind, or expose empty containersto meat, sparks or open flames. Storage: Keep away from heat,sparks, and flame. Keep away from sources of ignition. Store In a tightly closed container. Keep from contact with oxidizinu materials. Store In a cool,dry,well-ventilated area away from incompatible substances. Flammables-area..Do not store-near perchloratirs,peroxides,chromic acid or nitric acid. Engineering Contrais:Use explosion-proof ventilation equipment.Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits Eihyl atcohol 1000 plum TWA 10DI TW •1900 EWm3 A 3300 ppm IDI3i 11090=TWA;1900 mg1m3 TWA Water Incyne listed none listed I none listed OSHA Vacated PELs: Ethyl alcohol:1000 ppm TWA; 1900 rl TWA Water: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes:Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations In 29 CFR 1910.133 or European Standard EN166. Skin.,Wear appropriate protective gloves to prevent skin exposure. Clothing:Wear appropriate protective clothing to prevent skin exposure. Respirates:_A respiratory protection Program that meets_OSHA`s—Z9 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149-must be followed whenever workplace conditions warrant a respirator's use. Material Safety Data Sheet Ethyl Alcohol,70'l'o ACC#91791 40 NSDs Name-Ethyl Alcohol,701/6 Catalog Numbers:S7S119,575120,S556CA4 Synonyms:Ethyl Alcohol;Ethyl Hydrate; Ethyl Hydroxide; Fermentation Alcohol;Grain Alcohol; Methylcarbinol; Molasses Alcohol; Spirits of Wine. Company Identiffcation:- Fisher Scientific 1 Reagent.Lane Fair Lawn, NJ 07410 For;information,call:201-796-7100 Emergency_N u mber:201-79 6-7100- For CHENTREC assistance,cal1:800-424-9300 For International CHENTREC assistance,call 703-527-3887 SEE= 64-17-5 Ethyl alcohol 70 200-578-6 7732-18 5 = Water 3C 231-791-2 Hazard Symbols:F Risk Phrases:11 t. Iffig EMERGENCY OVERVIEW Appearance: colorless clear liquid.Flash Point: 16.6 deg C. Flammable liquid and vapor.May cause central nervous system depression.Causes severe eye irritation.Causes respiratory tract irritation.Causes moderate skin irritation. This substancehas caused adverse reproductive and fetal effects in humans. Warning!May cause liver, kidney and heart damage. Target Organs:Kidneys,heart,central nervous system, liver. Potential Health Effects Eye: Causes severe eye irritation. May cause painful sensitization to light. May cause chemical conjunctivltis and corneal damage. Skin:Causes moderate skin irritation.-May cause cyanosis of the extremities. Ingestion:May cause gastrointestinal irritation with nausea,vomiting and diarrhea.May cause systemic toxicity with acidosis.May cause--central nervous system depression,-characterized by excitement,followed by headache,dizziness, drowsiness,and nausea.Advanced stages may cause collapse,unconsciousness,coma and possible death due to respiratory failure. Inhalation:inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache,dizziness,unconsciousness and coma.Causes respiratory tract irritation. May cause narcotic effects in high concentration.Vapors may cause dizziness or suffocation. Chronic:May cause reproductive and-fetal effects. Laboratory_experiments have resulted in mutagenic effects.Animal studies have reported the development of tumors.Prolonged exposure may cause liver, kidney,and heart damage. R i _ t Eyess.Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.Gently lift eyelids and.flush continuously with water. Skin:Get medical-aid. Flush skin with-plenty of water for at least 15-minutes while removing contaminated clothing and shoes.Wash clothing before reuse-. Flush skin with plenty of soap and water. Ingestion:Do NOT-induce vomiting.If--victim is conscious and alert,give 2-4 cupfu;s of milk or water. Never give anything by mouth to an unconscious person.Get medical aid. Inh_lation: Remove frog exposure and move to fresh air immediately`If not breathing,give artificial respiration. If MSDS Page 3 Other precautions: Wash thoroughly after handling. Do not get in-eyes; on skinor clothing do not breathe mist. SECTION X—DOT iNFORMATIGN-AND DATE DOT Classification and Label: Not required by DOT MSDS Page 2 Flash Point (Specify Flammable Limits Lovear Upper Method/Degrees F) i % by Volume N/A N/A Fire Extinguishing Media: Use that which is appropriate for the surroundin fire. I ISpecial Fire Fighting Procedures: Wear bunker gear& a self-contained breathing apparatus... SECTION V— HEALTH HAZARD DATA Effects of Overexposure: May irritate sensitive individuals if on skin for prolonged period of time. Emergency