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Home My WebLink AboutDOT MSDS Pesticide Information - OT General - 4/6/1993 APR 0 8 1Qq C;;- INTRA-DE PARTMENT COMMUNICATION WASHINGTON STATE DEPARTMENT OF TRANSPORTATION DATE: 4-6-93 FROM: Casey McGill SUBJECT: Pesticide Information Requested TO: Tony Trask Telar 72 oz Oust 600 oz Escort 24 oz Spike 50 Ibs Krenite 8000 oz Garlon 3A 1000 oz Garlon 4 500 oz Banvel 100 oz Weedar 64 1000 oz Round Up 800 oz Karmex 1000 Ibs cou PON M A.T £;R t A t:.S A F £ T Y :.'D A T A .:5 H E E T Du Pont Agricultural Products ism M0000026 ANWIM&W, — MW Revised 02-Oct-90 Printed 16-Jan-92 "Telar" Herbicide MATERIAL IDENTIFICATION Corporate Number D0003027 "TELAR" is a registered trademark of Du Pont. Manufacturer/Distributor Du Pont 1007 Market Street Wilmington, DE 19898 Phone Numbers Product Information 1-(800)441-7515 Transport Emergency 1-(800)424-9300 Medical Emergency 1-(800)441-3637 Grade 75% FORMULATION Chemical Family SULFONYLUREA Du Pont Registry Number DP419-32-3 NFPA Ratings Health: 1 Flammability: 1 Reactivity: 0 NPCA-HMIS Ratings Health: 1 Flammability: 1 Reactivity: 0 Personal Protection rating to be supplied by user depending on use conditions. COMPONENTS Material CAS Number Percent CHLORSULFURON 64902-72-3 75 (2-CHLORO-N-[[4-M ETHOXY-6-METHYL-1,3,5-TRIAZIN- 2-YL)AMINO)CARBONYL]BENZENESULFONAMIDE) INERT INGREDIENTS 25 (continued) Printed on Recycled Paper PHYSICAL DATA Water Solubility Dispersible Odor None Form Solid Color White to tar Specific Gravity 0.59 at 25=C (77=F; Bulk Density 36 Ibs/cu ft (!pose) 30 Ibs/cu ft(p2CkC-c) FA-ZA_RDOUS REACTIV?TY Instacility Gable at rcr:,,a! :e'ri'CeratureS arc s crag ., nci::cr'S. Incompatibility None reasorac:y foreseeable. Decomcositicr Deco mCcsc5z'N:M ^eat. Polymerizarcr Foiymerz=lion *il not occur. FIRE AND EXPLOSION DATA Lcxer E----plosive 0.090 c/L Fire and Explosion Hazards None. Lake . �cst orcanic.cowders cr crystais. urcer severs cusiir,C conditicrs. Iris material may form excicsive -!x::.reS 'r, a:.. Extinguishing Media V/ata-r Spray. rY C~emicai. Special Firs Fighting Instructions Wear serf-ccnmined breathing 2CCcrc .5. ','sa wcie' /. ---cci tank.Icortainer wan water spray. If area is heavliv exooSed to fire and if=ncition5 let fire burn ;iseif cut since Water may :rc.'ease ire area contaminatec. HEALTH HAZARD INFORMATION 7 CAUTION! Mav ____tate eves, nose, throat cz s!c_n. RCUTES OF EXPOSURES A-M.) E..=ECTS ORXL (Fasted Rat) LD 50: _', 053 mg/kc (male) , 2, 341 me/kc Slichtly toxic by izcest_cn. DER AL LD30: >2, 000 =/kg (rabbit; Slightly to ctcd'erate'_v c__.ic tv centac-::. S-KIN IRTLTTATICN AND S `7SIT,W%_ICN Not a skin ==_tar.= (r3:b_ts) nc= a sensi=-=ar (guinea igs) . ,ccrt i MCCCCC25 =ace 2 HEALTH HAZARD INFORMATION(conbnued) EYE CONTACT Administration of 10 mg to rabbit eye produced very mild temporary conjunctival irritation and slight corneal cloudiness. Eyes were normal within four days. CHRONIC STUDIES - CHLORSULFURON DIETARY Administration of 0, 100, 500, and 2, 500 ppm chlorsulfuron to male and female young adult dogs for 6 months produced a no-observable-effect level (NOEL) of 2, 500 ppm in the diet. No compound-related changes in nutritional, clinical, biochemical, gross or histopathological observations were made. Administration of 0, 100, 500, and 2, 500 ppm chlorsulfuron to male and female weanling rats for 2 years produced a NOEL of 100 ppm in the diet based on mild to moderate reduction in mean body weights and weight gains in male rats from the higher dose groups. Oncogenicity studies conducted with male and female mice by dietary administration of 0, 100, 500,and 5, 000 ppm - chlorsulfuron for 2 years showed no compound-related behavioral, clinical, hematological, gross pathological, or histological abnormalities. Chlorsulfuron was not oncogenic at any level. The overall NOEL was 500 ppm as a body weight reduction occurred in the 5, 000 ppm level. REPRODUCTICN (Rats) The dietary prese..^.e of chlorsulfuron at 500 ppm had no adverse effect on the reproduction or lactation performance of young adult rats (3-generation, 2-litters per generation) . TERATOGE,NICITY Not teratogenic in rats at 2, 500 ppm or up to 75 mg/kg in rabbits. MUTAGENICITY Not mutagenic in Ames bacterial assay, Chinese Hamster Ovary maT*r*+alian cell assay, rat dominants lethal assay, in vitro cytogenetic assay, or DNA repair assay. No data is available to confidently predict the effects of overexposure to humans. However, based on animal studies human health effects of overexposure by inhalation, ingestion, or skin or eye contact may initially include: eye irritation with discomfort, tearing, or blurring of vision, or irritation of the upper respiratory passages. Carcinogenicity None of the components in this material is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. (c-_n,inuec) M0000026 Page 3 v eSed sz00000w (pi (panuiluoo) -dn daanns Jo lanoyS 'Seale Moi Jo sAeMJaleM'sJaMas 6uualua woJ1 p!nb!l luanaJd •II!ds @�!O do uealo bu!Jnp 1N3WM03 3ni1031OHd WNOSH3d alepdoJdde ash 'dn uealo yl!M 6u!paaooJd aJolaq SNOl nv33Hd AL3JVS Pue SOddZdH NOISO1dX3 ONd 3EIId Malnaa :31ON asealaa io 'mea1 'll!d S wdd 000< :SMOuufw peaylel '0901 Jnoy 96 wdd 09Z < :1noJl Moqu!eJ '0501 Jnoy 96 •olx0l AIly61Is of Mol/GaA paJap!suoo s1 lualPaJ6u! an!loe ayl Allolxol ollenbd NOLLvNI ojm TvsodSIQ amen 13V ayl paaoxa Aew aJnsodxa 1! JolendsaJ apo!lsad panoJdde ue JeaM . .6u!ylolo pue 'saAa 'u!Ns y1!M 10Eluoo pone 'JanaMoy `pa!l!oads s! 3dd ON luawd!nb3 anlioaloJd IeuosJad 'leualew s!yl yl!M palEu!weluoo awooaq Aew �(ayl aJayM seaJe ayl u! 000egol Jo�uup'pool awnsuoo 1ou o0 saweg pue s�Jeds '1E9y woJ1�(eME daa){ •uo!1el!luan alenbape yl!M Aluo ash suo!lneoald pue sainseaw Ialuo0 algeoiiddd AlleaauaO 61 NOLLVMOJM NOIiOnodd 'ueioisA U a i n'uosJad sno,osuooun ue of ylnow Aq 6u!y1AUE an6 JanaN 6wO aonpu! pueJalEM 10 sassEl6 Z an!6 Alaepa!uwl 'paMollEMs 11 uollsa6ul 'uep!sAgd a Ile0 'salnu!w 51 lseal le Jot JalEM 10 Iluald yl!M saAa ysn11 Jtlale!paww! 