and First Aid Procedures: If Swallowed: Do not induce vomiting, get medical attention. If on Skin: Flush with soap and water, remove and launder contaminated clothing. If in Eyes: Flush with plenty of water for at least 15 minutes. If Inhaled: Remove to fresh air. SECTION VI— REACTIVITY DATA Stability Unstable Conditions to Avoid Stable X I N/A Incompatibility (Materials to Avoid): None Known Hazardous Decomposition Products: None Known Hazardous ��!fll'MotcOccur Conditions to Avoid Polymerization X N/A SECTION VII —SPILL OR LEAK PROCEDURES Steps to be taken-in case material is released or spilled: Scoop residue and remove. Mix with surrounding soil if possible; Recycle if possible. Waste Disposal Method: Wastes resulting from the use of this product may be disposed of on site orat an approved waste disposal facility. SECTION Vill —SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify type): N/A Mechanical (General): N/A Ventilation: Use with adequate ventilation. Local Exhaust: N/A Protection Gloves: N/A Eye Protection: N/A Other Protective Equipment: Change cloths daily; bathe daily, wash cloths separately before reuse. SECTION IX—SPECIAL PRECAUTIONS =prejerablyin s to by taken in handling and storing: Store in the original container, a locked store a area. KEEP OUT OF REACH OF CHILDREN' MSDS Page 1 MATERIAL SAFETY DATA SHEET SECTION 1 — INDENTIFICATION OF PRODUCT Manufacturers Name Emergency Phone Number Dr. Earth Company (707) 448-4676 P.O. Box 460 Fax: (707) 448-4760 Winters, CA 95694 Trade Name & Synonyms Dr. Earth® Final Stop®R Snail & Slug Spray Chemical Name & Synonyms Chemical Family Essential Ois & Garlic Extract Organic liquid SECTION II — HAZARDOUS INGREDIENTS OF MIXTURES Component Rosemary Sesame Peppermint Thyme Cinnamon Garlic Inert Ingredients Beeswax, Calcium Carbonate, Carrageenan, Cellulose, Citric Acid, Glycerin, Kaolin, Lecithin, Mustard Powder, Sodium Bicarbonate, Sodium Chloride, Soybean Oil, Wintergreen Oii, Water SECTION III — PHYSICAL DATA Appearance & Odor: Liquid, Tan in color Boillna Point(Degrees Fahrenheit) Specific (Water= 1) Bulk Density N/A N/A N/A Vapor Pressure (MM of!Mercury) Percent Volatile (By Volume) N/A N/A Vapor Density (Air= 11 Evaporation Rate (Butyl acetate = 1) N/A N/A Solubility in Water 100% soluble. SECTION IV— FIRE AND EXPLOSION HAZARD DATA Material Safety Data Sheet Concr®blum lie®Id C®ntrole '�Sr' 7 _ � fix'' 4 lH Siore containers between 39'F(4°C)and 100°F(38°C" If product freezes,thaw and mix thoroughly. No special handling requirements. Keep out of reach of children. r ,r .+'''- f''k' ,r"��. y„ '- "-.. No special controls,ventilation,or personal protective equipment is require- in handling the product. However,to avoid applicator exposure to mold or mold spores during use,see label for"PERSONAL PROTECTION EQUIPMENT REQUIREMENTS FOR APPLICATORS". Appearance: Clear liquid Odor: Odorless Roiling Range: 212°F 1100°C Weight/US Gal: 0:5 lbs(3.9 kg) Evaporation Rate: Slower than ether Vapor Density- Heavier than air pH: 11.1 —11.5 Stability: Stable Reactivity: Non-reactive Hazardous polymerization: Will not occur Hazardous decomposition products: None Oral:No known hazards in normal use. LDso>5000 mgi"rg Dermal:No known hazards in normal use. LD5o>5050 mg/kg Eye Irritation: No known hazards in normal use. Non-irritating Skin Irritation:No known hazards in normal use. Non-irritating Inhalation:No known hazards in normal use. LCso>2_28 mg/L Sensitization:No known hazards in normal use. Not a ,sensitizer No special disposal considerations beyond accordance with federai, provincial,or local wastewater regulations. Recycle empty container. DOT SHIPPING DESCRIPTION: Not Regulated DOT HAZARD CLASS: NIA UN NUMBER: NIA DOT PACKING GROUP: NIA DOT PRIMARY/SECONDARY LABEL: N/A DOT PRIMARY/SECONDARY PLACARD: NIA DOT EMERGENCY RESPONSE GUIDE#: N/A The information set forth herein is believed to be accurate.Siamons International Inc.makes no warranty,expressed or implied,regarding the accuracy of the data or the results to be obtained from the use thereo`:The information issupolied solely for your information and consideration,and Siamons International Inc.assumes no responsibility for use or m iance Thereon.It is the responsibility of the user of Siamons international Inc.products to comply with all applicable federal,state and-local law.