'loeluoo 10 asEo ul loeluoO 8J(3 -asnaJ aJolaq 6u!ylolo paleu! � uweluoo yseM JaIEM pue dEOS y11M UI�S ySEM/�lalelpawwl 'loeluoo 10 aseo ui loeluo IKS 'uE!o!sAgd a IleO •u96Axo ani6 '11no!11!p s! 6uiyleaJq 11 'uopendsaJ JE1o!1!1Je an16 '6u!yleaJq•lou 11 •J!e ysaJj of anowaJ 'paleyu! 11 uolleleyui QIrd Z52II3 yse Jalle AIy6noJoyl 6u!ipuey /H '6u!U1olo Jo'u!�{s 'sa�(a yl!M loeluoo pony •lsnp 6u!y1eaJq pony •1s!w Jo SJ6dEA 6u!yleaJq pony suo!lneowd J(le1eS 'aouapaoaJd eMej I)eys sl!wil yons'10aga ui aJe)3y ayP ueyl Jamol aM yoiynn s4iwq ainsodxa Ieuolledn000 pasodwi Alle3uawwano aJayM 3iwri aJnsodx3 algeidaooy s,luod nQ st 13y pays!lgels3 auoN (VHSO) 13d Pays!IgEls3 auoN (HIJO`d) A11 VMl'JH Z l 'S 8- EuJ/6w 0 L puOd n0) .13V NOHf1d1nSHO1H0 suwtl ajnsodx3 oIgeoliddd (panuguoo)NoIjIV `I2iOjM (jZr%rZVW H.L'I`d3j; DISPOSAL INFORMATION(conOnued) Waste Disposal Treatment, storage, transportation and disposal'must be in accordance with applicable Federal, State/Provincial, and Local regulations. Remove nonusable solid material and/or contaminated soil, for disposal in an approved and permitted landfill. Do not flush to surface water or sanitary sewer system. Do not reuse container. Triple rinse (or equivalent), then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incinerator,or if allowed by State and Local authorities, by burning. SHIPPING INFORMATION DOT Proper Shipping Name NOT REGULATED BY D.O.T. DOT/IMO Proper Shipping Name NOT REGULATED BY IMO STORAGE CONDITIONS Store in well ventiiated area. Keep container tightly closed. Do rot store or consume food, drink or tobacco in areas where they may become contaminated with this material. TITLE III HAZARD CLASSIFICATIONS Acute No Chronic No Fire No Reactivity No Pressure No ADDITIONAL INFORMATION AND REFERENCES This product is registered under EPA/?IPRA regulations. EPA Reg. No. 352-404 The data in this Material Safety Data Sheet relates only to the specific material designated he and does not relate to use in combination with any other material or in any process. Responsibility for MSDS: Du Pont Agricultural Products Registration & Regulatory Aff. Wilmington, DE 19898 800-441-7515 End of MSDS M0000026 Page 5 cou MAT £ RIAL -'SAFETY DATA --SHEET Du Pont Agricultural Products iF I M0000028 Revised 04-Mar-91 Printed 16-Jan-92 dust Herbicide MATERIAL IDENTIFICATION Corporate Number DUO03048 "OUST" is a registered trademark of Du Pont. Manufacturer/Distributor Du Pont 1007 Market Street Wilmington, DE 19898 Phone Numbers Product Information 1-(800)441-7515 Transport Emergency 1-(800)424-9300 Medical Emergency 1-(800)441-3637 Grade 752; FORMULATION Chemical Family SULFONYLUREA Du Pont Registry Number DP292-84-6 NFPA Ratings Health: 1 Flammability: 1 Reactivity: 0 NPCA-HMIS Ratings Health: 1 Flammability: 1 Reactivity: 0 Personal Protection rating to be supplied by user depending on use conditions. COMPONENTS Material CAS Number Percent SULFOMETURON METHYL 74222-97-2 75 (METHYL 2-[[[[(4,6-DIMETHYL-2-PYRIMIDINYL)- AMINO]CARBONYL]AMINO]SULFONYL]BENZOATE INERT INGREDIENTS 25 (contin-ued) P^nted on Recycled Paper 1 PHYSICAL DATA Water Solubility Dispersible Odor None Form Solid, dry flowable Color Off-white Specific Gravity 1.46 Bulk Density 33 Ibs/cu ft(loose) 39 ibs/cu ft(packed) HAZARDOUS REACTIVITY Instability Stable at normal temperatures and storage conditions. Incompatibility None reasonably foreseeable. Decomposition Decomposition will not occur. Polymerization Polymerization will not occur. FIRE AND EXPLOSION DATA Flammable Limits in Air, % by Volume LEL 0.092 g/L Not a fire and explosion hazard. Fire and Explosion Hazards Like most organic powders or crystals, under severe dusting conditions, this material may form explosive mixtures in air. ExtinguishingMedia Water Spray. Foam. D Chemical. CO2. Dry Special Fire Fighting Instructions Wear self-contained breathing apparatus. Wear full protective equipment. Use water spray. Runoff from fire control may be a pollution hazard. If area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the contamination hazard. HEALTH HAZARD INFORMATION CAUTION! May irritate eyes, nose, ' throat and skin. ROUTES OF EXPOSURE AND EFFECTS Acute Oral LD50: >5, 000 mg/kg (rat) Very low order of toxicity. Acute Dermal LD50: > 8,000 mg/kg (rabbit) males > 2, 000 mg/kg (rabbit) females Slight to moderate order of toxicity. 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ME 1!Jo'u0llela6an algnlen Jaylo Jo sdoJo aonpoid of pasn punoJ6 uo sl eaJe Inds 11 do deaMs Jo lanoyS •seaJe MOl JO shmialeM'SJaMaS 6uualue woJ1 p!nbll luanaJd •11!ds @M!o -dn ueaio bu!Jnp 1N31NdinCA 3AUD3*10Hd IVNOSH9d alelJdoJdde ash •dn ueal0 yl!M 6ulpaaooid aJolaq SNOI-LnvO3Hd ,k13ziVS PUB SaHdZVH NOISO1dX3 (INV 3811 MalnaH :310N aseelaH Jo')iea-l '111dS wdd OZ9'S< :i!enb al!gmgoq '0901 IeJO wdd 000'S< :sNonp piellew 'OSOI IeJO /l!olxol IeluawuoJlnu3 wdd S-Z L< :inoJl MoquleJ '05o1 Jnoy 96 bylaw uoJnlawol1nS Ailo1xol 01lenbd xoL,vmojm 7vsodsia slleJanoo 'sla�{oef 'siued 'uoJde 'sanol6 snowadwl 'aleudoJdde se team' pue alge11ene aney 10e1u00 ulMs Jol Iellualod sl aJayl aJayM •sJoleJldsaJ ap!o1lsad panoJdde VHSw/HSOIN JeaM 'sl!wll algeolldde 10 ssaoxa ui samsodxa awogne Jol lellualod sl eiayl aJayM sal66o6 yselds ieolwayo Jo sassel6 dales JeaM'saAa yl!M 10eluoo pone of :aJnsodxa aAISSaOxa Jol lellualod sl aJayl 1! PapuawwooaJ s! 3dd 6ulMollol ayl 'lagel ayl Aq paloaJlp se lonpoJd slyl bulsn uagm pannbai sl 3dd'ou al!yM luawdlnb3 anlPelOJd IeuosJad -leualew slyl yl!M paleulweluoo awooaq Sew Aayl aJagm seaJe ayl u! 000egol Jo�luup 'pool awnsuoo lou oo *pasolo Aily6ll Jauleluoo daa}i -sawell pi e snljeds 'leay woJ1 AeMe daayl 'uollel!luan alenbape yl!M Aluo asN suollneoaJd pue saJnseaw loJluoO algeollddb AlleJauas NOLLVYII OJM NOUDaloZid — 'tiessa0au 1! uelolsAgd llnsuoo •uollsabu! Aq snopJezey aq of Ala�ill lou sl punodwoo se paleolpu! s! uolluanJalu!o!1!oads ON uo!lsa6ul -ue►olsAgd a IleO •sainulw 9iseal le — Jot JaleM to�luald yl!M saAa ysnil Alalelpawwl 'loeluoo 10 aseo ui 10e1u00 aA3 'loeluoo anlssaoxa Jal1e JaleM yl!M ulNs ysnld loelu o'J UIMS -uelolsAgd a Ilex •ua6Axo anl6 '11rio!1!P sl 6ulyleaJq 11 •uolleJldsaJ le1o!1!Ue anl6 '6ulyleaJq*lou 11 •J!e ysaJ10l anowaJ 'paleyu!ll uolleleyul My ISM I DISPOSAL INFORMATION(continued) �I Waste Disposal Treatment, storage, transportation and disposal-must be in accordance with applicable Federal, State/Provincial, and Local regulations. Remove nonusable solid material and/or contaminated soil, for disposal in an approved and permitted landfill. Do not flush to surface water or sanitary sewer system. Triple rinse (or equivalent) the container. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill,or by incineration, or if allowed by State and Local authorities, by burning. SHIPPING INFORMATION DOT Proper Shipping Name NOT REGULATED 6Y D.O.T. DOT/lM0 Proper Shipping Name NOT REGULATED STORAGE CONDITIONS Store in well ventilated area. Keeo container tightly c!osed. Do not store or consume food,drink or tooacco in areas where they may become contaminated with this material. TITLE III HAZARD CLASSIFICATIONS Acute Yes Chronic No Fire No Reactivity No Pressure No ADDITIONAL INFORMATION AND REFERENCES This product is registered under EPA/FIFRA regulations. The EPA Reg. No. is 352-401 The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other materiai or in any process. Responsibility for MSDS: Du Pont Agricultural Products Registration & Regulatory Aff. Wilmington, DE 19898 800-441-7515 End of MSDS MOO00O28 Page 5 I a P 0 T M'A T-E:.R ! A t' -->S-A F E T Y=: D=A T A S H E E T Du Pont Agricultural Products M0000185 Revised 26-Aug-91 Printed 16-Jan-92 "XARMEX" DF Herbicide # MATERIAL IDENTIFICATION Corporate Number D0003060 "KARMEV is a registered trademark of Du Pont. Manufacturer/Distributor Du Pont 1007 Market Street Wilmington, DE 19898 Phone Numbers Product Information 1-(800)441-7515 Transport Emergency 1-(800)424-9300 Medical Emergency 1-(800)441-3637 Grade AN 80% FORMULATION Du Pont Registry Number DP147-19-7 NFPA Ratings Health: 1 Flammability: 1 Reactivity: 0 NPCA-HMIS Ratings Health: 2 Flammability: 1 Reactivity: 0 Personal Protection rating to be supplied by user depending on use conditions. COMPONENTS Material CAS Number Percent DI U RON 330-54-1 80 (3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA) INERT INGREDIENTS 20 (continued) Printed on Recycled Paper PHYSICAL DATA Water Solubility Dispersible Odor Odorless Form Granules Color Brown Bulk Density 32.5 Ibs/cu ft(loose) 39.5 lbs/cu ft (packed) HAZARDOUS REACTIVITY Instability Stable at normal temperatures and storage conditions. Incompatibility None reasonably foreseeable. Polymerization Polymerization will not occur. FIRE AND EXPLOSION DATA Flammable Limits in Air, % by Volume LEL 0.070 g/L Autoignition 455°C (851 T) Fire and Explosion Hazards Like most organic powders or crystals, under severe dusting conditions, this material may form explosive mixtures in air. Extinguishing Media . Water Spray. Foam. Dry Chemical. CO2. Special Fire Fighting Instructions Wear self-contained breathing apparatus. Use water spray. If area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the contamination hazard. HEALTH HAZARD INFORMATION WARNING! Causes eye irritation. May irritate nose, throat, and skin. ROUTES OF EXPOSURE ARID EFFECTS Oral LD50: 2, 900 mg/kg (rats) body Weight Considered slightly toxic. Dermal LD50: > 2, 000 mg/kg (rabbits) Slightly to moderately toxic by contact. 0.05 g "Karmex" as an aqueous paste applied to intact human skin produced no irritation, Technical Diuron produced no sensitization in guinea pigs. EYE (continued) M0000185 Page 2 HEALTH HAZARD INFORMATION(continued) Produced mild to moderate corneal opacity, mild conjunctural redness and slight to mild chemosis in unwashed rabbit eyes. Eyes normal within 14 days after exposure. Considered moderate eye irritant. CFRONIC STUDIES - DIURON The compound is a skin irritant, is an eye irritant, but is not a skin sensitizer in animals. Toxic effects described in animals from short exposures include: blood effects, spleen effects, thyroid effects, methem globinemia, and nonspecific effects such as weight loss and irritation. Tests in some animals demonstrate carcinogenic activity. Tests in animals demonstrate no embryotoxic activity at concentrations equal to or less than the TLV of 10 mg/m,'#. Animal testing indicates that this compound does not have mutagenic, or reproductive effects. HUMAN HEALTH EFFECTS Overexposure by inhalation, ingestion, or skin or eye contact may initially include: skin irritation with discomfort or rash; eye irritation with discomfort, tearing, or blurring of vision; liver enlargement; spleen and thyroid effects; red blood cell destruction; or reduction of the blood' s oxygen carrying capacity with cyanosis (bluish discoloration) , weakness, or shortness of breath by formation of methe=globin. Significant skin permeation after contact appears unlikely. There are no reports of human sensitization. Carcinogenicity None of the components in this material is listed by IARC. NTP, OSHA, or ACGIH as a carcinogen. Applicable Exposure Limits DIURON AEL ' (Du Pont) 10 mg/m3 -8 Hr TWA TLV (ACGIH) 10 mg/m3 -8 Hr TWA PEL (OSHA) 10 mg/m3 -8 Hr TWA AEL is Du Pont's Acceptable Exposure Limit. Where govemmentally imposed oc,^,upational exposure limits which are lower than the AEL are in effect,such limits shall take precedence. Safety Precautions Avoid breathing vapors or mist. Avoid breathing dust. Avoid contact with eyes, skin, or clothing. Wash thoroughly after handling. FIRST AID Inhalation If inhaled, remove to fresh air. if not breathing, give artificial respiration. if breathing is difficult, give oxygen Call a physician. Skin Contact Flush skin with water after contact. Wash contaminated clothing before reuse. Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Ingestion If swallowed, immediately give 2 glasses of water and induce vomiting. Never give anything by mouth to an unconscious person. Cali a physician. (continued) M0000185 Pace 3 PROTECTION INFORMATION Generally Applicable Control Measures and Precautions Use only with adequate ventilation. Keep container tightly closed. Do not consume food,drink or tobacco in the areas where they may become contaminated with this material. Personal Protective Equipment Label instructions do not specify any PPE to be worn when using this product only that farm workers performing hand labor operations should not enter treated cropland areas without protective clothing until sprays have dried. The protective equipment recommended below applies to industrial handling and formulation only. Wear safety glasses. Wear coverall chemical splash goggles and face shield when the possibility exists for eye and face contact due to splashing or spraying of material. Wear protective clothing such as gloves, apron, boots or coveralls, as appropriate. Respiratory protection should not be required for normal use and handling. During abnormal exposures, use of an approved pesticide respirator is reconnended. DISPOSAL INFORMATION Aquatic Toxicity Diuron is considered moderately toxic. 96 hour LC50, rainbow trout: 3.5 ppm Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-contained breathing apparatus. Dike spill. Prevent liquid from entering sewers, waterways or low areas. Shovel or sweep up. Waste Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Remove nonusable solid material and/or contaminated soil, for disposal in an approved and permitted landfill. Do not flush to surface water or sanitary sewer system. SHIPPING INFORMATION DOT Proper Shipping Name NOT REGULATED BY D.O.T. IF <125 LBSIPKG. (SEE *NOTE) Freight Class HERBICIDE PREPARATIONS, OTHER DOT/IMO Proper Shipping Name NOT REGULATED 'NOTE: IF 125 LBS. OR MORE "KARMEX" DF PER PACKAGE: Proper Shipping Name : RO HAZARDOUS SUBSTANCE, SOLID, N.O.S. (DIURON) Hazard Class : ORM-E UN/NA No. : NA9188 (continued) 0000115 Page 4 H STORAGE CONDITIONS Store in well ventilated area. Keep container tightly closed. Do not store or consume food, drink or tobacco in areas where trey may become contaminated with this material. TITLE III HAZARD CLASSIFICATIONS Acute Yes Chronic Yes Fire No Reactivity No Pressure No ADDITIONAL INFORMATION AND REFERENCES ADDITIONAL REGU-�ATORY INFORMATION: SARA/CERCLA Reportable Quantity: Diuron (100 lbs) Regulatory Controls: "KAP- X" DF Herbicide is registered under EPA/FI_RA regulations. EPA Reg. No. 353-508. The data in this Material Safety Data Sheet reiates only to the specific material designated here r arc does not relate to use in comoination with any other material or.in any process. Responsibility for MSDS: Du Pont Agricultural Products Registration & Regulatory Aff. Wilmington, DE 19898 800-4d1-7515 Indicates undated section. F] End of MSDS i MC M0000185 Page 5 pou;p\ U IU/ MAT £ RIAC''SAf £ TY DATA -SHEET li�Du Pont Agricultural Products M0000027 Revised 01-Aug-90 Printed 16-Jan-92 "Escort" Herbicide MATERIAL IDENTIFICATION Corporate Number D0002103 "ESCORT' is a registered trademark of Du Pont. Manufacturer/Distributor Du Pont 1007 Market Street Wilmington, DE 19898 Phone Numbers Product Information 1-(800)441-7515 Transport Emergency 1-(800)424-9300 Medical Emergency 1-(800)441-3637 Grade 60% FORMULATION Chemical Family SULFONYLUREA Du Pont Registry Number DP543-60-6 NFPA Ratings Health: 1 Flammability: 1 Reactivity: 0 NPCA-HMIS Ratings Health: 1 Flammability: 1 Reactivity: 0 Personal Protection rating to be supplied by user depending on use conditions. COMPONENTS Material CAS Number Percent METSULFURON METHYL 74223-64-6 60 (METHYL 2-[[[[(4-METHOXY-6-METHYL-1,3,5- TRIAZIN-2-YL)AM INO]CARBONYL]AM INO]SULFONYL]- BENZOATE) INERT INGREDIENTS 40 (continued) Printed on Recyded Paper PHYSICAL DATA Water Solubility Dispersible Odor Odorless Form Solid Color Off-white Specific Gravity 1.47 Bulk Density 33.9 Ibs/cu ft (loose) HAZARDOUS REACTIVITY Instability Stable at normal temperatures and storage conditions. Incompatibility None reasonably foreseeable. Decomposition Decomposition will not occur. Polymerization Polymerization will not occur. FIRE AND EXPLOSION DATA Flammable Limits in Air, % by Volume LEL 0.135 g/L Not a fire and explosion hazard. Fire and Explosion Hazards Like most organic powders or crystals, under severe cussing conditions, this material may form explosive mixtures in air. Extinguishing Media Water Spray. Foam. Dry Chemical. CO2. Special Fire Fighting Instructions Evacuate personnel to a safe area. Wear self-contained bream'ir.c apparatus. Use water spray. If area is heavily exposed to fire and if conditions permit. let fire burn itself out since water may increase contamination hazard. HEALTH HAZARD INFORMATION CAUTION! Harmful if absorbed through skin. Causes eye irritation. ANI1,1AL DATA Acute Oral LD50: >5, 000 sg/kg (rat) Very low toxicity by ingestion. Acute Dermal LD50 : >2, 000 mg/kg (rabbit) Slightly to moderately toxic by contact. SKIN (continued) j M0000027 Page 2 HEALTH HAZARD INFORMATION(continued) Irritation (rabbit) and sensitization t ation 'n( i (guinea pig) : not a primary skin irritant, not a sensitizer. EYE Irritation (rabbit) : mild to moderate corneal irritation in unwashed eyes and mild conjunctival irritation in washed eyes. A11 effe cts reversed within 7 days. CHRONIC STUDIES - METSULFURON M-7THYL FEEDING STUDY No oncogenic effects observed in 18 month mouse and 2 year rat feeding studies. REPRODUCTION Slightly decreased parental body weight at 5, 000 ppm. No effect on rat reproduction or lactation at any dose tested (highest dose tested 5, 000 ppm) . TERATOGZNICITY Not teratogenic or embryo-fetal toxic by gavage in rats (highest dose tested 1, 000 mg/kg) or by gavage in rabbits (highest dose tested 700 mg/kg) . MUTAGENICITY Not mutagenic in Ames bacterial assay, Chinese Hamster Ovary Cell assay, or DNA rat liver repair assay; positive in the in vitro Chinese Hamster Ovary Cell cytogenetic assav but negative in the in vivo rat bone marrow cytogenetic assay. HUMAN HEALTH EFFECTS No data is available to confidently predict the effects of overexposure to humans; however, based on animal studies, overexposure by inhalation, ingestion, or skin or eye contact may initially include eye irritation with discomfort, tearing, or blurring of vision; or irritation of the upper