-and regulations. Siamons International Inc.warrants its products to be free from defects in material and:vorkrnanship. Siamons Intcmational Inc.'s liability on any claim of any kind,including claims based upon Siamons International Inc.'s negligence or strict liability,for any loss or damage arising out of,connected with,or resulting from the use of the products,shall in no case exceed the purchase price of the products or part thereof which give rise to the claim. In no evert shall Siamons International inc.be liable for consequential or incidental damages. 0 2011 Siamons Intemational Inc. Page 2 of 2 Material Safety Data Sheet Concrobium-Mold Control' } g G µ ai i Al' !e Product Name: Concrobium Mold Controls Product Use: FungistatlMildewstat(EPA Reg No.82552-1) Manufacturer: Siamons International Inc_ 48 Galaxy Blvd.,Unit 413 Toronto,Ontario,Canada M9W 6C8- (416)_213-0219 (Last update: Jan 5,2011) Proprietary mixture of food-grade,Inorganic salts and purified water. SARA 313 Substances: NONE Known or Suspected Carcinogens: NONE Organic Compounds: NONE Alcohols: NONE f Clear Air Act Sec. 122 Substances: NONE Ammonias: NONE VOCs: NONE Chlorines: NONE All ingredients are listed on the TSCA Chemical Substance Inventory. S F Hazard elating(HMISIWHMIS) Health 0- Fire 0 Reactivity 0 Special 0 Routes of entry: Dermal most likely Acute health hazards: None known Chronic health hazards: None known Carcinogens: No ingredients are listed by OSHA,IARC,or NTP as known or suspected carcinogens If irritation occurs,rinse area thoroughly with water. If swallowed,drink 1 glass of water. f3 Flashpoint: N/A Extinguishing Media: NON-FLAMMABLE Unusual Fire and Explosion Hazards: NON-FLAMMABLE Special Fire Fighting Procedures: NONE r a Recover usable material if possible_ Non-recoverable material can be disposed of in accordance with standard wastewater treatment methods. ©2011 Siamons Intemational Inc. Page 1 of 2 The Clorox Company 1221 Broadway Material Safety t Oakland,CA 94612 Data Sheet Tel.(510)271-7000 I Product: CLOROX REGULAR-BLEACH Description: CLEAR,LIGHT YELLOW LIQUID WITH A CHARACTERISTIC CHLORINE-ODOR Other Designations Distributor Ent encv Telephone loos. Clorox Sales Company For Medical Emergencies call: Clorox Bleach 1221 Broadway (800)446-1014 EPA Reg.No.5813-50 Oakland,CA 94612 For Transportation Emergencies Cherntrec (8001424-9300 11 Health Hazard Data IR-Hazardous Ingredients DANGER: CORROSIVE. May cause severe irritation or damage to eyes and Iryr redient Concentration Exposure Limit skin. Vapor or mist may initate. Harmful if swallowed. Keep out of reach of Sodium hypochlorite 5--10% Not=established children. CASE-7681-52-9 Some clinical reports suggest a low potential for sensitization upon exaggerated hydroxide <'r% 2 mg/m' exposure to sodium hypochlorite-if skin damage(e.g.,im Sodiumyroxe tafion)occurs during ' exposure. Under normal consumer use conditions the likelihood of any adverse CAS#1310-73-2 2 mg/m health effects are low. Medical conditions that may be aggravated by exposure to high concentrations of vapor or mist: heart conditions or chronic respiratory problems such as asthma,emphysema,chronic bronchitis or obstructive lung disease. FIRST AID: Eve Contact: Hold eye open and rinse with water for 15-20 minutes. Remove contact lenses,after first 5 minutes. Continue rinsing eye. Gall a physician. Skin Contact: Wash skin with water for 15-20 minutes. If-irritation develops,call 'ACGIH Threshold Limit Value(TLV)-Ceiling a physician. 20HSA Permissible Exposure Limit(PEL)Time Weighted Average(TWA.) Ingestion: Do not induce vomiting. Drink a glassful of water. If irritation develops,call a physician. Do not give anything by mouth to an unconscious person. None of the ingredients in this product are on-the-IARC,NTP or OSHA Inhalation: Remove to fresh air. If breathing is affected,call a physician. carcinogen lists. IV Special Protection and Precautions V Transportation and Re ulato Data No special protection or precautions have been identified for using this product DOT/IMDG/IATA-Not restricted. under directed consumer use conditions. The following recommendations are given for production facilities and for other conditions and situations where there EPA--SARA TITLE III/CERCLA: Bottled product is not reportable under is increased potential for accidental,large-scale or prolonged exposure. Sections 311/312 and contains no chemicals reportable under Section313. This product does contain chemicals(sodium hydroxide<0.2%and sodium Hygienic Practices: Avoid contact with eyes,skin and clothing. Wash hands hypochlorite<7.35%)that are regulated under-Section 304/CERCL A. after direct contact. Do not wear product-contaminated clothing for prolonged periods TSCA/DSL STATUS: All components of this product are on the U.S.TSGA- Inventory and Canadian DSL. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist Personal Protective Equipment: Wear safety goggles. Use rubber or nftrile gloves K in contact liquid,especially for prolonged periods. KEEP OUT OF REACH OF CHILDREN VI Spill Procedures/Waste Disposal Nil Reactivity-Data- Spill-Procedures:Control spill. Containerize liquid and use absorbents on Stable under normal use and storage conditions: Strong oxidizing— agent.-residual fiquid;dispose appropriately. Wash area and let dry. For spills of- Reacts with other-household chemicals such as toilet bowl cleaners,rust multiple products,responders should evaluate the MSDS's of the products for removers;vinegar,acids or ammonia containing products to produce hazardous incompatibility with sodium hypochlorite. Breathing protection should be worn in gases,such as chlorine and other chlorinated species. Prolonged contact with .enclosed,.and/or poorly ventilated areas until hazard assessment is complete. metal may cause pitting or discoloration. Waste Disposal: Dispose of in accordance with all applicable federai,state,-and local requilations. Vlll Fire and Explosion Data IX Physical Data Flash Point:None Boiling point...................................._.._...............................appro)C2121F/100°C Special Firefighting Procedures: None Specific-Gravity(HZ0=1).................................................................-1.1 at 70°F Solubility in Water..................................._............................................complete Unusual Fire/Explosion Hazards: None.Not flammable or explosive. Product pH ....-11.9 does not ignite when exposed to open flame. (F,1963,1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 08l09 Rug 24 05 09:39a FOX FROM SOIL 707826196E P. 13 6. EXPOSURE-CONTROLS/PERSONAL PROTECT ON PERSONA-LpItOTECTIV E EQUIPMENT EYES AND FACE:Eyeprotection recommended. SFJf+.. Gloves recommended. RESPIRATORY-: NIA- 7. PHYSICAL AND CHENUCA-1-PROPERTIES PHYSICAL STATE: Liquid COLOR:Dark Brown BOILING POINT:NIA SOLUBILITY IN WATER:Yes & STABILITY AND R€ACTI".n'I'Y STABLE:Yes HAZARDOUS POLYMERIZATION:Will not occur. CONDITIONS TO AVOID:NIA POLYMERIZATION:Will not occur. -INCOMPATIBLE MATERIALS:None known. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER,NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO-BE OBTAINED FROM THE USE THEREOF. ALWAYS READ AND FOLLOW-LABEL INSTRUCTIONS. Rug 24 05 09:388 FOX FARM SOIL 70782619GG P. 12 MATERIAL SAFETY DATA SHEET Date-Issued:8/1/04 MSDS Ref,No: Date-Revised:8/1/04 Revision No:Ncw MSDS 1.PRODUCT AND COW ANY IDENTIFICATION PRODUCT NAME:Big Bleam PRODUCT DESCRIPTION: U.1sid Plant Fertilizer MANUFAC URER: United Compost aed Organics DBA FoxFarm Soff and Fertiliser Co. 1220 5a It. Arcata,CA.0,5518 707-826-1"-! 2. HAZARDOUS INGREDIENTS IDENTIFICATION Nonhazardous Ingredients,Inert Materials,Proprietary. Chemical Name CAS# OHSA PEL ACGIH TLV Potassium Magnesium Sulfate 14477-37-8 NIA N/A Sodium Chloridc 7647-14-5 N/A N/A POTENTIAL;HEALTH EFFECT'S EYES:may cause eye irritation SKLN:M*y cause irritation. SKIN ABSORPTION:No INGLSTION Do not eat INHALATION:Yes ACUTE TOXICITY:None known CHRONIC:None known. 3. FIRST AID,'MEASURES EYES:Flush eyes with water.-Obtain medical attention i£irritation persists. SKIN: Wash with water and soap if irritation occurs.Seek medical attention if condition persists. INGESTION: Drink large amounts of water and Induce vomiting.Consult a physician. INHALATION:Move victim to fresh air.Give oxygen artificial respiration if necessary. Call a physician if discomfort persists. 4. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA.,Water spray.Material is non-flammable. FIRE FIGHTING PROCEDURES:NIA- AUTOIGNITION TEMPERATURE:-NIA Ff ASKPOINT_N/A HAZARDOUS DECOMPOSITION PRODUCES:None known. 5. HANDLING AND STORAGE HANDLING:lm case of spill.cofiect into a clean container for use if an contaminated.ircontaminaled,collect into containers for disposal.Inform-authorities-If sewers or watercourses are contaminated. STORAGE:Store in a tool-dry-location.Kee -out of reach of ebildres and domestic animals.. sinergy'llealth a✓r wo.6.;.rotecta yo✓r wwftl AZON. AX RAM, G m SAFETY DATA SHEET Smaller quantities can be disposed of in household waste. Larger quantities should be disposed of according to local authority regulations. Product does not require a classification for transport. M f A chemical safety assessment has not been carried out for the mixture by the supplier. Phrases Used in Section 3; R21/22:Harmful in contact with skin and if swallowed. R34:Causes Bums. R37/38:Irritating to respiratory system and skin. R41:Risk of serious damage to eyes. R50:Very toxic to aquatic organisms. The information contained in this Safety Data Sheet,which has-been prepared in accordance with regulatory requirements is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Synergy Health(UK)Ltd shall not be liable for any damage resulting from handling=orfrom contact with the above product. Revision 2 05/07/2012 Page 5 of 5 as health our wak vn-teces your worlJ A70MAX RANGE - SAFETY DATA SHEEP Stable under nornal-conditions. Heat Avoid contact with strong acids or strong oxidising agents. i.X. In combustion emits toxic furnes. Afftaw Toxicity values: Not applicable. MrW" -- - Ecoioxicit;values.-Not applicable. Biodegradeable No bioaccumulation potential. x. µ -Readily absorbed into soil. �N 272 Fu Not applicable: Negligible ecotoxicity. Revision 2 05/07/2012 gat our xrork protects your warlO AZOMAX RANGE - SAFETY DATA SHEET .-.. ,. t.,.: .. �C1'?vr* `" ix . ...:,;-r wY-.::; •.:r-r. r�r iv .:`r"`�. ,.3_:_w's Environmental Precautions:Dilute with plenty of water,do not allow to enter sewers/surface or ground water. `- _ . . �� _ -. � a�::•_.� �'`�_ .� :. :ram: .^�. �. ;�`.�-�. . Collecting and Cleaning:Absorb with liquid binding material,(sand,diatomite, acid binders,universal binders,sawdust). Transfer to a closable, labelled salvage container for disposal by appropriate method. .,y Handling: No special requirements Storage: Store in a cool,well ventilated area. Keep container tightly closed. g • Worlg3lace exposure limits: Not applicable MINIM Hand Protection: Proiective gloves may be worn. Respiratory Protection: Respiratory protection not required. Eye protection: Safety glasses. Ensure eye bath to hand. Skin protection: Suitable protective clothing. Colour:Colourless Odour: Pleasant pH:Approx.7 Relative density: 0.999 Flash point°C: N/A Soiubility in Water: Soluble -y-'.9C :-E .r:�x�.t�G�' a � ,�i `�'. •a-�3ay; t's'�,'�'�'"�,�.=itr'. sm ��L' z `='�i_ ." t �''�'�f As supplied the product is stable and has no adverse reactions with commonly used chemicals. Revision 2 05/07/2012 Page 3 of 5 + syre W- health ✓✓r wxk protecfsyour world AZOMAX RANGE - SAFETY DATA SHEET Hazardous Ingredients: C12-C14 ALKYL BENZYL DIMETHYL AMMONIUM-CHLORIDE EINECS CAS CHIP Classification CLP Classification aercent Xn:R21/22,C:R34;N:R50 - `1 BRONOPOL INN 200-143-0 52-51-7 Xn: R21/22,Xi:R37/38,Xi:-R41, - <1% N:R50 , ir; _ AM PW Eye-contact: Bathe the eye for 15 minutes with running-water. Skin contact: Wash hands after use. Inhalation: Seek medical advice if feeling unwell. Ingestion: Wash out mouth with water. y a xkw L x Eye contact: There may be iritation and redness. Skin contact: No symptoms. Inhalation: No symptoms. Ingestion: There may be irritation of the throat. Use fire extinguishing methods suitable to the surrounding fire. Use water spray to cool containers. "� - 2 aL ��fi�-•;_ma's��.tiT1Y+.,,. 14 ��>�.y �":$a t£ih�-:e In combustion emits toxic fumes. a; n ac Advice for fire-fighters:Wear self-contained breathing apparatus.Wear protective clothing to prevent contact with skin-and-eyes. `_. Personal Precautions: Refer to section 8 of SUS for personal_protection information.Turn leaking containers leak side up to prevent escape of liquid_ Revision 2 05/07/2012 Page 2 of 5 - 1 S)Cewhealth __ wwa nrorccts row wucra AZOMAX RANGE - SAFETY DATA SHEET IOCAn Trade?dame: AZOMAXTm Product Codes:AM050W,AM100W,AM100NW,AM200W,AM300W,AM500S,AM050WCE,AM100WCE, AM200WCE,AM500SCE Product available in form of sprays and impregnated wipes contained in flow-wraps, canisters and buckets. C,,�. Jw$r l S Company Name: Synergy-Health(UK)Ltd Address: 1 Western Avenue -Matrix Park Chorley Lancashire PR7 7NB United lQngdom Telephone: +44(0)1772 299900 Fax: +44(0)177229MI +44(0) 1772 299900 01 ON. This is a water based liquid that is classified as non hazardous. This product has no classification under CHIP. p Fm Label Elements under CHIP: - Hazard Symbols: No Significant Hazard. .a...... MOWr.e cY ..:._: a�.! c¢ r•�. ..�f .". _ .fit "Y "s.K .�.».......�._.