respiratory passages. Repeated dermal exposure may lead to skin irritation with discomfort or rash. Carcinogenicity None of the components in this material is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. Applicable Exposure Limits METSULFURON METHYL AEL ' (Du Pont) 10 mg/m3 -8 & 12 Hr TWA TLV (ACGIH) None Established PEL (OSHA) None Established AEL is Du Pont's Acceptable Exposure Limit. Where govemmentaliy imposed occupational exposure limits which are lower fan the AEL are in effect,suu�limits shall take precedence. Safety Precautions Avoid breathing vapors or mist. Avoid breathing dust. Avoid contact with eyes, skin, or clothing. Wash thoroughly after handling. Wash clothing after use. (continued) M0000027 Page 3 FIRST AID Inhalation If inhaled, remove to fresh air. If not breathing,give artificial respiration. If breathing is difficult, give oxygen. Call a physician.. Skin Contact Flush with water after excessive contact. Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Ingestion No specific intervention is indicated as compound is not likely to be hazardous by ingestion. Consult physician if necessary. PROTECTION INFORMATION Generally Applicable Control Measures and Precautions Use only with adequate ventilation. Keep away from heat, sparks and flames. Do not consume food, drink or tobacco in the areas where they may become contaminated with this material. Personal Protective Equipment Label instructions do not specify any PPE to be worn when using this product. The protective equipment recommended below applies for industrial handling and formulation only. Wear safety glasses. Wear coverall chemical splash goggles and face shield when the possibility exists for eye and face contact due to splashing or spraying of material. Wear protective clothing such as gloves, apron, boots or coveralls, as appropriate. Respiratory protection should not be required for normal use and handling. During abnormal exposures, use of an approved pesticide use respirator is recommended. DISPOSAL INFORMATION Aquatic Toxicity Metsulfuron Methyl LC50, rainbow trout and bluegill sunfish: > 150 ppm Environmental Toxicity Oral LD50, mallard duck: >2,510 mg/Kg Oral LC50, bobwhite quail: > 5,620 ppm Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Dike spill. Prevent liquid from entering sewers,waterways or low _ areas. Shovel or sweep up. Waste Disposal Treatment, storage,transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Do not contaminate water, food or feed by storage,disposal or cleaning of equipment. Wastes resulting from the use of this product may be disposed of on site or at an approved (oondnued) M0000027 Page 4 DISPOSAL INFORMATION(continued) waste disposal facility. CONTAINER DISPOSAL: Triple rinse (or equivalent) the container.Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill or by incineration,or if allowed by State and Local authorities, by burning. If burned, stay out of smoke. SHIPPING INFORMATION DOT Proper Shipping Name NOT REGULATED BY D.O.T. Freight Class WEED KILLING COMPOUND, N.O.S. STORAGE CONDITIONS Store below 1400C (284°F). Store in well ventilated area. Keep container tightly closed. Do not store or consume food, drink or tobacco in areas where they may become contaminated with this material. TITLE III HAZARD CLASSIFICATIONS Acute Yes Chronic No Fire No Reactivity No Pressure No ADDITIONAL INFORMATION AND REFERENCES "ESCORT" Herbicide is a FIFRA regulated product. EPA Reg. No. 352-439. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS: Du Pont Agricultural Products Registration & Regulatory Aff. Wilmington, DE 19898 800-441-7515 End of MSDS i I M0000027 Page 5 VISKO-RHAP LOW VOLITLE ESTER 2D _ 42545-32 U.S. DEPARTMENT OF LABOR I Ar, ••n•Ca �� 3E7� Occupational Safety and Health Admimstrltrt'n C7M it yu. •14 R I MATERIAL SAFETY DATA SHEET fiPrprrrr 1 'rnrli r IJ"DL :".Arty mi" li .Iitl. I1rr)ui.rtinn. for Nhri Repairrnq, Sh1(rbulldiny, and Siti)7lncdkrny 12'.1 CFR 191! 1JIti, 1J17) SECTION I [AODRESS(,Vu,nber,Srree1, ANUFACTURER'S NAME EMERGENC a TELEPHONE NO. ILHORE CHE_dICALS, INC. 816-238-3377 _ C1:y,Stag,and ZIP CudeJ KZ-2 - t V r J C°'1H N. 64504 CHEMICAL NAME AND SYNONYMS 1 =f >r L•--n 11 TRADE NAME ANOSYt4oNYMS ESTER 2D; 2-Ethvlhexvl ester of 2,4-dichlorcohe xvacetic acid CAS:25168-26-7 CHEMICAL FAM:LY FORMULA Phenoxv herbicide C16H22C1203 SECTION II - HAZARDOUS INGREDIENTS PAINTS,PRESERVATIVES,6 SaLV ENTS % TLV ALLOYS AND METALLIC COATINGS X TLV nln PIGMENTS (Unite) BASE METAL CATALYST ALLOYS VEHICLE METALLIC COATINGS SOLVENTS FILLER METAL - PLUS COATING OR CORE FLUX ADDITIVES OTHERS OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS,SOLIDS,OR GASES TLV % (Units) 2-Ethvlhexvl ester of 2,4-dichlorooheroxvacetic aid 35.64 Inert inaredients SECTION III - PHYSICAL DATA BOILING POINT ('F.) --- SPECIFIC GRAVITY(H10=1) — O.S7E7 VAPOR PRESSURE (mm Hg.) - PERCENT,VOLATILE --- By VOLUME (%) VAPOR DENSITY (AIR-1) EVAPORATION RATE - SOLUBILITY IN WATER 01UblC APPEARANCE AND ODOR Brown Clear llculd Phenolic odor SECTION IV FIRE AND EXPLOSION HAZARD DATA rEXTINGUISHINCG LASH POINThletn0' usedE LIMITS1070F TCC LeI U.I MEDIA Foam - CO - Dry Chemical_ SPECIAL FIRE FIGHTING PROCEDURES --- Self-contained breathing aunaratus UNLiSUAL FIRE AND EXPLOSION HAZARDS This is a combustible liquid PAGE (1) (Continued on reverse side) Form OSHA-2^, R". mby 72 - —SECTION V - HEALTH HAZARD DATA. \ T►IHI!,11OLD LIMIT VALUE 1'LV-IWA; lU_U ppm (aromatic. solvent lyul EFi EC7S OF OVEREXPOSURE - - — J �"" ----- ----- _• _ ._. E CRGENCY ANO FIRST AIDPROCEDUR-ES . - us�l eye!; - ttoro--u-y— _ y wit t► larye volume. •c;� �;;Etc - KIN: .Wash with sgap & large volume of water. Seek medicallassistancelas necessar u dPVPln C t'1T or —_ L2 SI GtS yi INHALATION: Remove from area of exposure. Seek medical assistance INGEST N: I v m' ce as necessa i as neress rv. SECTION VI - REACTIVI TY DA TA STABILITY CONDITIONS TO AVOID UNSTABLE STABLE X Avoid heat and oDen fiame th oteria S JO avOr J HAZARDOUS DECOMPOSITION PRODUCTS o H dr en chloride and carbon oxides ma be emitted on combustion. HAZARDOUS MAY OCCUR CONDITIONS TO AVOID POLYMERIZATION WILL NOT OCCUR X SECTION VI - SPILL OR LEAK PR OCEDURES URES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Absorb on vermiculite and sweep uD int a st-A drum WASTE OISFOSAL METHOD Bursecure a rrFederal i S SECTION VIII - SPECIAL PROTECTION INFORMATION FRESPIRATORY PROTECTION tS^tCify type) No normally required NTILATION LOCAL EXHAUST ti••�CIvL I n v MECHANICAL (General) O'f,4CQ— Use local exhaust fans in confined area = ;>vide adequate ventilatio PROTECTIVE GLOVES =-• Use Rubber Gloves EYE PROTECTION OTHER PROTECTIVE EQUIPMENT �- -mical works Go IgS Maintain e e wash fountain and safety shower in work are..t. SECTION IX . SPECIAL PRECAUTIONS FPREAIONS TO BE TAKEN IN HANOLING AND STORING Store jn cool, dry area 1n tjgnt }• c ese,:ers. Avoid heat o en flame hot surfaces sparks or eye t-' Lorekeepjng jn the work a . storage areas. Avoid breathing vapors or mists. „� _prolonged contact with skin and eves. wash hands thorouahl� after haadli^c C� OTHER PRECAUTIOIrS not eat, rin , Or smU a jn tHa work area. Avol spraying In or nea crc teas. Do not allow spray drift to contact desirable plants. Do rot store with fee�� e s, oodstu rs, lnsectjcjaes, or unglcj es. Co not ce.ztart►jnate water sources a: se containers. Launder contaminated clo•hinq before re-use. Read label carefull>, - ore u ,e. Keep out or rear_h of chlldren an anlnals. PA E t CPO 9W.34O Formos"-20 • A•..Mryr )2 !t�''ic=d:�}: "'tam K'T' i°. `r'a �.s.�:►la�a.3-..T_'_�?-��•- y-.. ��•i'1,7+<�`�Z_. .:.I��.J�:7._r:'cl .,eta►r_ ' .C_^ -�: ��i;�;.x�•LI•:�•r r.....•r � ' i yam•:,•-,�, - ?.� y.•;--�`i-'�._'!,.�: i - ELANCO j "<<"• -� :]c - �`}_ .'�'.._ ..� j1 Kt wr ^c s.'1ty.r•+ v,t_.�y_^ �`2 L,.`?r�,•�t-Ys� .._ 4 -•"�'�: ;F��a�� .1 1;7�r -�"� - : 1 :• �T.�Y. ` .:.� •v�Y.l^ Y.y Jti - .,�.f-• a' .G1,7575 `�- 9 J spiKe 88W ID 5955 SPIKE'--"' 80w is a preemergence herbicide for total con. tro!of vegetation in noncropland areas. 11• STABILITY AND STORAGE I. PHYSICAL AND CHEMICAL Stable under normal storage conditions PROPERTIES III. UNUSUAL FIRE AND EXPLOSION A. Active Ingredient Generic Name HAZARDS Tebuthiuron The explosive potential of SPIKE 80W as an airborne dust is rated as severe. The mini. E3- •Chemical Name mum ignition temperature of a dust cloud is N•(5-(1,1-dimeth leth I • 948OF (509'C)- Spills or accumulations of Y Y ) 1,3.4•thiadiazol• dust should be cleaned 2•yll-N,N'-dimethyluraa d up immediately. C. DOT Classification IV. SPILL INFORMATION Nonregulated Do not contaninate any body of water.Sweep up material. Place it and damaged unusable D. Normal Physical State containers in a landfill approved for pesticides Avery fine, off-white wettable in accordance with applicable regulati Powder Avoid dusting, ons. with a mild odor Large spills due to traffic accidents,etc.,should E. Auto-Ignition Temperature be reported immediately to CHE.MTREC and 518°F (270°C) Elanco Products Company for assistance. Pre- F. p vent spilled material from flowing on adjacent Nootf applicable land or into streams,ponds or lakes. V. PROTECTIVE EQUIPMENT G. Explosive Limit (minimum concentration REQUIREIMENTS for dust cloud) When hand!izg material, wear goggles, rubber 0.06 ounce per cubic foot gloves, NIOS.i (1) aoprcved dust resairator H. Solubility for dust and protective ecu:p:nznt to prevent contact with skin and eyes and inhalation of Disperses in water dust. I. Threshold Limit Value VI. FIRE FIGHTING INFORMATION Not established Considered ncn flammable. May emit J. pH (aqueous 50/50) fumes when healed to decomposition, Do of 7.4 allow water run-of: from fire ;ice to enter near e by str_ar^.,,, ponds or laces. Keep contain- ers cooled with water spray, Z119F FL �-"_ �.;e•` �' !_.A/•.s7. r..` � - :._Y_ -i .�" 'Y -� -' =-J`� a.r.'Yt•'yam.�� R�{�,� •�'P'.T'�C .? 11,119111110, -_ F\• •\ .1 - -1 -a , 1 r' - •I• 1' 1,01 . . '>aT�`3•St57•ns+t 4� ..►•� j"i_ �y •� ^.�.. .yam. �a.r.T-."�� :c rw _ -_ ,\.t'3=.�''—.... Sri--^f��-`a:r C.... �.._ �•..��,� tx _•'��.. ...,r Via• ,_.-<�`• �T�c �.r_F1 p::.•., - -r �� _ a'�.- �n-�^ate..,: � `"'�Cc r' S}x:�.-'_+�-, ��.:;� '�`•^ L` �:.�i-.�.��-fi-• �-,-^-�`'_'��''— _ �. -L � •-�'�;1.��.'��.;r:.�� 'lrt'F+-'7�.�-'�.��.^�i -fir•'TM'..-j''_« J Wit,;:� - ^. VII. TOXICOLOGY A. Eyes IX. LABEL STATEMENTS A. Container Disposal Slight irritation, which cleared within 24 ( hours, occurred when 23 m Do not contaminate food or feed by stor- g of SPIKE age or disposal. Open dumping is prohib. 80W were placed in the eyes of rabbits. iced. Do not reuse empty container. Dis- B. Skin Pose in an incinerator or landfill approved for pesticide containers or bury in a non. No skin irritation or other toxicity was per k cropland area away from desirable plants, observed when 2 9 of SPIKE 80W P 9 trees and supply. �of body weight were applied to the shaved backs of rabbits for 24 hours. B. Precautions C. Inhalation 1. Human Rats were exposed to 1.37 mg of SPIKE Harmful if swallowed. Avoid contact- BOW per liter of air and observed for 14 with skin, eyes or clothing. Avoid in- days. This treatment caused only mild haling dust from product. In case of transient effects. contact,flush with water. D. Ingestion 2. Environmantal Rats were given a single oral dose of 500 Do not contaminate any body of mg of SPIKE 80W per kg of body weight water, ponds or streams as death or and observed for 14 days. This treatment injury may occur to vegetation irri- caused no adverse effects, gated by such. Do not contaminate water by cleaning of equipment or E. Chronic Exposure disposal of wastes. Large dietary concentrations of technical X. REFERENCES tebuthiuron, the active ingred;ent of SPIKE 80W, were fed to mice and rats for (1) July, 1978 NIOSH Certified Equipment two years. No carcinogenic or important Guide. chronic effects were observed. NOTE: This information applies only to SPIKE 80by VIII. FIRST AID/HEALTH • sold in the U.S. � A. Eyes Flush with large amounts of water and contact a physician if irritation develops. B. Skin Wash exposed areas with soap and water. Wash all contaminated clothes before re- use. C. Inhalation If discomfort occurs, move to fresh air. If breathing difficulty occurs, start mouth. to-mouth artificial respiration and con- tact a physician. D. Ingestion Contact a physician immediately. If swal- lowed, induce vomiting by tickling the back of the throat with a finger or a blunt object. If necessary give syrup of ipecac: Children 1 to 5 years 15 ml (1 tablespoon, 1/2 oz) Adults and older children 15-30 ml (2 tablespoons, 1 oz) Then give at least 10 oz of water to chil- dren and 24 cz to adults. SPIKE) (tebuthiuron, Elanco) February, 1980 Revised, May 1980 Revised December, 1980 "�` ,—}a ''a':. �� i,:.