� PST:this substance is not identified as a PBT substance. Revision 2 05/07/2012 Page 1 of 5 -Air - 3 --PREMI -ER -POTTIN 6 MWE IX: Super Soil for f for S Outdoor Growing Containv-Sarefoot.Soil Earthworm:Castings, composted dairy manure, perlite. rice hulls,-batguano,_flsh-bone meal,-blood-meal..epsom-saltl..lime*_azomite; hurnic acid, oyster shelf gypsum,phosphate,alfalfa meat,_kelp meal, and Endo mycorrhizae. A. c-ornp te.start to finish plantiing MIX. we recommend periodic use of wom casting tea and adjustment of teas and water to OR 6434AL 1 Cubic Foot. (2,93. Liters) Yelrn Earthaaorm and Castinga-Far-m ` .. 14741. Lawrence take Rd SE l !� Yelm, WA 98597 � 1 Page:7/7 National Fire Protection Association(USA.): Flammability- HeAl - InstabilityMeactivity Special Reprinted with permission from NFPA 704-2001,Identification of the Hazardsof Materials for Emergency Response Copyright©1997,National Fire protection Association,Quincy,MA 02269.This reprinted material is not the complete and-official position of the National Fire Protection Association,on the referenced subject which is represented only by the standard in its entirety. Copyright©2001,National Fire Protection Association,Quincy,MA 02269,This warning system is intended to be interpreted and applied only by proper!;trained individuals to identify fire,health and reactivity, hazards of chemicals.The-user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325,which would be used as a guideline only.Whether the chemicals are classified by NFPA or not,anyone using the 704 systems to classify chemicals does so at their own risk. Date of printing Print date Date of issue Validity date**-*. Version Report versionReport version Notice to reader To-the best of our_mowledge,the information contained herein is accurate.However,neither the above- named supplier,nor any-of its subsidiaries,assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user.-All-materials may present unknown hazards and should be used with caution. Although certain hazards are-described-herein,we cannot guarantee that these are the only hazards that exist. Report -version-Re port Version: version Date ofissuelDateof revision: Validity date***. Date ofpretious issue: 00/00/0000 1000226ro4-401(Retried-12/t2/2013 by, Waddbw Page:6/7 15 Regubtory information United States US.Federal regulations United States-TSCA 12(b)-Chemical export notification: None of the components-are listed. United States-TSCA 8(a)-inventory update rule(IUR): Not determined SA-RA 30213041311/312 extremely hazardous substances: No products were found. SARA 302/304-emergency planning and notirwation: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution-chemical inventory-hazard identification: No products were round. United States inventory(TSCA Not determined. 8b) State regulations Massachusetts New York New Jersey Pennsylvania California Prop.65 Not available. International regulations Canada inventory Not determined. International lists Australia inventory(AICS): Not determined. Taiwan inventory(CSNN): Not determined. Malaysia Inventory(EHS Register): Not determined. Japan inventory: Not determined. Korea inventory: Not determined. New Zealand Inventory of Chemicals-(NZIoC): Not determined. China-inventory(IECSC): Not determined. Philippines-inventory(PICCS): Not determined. 16.Other information Report versionRe port Version: version Date of issue/Date of revision:- Validity date***- Date ofprevious issue: 00/00/0000 100022M&G1 I Released-12/1?=13 by. WOddbW Page:11 Latest revision date: 11/24/2013 Version: 1.0 United States Material Safety Data Sleet ROUNDUP EXTENDED CONTROL WEED &GRASS CONTROL-RTU REFILL 1. Product and company identification MSDS# 320000000422 EPA Registration Number: 71995-4 7 2. Hazards identification l Physical state liquid Color Hazy to slightly hazy OSHA/HCS status While this material is not considered hazardous by the OSHA Hazard Communication Standard(2^>CFR 1910.1200),this MSDS contains valuable information critical to the safe handling and proper use of the product.This MSDS should be-retained-and available for employees-and other users of this product. Emergency Overview No harmful effects expected. Potential acute health effects Inhalation No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Skin No known significant effects or critical hazards. Eyes No known significant effects or critical hazards. Target organs 1. Not-available. Potential-chronic health effects:See section 11 for more information Over-exposure siens/svmptoms Inhalation No specific data. Ingestion No specific data. Skin No specific data. Eyes No specific data. Medical conditions aggravated None known. by over-exposure See toxicological information(Section 11) 3. Composition/information on-ingredients There are no ingredients present which,within