- ter•. .-..., � i=:, "• ,� ` — ��Z�� h2- - ��1 J��"�S'i.G.Yi-C �.._rt � � .f ✓'TWv.+�i= `� '%s.�.�;.'. `�%+w y � S "KRENITE" BRUSH CONTROL AGENT MANUFACTURER: E. I. DU PONT DE NEMOURS & CO. (INC. BIOCHEMICALS DEPARTMENT ) _ WILMINGTON, DELAWARE 19898 ' t FOR CHEMICAL EMERGENCY: CALL CHEMTREC TOLL FREE DAY OR NIGHT (800) 424-9300 -- WORLDWIDE (202) 483-7616 OR CALL DU PONT (302) 774-2421 Active Ingredient: Fosamine Ammonium [Ethyl hydrogen (aminocarbonyl)phosphonate]. .... .. 41.5% Inert Ingredients. . . . . . . .. .. . . . .. . • SECTION I - PHYSICAL DATA Physical Form: Dark brown liquid Vapor Pressure: Negligible Solubility in Water: Miscible Specific Gravity: Approximately 10.4 lbs./gallon a SECTION II - HEALTH HAZARDS Statement *of Hazards: CAUTION! May irritate eyes, nose, throat, and skin. Precautionary Measures: Avoid breathing spray or mist. Avoid contact with skin, eyes, and clothing. First If in eyes, flush with plenty of water. If on skin, wash with plenty of soap and water. NOTICE FROM OU PONT THE INFORMATION CONTAINED HEREIN IS OFFERED ONLY AS A GUIDE TO THE HANDLING CF THIS SPECIFIC MATERIAL. SINCE SUCH INFORMATION DOES NOT RELATE TO USE OF THE 4MATERIAL WITH ANY OTHER MATERIAL OR IN ANY PROCESS, ANY PERSON USING THIS INFORMATION MUST DETERMINE ITS' SUITABILITY FOR ANY PARTICULAR APPLICATION. 8-22721 �. DATE: June, 1983 Material Safety Data Sheet for -� "Krenite" Brush Control Agent Page 2 of 3 • SECTION II - HEALTH HAZAltOS (Cont 'd) Acute Ural LUSU (slats): 2440U mg/kg Exposure Limits: Not yet established. _ Spill or Leak Procedure: Clean up promptly. Do not flush with water. Absorb spills with earth, sand, or other absorbent material; clean up promptly by scoop or vacuum. Package this material in plastic lined fibre drums, plastic or metal containers and dispose of according to applicable Federal, state or local procedures. If spill area is on ground near trees or other valuable plants, remove top two inches of soil after initial cleanup. • SECTION III - FIRE HAZARDS Flash Point: Greater than 200OF (closed cup). N.F.P.A. Classification - Class III B combustible liquid. Statement of Hazard: Non-flammable Fire Fiahtina/Extinquishinq Media: On fire, use dry chemical, carbon dioxide, halon, foam or water spray. Cool exposed containers with water. If area is heavily exposed to fire, and if conditions permit, let fire burn itself out since water may increase the area contaminated. Wear self-contained breathing apparatus and appropriate protecti fire fighting and cleanup. . .see SECTION II - HEALTHHAZARDsVe equipment for • SECTION IV - REACTIVITY Under Normal Conditions: Stable Hazardous Decomposition Product(s): None • SECTION V - TRANSPORTATION STORAGE ADO DISPOSAL Transportation: Not regulated under D.U.T. Freight Classification: Weed Killing Compound, N.U. I.B.N. Storage: Keep out of reach of children. Do not contaminate water, food, or feed by storage. Keep from contact with fertilizers, insecticides, fungicides, and seeds. 2. I -- I Material Safety Data Sheet for "Krenite" Brush Control Agent Page 3 of 3 • SECTION V - TRANSPORTATION STORAGE AtD DISPO A S L (Cont d) Pesticide Ui ;pusal: Pesticide, spray mixture or rinse water that cannot be used according to label instructions must be dis posed of according to ap plicable Federal, state or local procedures. Do not contaminate water, food, or feed by disposal. Container Disposal: Triple rinse (or equivalent) and dispose of in sanitary landfill or by incineration (for plastic jugs) if permitted byState and local authorities. Do not re-use container.- Special Precautions: Do not use on food crops. Do not allow drift or spray mist to contact desirable trees, shrubs, or other plants, as injury may result. Do not apply directly to water. Do not contaminate water by cleaning of equipment or disposal of wastes. o SECTION VI - SPECIAL PROTECTION INFORMATION Personal Protective Equipment: Use with adequate ventilation. Wash r thoroughly after handling. t= M A T E R I A L A F, E T Y Ii A T A H E E T F'a► E' : ,DOU CHEMICAL U.S.A. MIDLAND MICHIGFIN 4,0674 EMERGENC) FlioNiE: Si7-E36-4400 EFFECTIVE DATE : 14 JAN 85 DATE PRINTED: 1 AU"' 85 PRODUCT CODE: 33321 PRODUCT NIAME. GARLON (R) 3A HERBICIDE MSD : CC 6-71 INGREDIENTS (TYPICAL VALUE- SPECIFIC ATI0;11 ) 7 TRICLOPYF;((t (3 , 5 . 6-TF;ICHLOF:O-2-F'YF:IDI�4YL)OXY!ACETIC ACID) , TRIETHYLAMINE SALT EMULSIFIERS, WATER, AND METHANOL (Q.7X) 44.4 55.6 SECTION 1 FH Y SIC:AL DATA BOILING POINT : NOT 'DETERMINED : SOL. It! tlATER : HIGH (EMULSIFIES) VAF' PRESS: NOT DETERMINED : SF'. GRAVITY: i 135 (68;68F) VAP DENSITY (AIR=i ) : NOT APPLIC. : `X VOLATILE FY VOL : LOW A' SRANCE AND ODOR : DARK PURPLE LIQUID. SECTION 2 FIRE AND E);F'LOSIOI! HAZARD DATA FLASH. POINT : i 1 OF , 43C FLAMMABLE LIMITS METHOD USED : TCC LFL_ : NOT DETER. UFL: NOT DETER. EXTINGUISHING MEDIA : ALCOHOL FOAM AND CO2 .SPECIAL FIRE FIGHTING EQUIPMENT AND HAZARDS: IRRITATING VAPORS UNDER FIRE CONDITIONS. USE POSITIVE PRESSURE SELF-CONTAINED BREATHING . EQUIPMENT. SECTION 3 REACTIVITY DATA TABILITY: COMBUSTIBLE, AVOII) SOURCES OF IGNITION IF TEMPERATURE IS NEAR OR ABOVE FLASH POINT. .NCOMPATIBILITY : ANY OXIDIZING AGENT. CONSULT MANUFACTURER FOR SPECIFIC CASES. l►l7_ARI)OUS DECOMPOSITION PRODUCTS: IRRITATING VAPORS UNDER FIRE CONDITIONS. ,_'-p"g:DOUS POLYMERIZATION: WILL NOT OCCUR. L% N U E D ON PAGE ) R, DICAA.`•' A TRADEMARK' OF THE DOW CHEMICAL COMPANY M A T E R I A L S A F E T Y D A TEA S H E E T PAGE : 2 DW CHEMICAL U.S.A. MIDLAND MICHIGAN 48674 EMERGENCY PHONE: 517--636—•4400 =FECTIVE DATE : 14 JAN 85 DATE PRINTED : 1 AUG . 