the-current knowledge of-the supplier and in-the concentrations applicable,are classified as hazardous to-health or the environment and-hence require reporting in this section. Report version Re port Version: version Date of issuelDate of revision: Validity date***. Date of previous issue: 00/00/0000 100022ONG"l I Released-12/121201S by, Woddlow Page:2/7 4 First aid measures i Eye contact Check for and remove any contact lenses.Immediately flush eyes with plenty of water for at least 15 minutes,occasionally lifting the upper and lower eyelids.Get medical attention if symptoms occur. Stain contact In case of contact,immediately flush skinwith plenty of rater for at least 15 minutes while removing-contaminated clothing and shoes.Wash clothing before reuse.Clean shoes thoroughly before reuse.Get medical attention if symptoms occur. Inhalation Move exposed person to fresh air.If not breathing,if breathing _is irregular or if respiratory arrest occurs,provide artificial respiration or oxygen by trained personnel.Get medical attention if symptoms occur- Ingestion Wash out mouth with water.Do not induce vomiting unless-directed to do so by medical-personnel.Never give anything by mouth to an unconscious person.Get medical_attention if symptoms occur. Notes to physician No specific treatment.Treat symptomatically.Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. §. Fire-fthfing measures Hammability of the product In a fire or if heated,a pressure increase will occur and the container may .burst. Extinguishing-media Suitable Use an extinguishing agent suitable for the surrounding fire. Not suitable None known. Special exposure hazards Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.No action shall be taken-involving any personal risk or without suitable training. Hazardous-tiiermai- No specific data_. decomposition-products Special protective equipment Fire-fighters should wear appropriate protective equipment and self- forfre-fighters contained breathing apparatus(SCBA)with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal precautions No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas.Keep unnecessary and unprotected personnel from entering.Do not touch or walk through spilled material.Put on appropriate personal protective equipment(see Section 8). Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains-and sewers.Inform the relevant authorities if the-product has caused environmental pollution(sewers,waterways,soil or air). Methods for-cleaning up Small spilt Stop leak if without risk.Move containers from spill area.-Dilute-with water and mop up if water-soluble.Alternatively,or if water-insoluble,absorb with--air-inert dry material and place in an appropriate waste disposal -container.Dispose of via a licensed waste-disposal contractor. Large spill Stop leak if without risk.Move containers from spill area.Prevent entry_ Report version-Re port- Version. version Date of issuelDate-c-revision: Validity date***. Date of previous issue: 00/00/0000 10002 S964-01 I ReWised-12I12i2013 by, Workflow Page:?/? into sewers,water courses,basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with-non--combustiule,absorbent material-e.g.sand,earth, vermiculite or diatomaceous-earth and place in container for disposal according-to local regulations(see Section 13).Dispose of via a ficensed- waste disposal-contractor.Note:see Section 1 for emergency contact information and Section 1 forwaste disposal. 7. Handling and storage Dandling Put on appropriate personal protective equipment(see-Section 8).Eating, -drinking and smoking-should-bee prohibited in areas where this material is handled,-stored and-processed.Workers should wash-hands and face before -eating,drinking and smoking.Remove contaminated clotting and protective equipment before entering eating areas. Storage -Store in accordance with local regulations.Store in original-container protected from direct sunlight in a dry,cool and well-ventilated area,away -from incompatible materials(see Section 10)=and food and drink.Keep container tightly closed and sealed until ready for use.Containers that have been opened-inustbe carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination. 8.Exposure controWpersonal protection Occupational exposure limits No exposure standard allocated: Consult local authorities for-acceptable-expusure-limits: Recommended monitoring If this product contains ingredients with exposure limits,_personal, procedures workplaceatmosphere or biological.monitoring may be required to sletermine-the-effectiveness of the ventilation-or other control-measures and/or the-necessity to use respiratory protective equipment.-Reference should be made to appropriate monitoring standards.Reference to national -guidance documents for methods for the determination of hazardous substances will-also-be_required. Engineering measures No special ventilation requirements.Good general ventilation should be sufficient to control worker exposure to airborne contaminants.If this product contains-ingredients with exposure limits,use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Hygiene measures Wash hands;-forearms and face thoroughly after handling chemical products,-befom eating,-smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash-contaminated clothing before reusing.Ensure that eyewash stations and safety showers are close to the workstation location_ Personal protection Respiratory Use a properly-fitted-;air-purif}ing or air-fed respirator complying with an approved-standard if a risk-assessment indicates-this is necessary. Respirator selection must be based on-known or anticipated exposure Report version-Re port Version: version Dale of issue/Date of revision: Validity date***. Date of previous issue: 00/00/0000 1000226904-01 i RdeawW-12/1212019 by, WoMw - Pager/7 levels,the hazards of the product and the safe working limits of the selected respirator. Hands Chemical-resistant;impervious-gloves complying with an approved mi standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Eyes Protective eyewear is not required,but may_be used in situations were contact is-expected. Skin No special protective clothing is required. Environmental exposure Emissions from ventilation or work process equipment should be checked controls to ensure they comply with the requirements of environmentnLprotection legislation.In some cases;fume scrubbers,filters or engineering modifications to the process equipment will be necessary to reduce emissions to-acceptable levels: 4.Ph sisal and chemical properties Physical state liquid Flash point Not Applicable Burning time Not Applicable Auto-ignition temperature Not Applicable Flammable limits Not Applicable Density 1.02 g/cm3 Color Hazy to slightly hazy Odor Not Applicable PH 7.4 Boiling/condensation point Not Applicable Melting/freezing point Not Applicable Relative density 1.020 Vapor pressure Not Applicable Vapor density Not Applicable Volatility Not Applicable Odor threshold Not Applicable Evaporation rate Not Applicable Viscosity Not-Applicable Solubility Not Applicable Solubility in water Not Applicable_ 10.Stability and reae ivi Chemical stability The product is stable. Conditions to:-void No specific data. Incompatible materials No specific data. Hazardous decomposition Under normal conditions of storage and-use,-hazardous decomposition products products should not be produced. Possibility of hazardous Under normal conditions of storage and use,hazardous reactions will not reactions occur- 11.Toxicological information Acute toxicity Conclusion/Summary Report version.Re port Version: version Date of issuelDate of revision: Validity date**. Date of previous issue: OO100/0000 100022s9e4-01 I Rebased-12/122D13 by, WO M M Page:517 Irritation/Corrosion Skin Not available. Eyes Not available. Respiratory Not available. Sensitizer Condusion/Summary Skin Not available. Respiratory Not available. Chronic toxicity Conclusion/Sumr`ary Not available. Carcinogenicity Product/ingredient name_ Result Species Dose Exposure Conclusion/Summary Not available. Mutasenicity Conclusion/Summary Not available. Teratosenicity Product/ingredient Result Species Dose Exposure name Conclusion/Summary Not available. Reproductive toxicity Conclusion/Summary Not available. 12.Ecological information Ecotoxicity -No known significant effecis or critical hazards. Aouatic ecotoxicity Conclusion/Summary No known significant effects or critical hazards. Persistence/desradability Conchision/Summary No known significant effects or critical hazards. Partition coe[f ident:n- No known significant effects or critical hazards. octanollwater Other adverse effects No known significant effects or critical hazards. 13.Disposal considerations Waste disposal Disposal should be in accordance with applicable regional,national and local laws and regulations. 4.Transport information Not classed as-dangerous Report versionAe- pori Version: version Date of issuelDate of revision: Validity date***. Date of previous issue: 00/00/0000 1000226OU-0001 I Releaser!-12/1212013 by, WmM wv