85. PRODUCT CODE: 38321 ,UCT (CONT ' D) : GARLON (R) 3A HERBICIDE MSD : 0639 � _CTION 4 SPILL , LEAK. , AND. DISPOSAL PROCEDURES :TION TO TAKE FOR SPTl_LS: LIKE LARGE SPILLS. KEEP OUT OF STREAMS AND DOMESTIC WATER SUPPLIES. ABSORB SMALL SP ILLS IN ItdERT MATERIAL SUCH AS :SAND. SPOSAL METHOD : IN CASE OF LARGE SPILLS, CONTACT THE DOW CHEMICAL COMPANY. BURY CLEAN—UP -MATERIAL FROM SMALL SPILLS IN NON—CROP AREA AWAY FROM WATER SUPPLIES, IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. SECTION 5 HEALTH HAZARD DATA E: MAY CAUSE SEVERE IRRITATION -WITH CORNEAL INJURY WHICH MAY RESULT IN PERMANENT IMPAIRMENT OF VISION, EVEN BLINDNESS. IN ANIMALS, IRRITATION HEALED WITHIN 14 DAYS, BUT THE CORNEAL INJURY • DID NOT HEAL_ IN 21 DAYS. WHEN TESTED ON ANIMALS, DILUTIONS OF -THIS IATERIAL WERE LESS IRRITATING TO EYES THAN THE UNDILUTED PRODUCT. LN CONTACT : PROLONGED OR REPEATED EXPOSURE MAY CAUSE SKIN IRRITATION, _VEN A: BURN. WHEN TESTED ON ANIMALS, DILUTIONS OF THIS MATERIAL WERE _ESS IRRITATING TO 'SKIN THAN THE UNDILUTED PRODUCT. Al'rFTc•T•ION : NOT LIKELY TO BE AREOF:BED THROUGH SKIN IN HARMFUL .Al S FOLLOWING A SINGLE PROLONGED SKIN EXPOSURE. THE LD50 FOR f 'I;: BSORPTION IN RABBITS IS >3980 MG/KG. ESTION: SINGLE DOSE ORAL TOXICITY IS LOU. THE ORAL LD50 FOR ALE RATS WAS 2-830 MG/KG. Al_ATION: VAPORS ARE UNLIKELY DUE 1-0 PHYSICAL PROPERTIES. TEMIC 1, OTHER EFFECTS : EXCESSIVE EXPOSURE MAY CAUSE LIVER OR KIDNEY 7FECTS. NO CARCINOGENIC EFFECTS HAVE }`EEN' SEEN IN LONt—TERM ANIMAL' TUDIES. BIRTH DEFECTS -ARE UNLIKELY. EVEN EXPOSURES HAVING AN ADVERSE =FECT ON THE MOTHER SHOULD HAVE 140 EFFECT ON THE FETUS. IN ANIMAL FUDIES, HAS BEEN SHOWN NOT TO INTERFERE WITH REPRODUCTION. RESULTS IN VITRO ( 'TEST TUBE' ) MUTAGENICITY TESTS HAVE BEEN NEGATIVE. =SULTS OF MUTAGENICITY TESTS IN ANIMALS HAVE BEEN NEGATIVE. SECTION 6 FIRST AID IRRIGATE WITH FLOIJING WATER IMMEDIATELY AN'D CONTINUOUSLY FOR MINUTES. C014SUI_T MEDICAL PERSONNEL. WASH OFF IN FLOWING WATER OR SHOWER. CLOTHING : REMOVE NTAMINATEI> CLOTHING AND WASH FIEF-ORE REUSE. DO NOT INDUCE VOMITING . GIVE LARGE AMOUNTS OF WATER OR LK AVAILABLE AND TRANSPORT TO MEDICAL FACILITY. _y _ATION : NO ADVERSE EFFECTS ANTICIPATED BY' " 'THIS ROUTE OF EXPOSURE.' FINUED ON PAGE 3 ) 'NDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY M A T E R I A L S A F E T Y D A T A S H E E T PAGE: 3 l' jICAL U.S.A. MIDLAND MICHIGAN 48674 EMERGENCY PHONE : 517-636-4400 �TIVE DATE: 14 JAN 85 DATE PRINTED : 1 AUG 85 PRODUCT CODE: 38321 vUCT (CONT 'D) : GARLON (R) 3A HERBICIDE MSD: 0639 SECTION 6 FIRST AID (CONTINUED) r TO PHYSICIAN: THE DECISION OF WHETHER TO INDUCE VOMITING OR NOT SHOULD BE MADE BY AN ATTENDING PHYSICIAN. IF BURN IS PRESENT, TREAT AS. ANY THERMAL BURN, -AFTER DECONTAMINATION. NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT EASED ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. SECTION 7 SPECIAL_ HANDLING, INFORMATION EXPOSURE GUIDELINE(S) : DOW INDUSTRIAL HYGIENE GUIP.E IS 10 MG/M3 FOR . TRICLOPYR. ACGIH TLV AND OSHA PEL ARE 200 PPM FOR METHANOL. VENTILATION: CONTROL AIRBORNE CONCENTRATIONS BELOW THE EXPOSURE GUIDELINE. GOOD GENERAL VENTILATION SUFFICIENT FOR MOST CONDITIONS. LOCAL EXHAUST VENTILATION MAY BE NECESSARY FOR SOME OPERATIONS. RESPIRATORY PROTECTION : ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR HANDLING THE CONCENTRATE UNDER CERTAIN OPERATIONS, USE A NIOSH APPROVED AIR- PURIFYING RESPIRATOR. PROTECTIVE CLOTHING : FOR BRIEF CONTACT, NO PRECAUTIONS OTHER THAN "' EAR! BODY-COVERING CLOTHING SHOULI) FE NEEDED. USE IMPERVIOUS f DVES WHEN PROLONGED OR FREQUENTLY REPEATED CONTACT WITH THE 1ENTRATE COULD OCCUR. =Yw rr;OTECTION: USE CHEMICAL GOGGLES WHEN HANDLING THE CONCENTRATE. EYE WASH FOUNTAIN SHOULD BE LOCATED IN IMMEDIATE WORT: AREA. SECTION 8 SPECIAL PRECAUTIONS AND ADDITIONAL INFORMATION 'RECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: SEE LABEL. AVOID BREATHING SPRAY 'MIET.- DO NOT SWALLOW. AVOID SKIN CONTACT. PREVENT EYE CONTACT. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM CHILDREN. DO NOT CONTAMINATE DOMESTIC WATER SUPPLIES OR WATER USED FOR IRRIGATION. DDITIONAL INFORMATION : REVISED SECTIONS 2, 3, 5, 6, 7. 1) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY LAST PAGE IE INFORMATION HEREIN IS GIVEN IN COOP. FAITH, BUT NO WARRANTY, <PRESSED OR IMPLIED,- IS MADE. *CONSULT THE DOW CHEMICAL COMPANY IR FURTHER INFORMATION. i 1 f I M A T E R I A L S A F E T Y D A T A S H E E T PAGE : 1 DOW CHEMICAL U.S.A. MIDLAND MICHIGAN 48674 EMERGENCY PHONE: 517-636-4400 EFFECTIVE DATE : 30 JUL 85 DATE PRINTED : i AUG 85 PRODUCT CODE: 33322 PRODUCT NAME : GARLON (R) 4 HERBICIDE MSD : 1314 INGREDIENTS (TYPICAL VALUES-NOT SPECIFICATIONS) TRICLOPYRI (3, 5, 6-TRICHLORO-2-PYRIDINYL)OXY !ACETIC ACID, BUTOXY ETHYL_ ESTER, CAST L4700-50-7 : 61 .6 ; INERT INGREDIENTS : 38.4 KEROSENE, CAST SOOS-20-6 2-BUTOXYETHANOL , CAST i11 -76-2 PROPRIETARY INGREDIENTS SUBSTANCES LISTED IN THE INGREDIENTS SECTION ARE THOSE IDENTIFIED, AS BEING PRESENT AT A CONCENTRATION OF 1% OR GREATER, OR 0. 1 /. IF THE SUBSTANCE IS ON THE LIST OF POTENTIAL CARCINOGENS CITED IN OSHA HAZARD COMMUNICATION STANDARD. WHERE PROPRIETARY INGREDIENT 1;-- SHOWS, THE IDENTITY OF THIS SUBSTANCE MAY BE MADE AVAILABLE AS PROVIDED IN 29 CFR 1910. 1200( I ) . SECTION 1 PHYSICAL DATA BOILING POINT: >302F, 150C INITIAL : SOL. IN WATER : - EMULSIFIES VAP PRESS: 0. 1 MM @ 37.8C (KEROSENE) : SP. GRAVITY : 1 .08 VAP DENSITY (AIR=1 ) : >1 X VOLATILE BY VOL: 33 APPEARANCE AND ODOR : AMBER LIQUID SECTION 2 FIRE AND EXPLOSION HAZARD DATA . FLASH POINT : 147F, 64C FLAMMABLE LIMITS METHOD USED : TCC LFL: NOT DETER. UFL : NOT DETER. EXTINGUISHING MEDIA : WATER FOG, F PECIAL FIRE FIGHTING EQUIPMENT ANI) HAZARDS: USE POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS_ IRRITATING VAPORS MAY BE PRODUCED UNDER FIFE CONDITIONS. SECTION 3 REACTIVITY DATA STABILITY : COMBUSTIBLE . AVOID SOURCES OF IGNITION IF TEMPERATURE t-, NEAR OR ABOVE FLASH POINT. C HUED .iN PAGE 2 ) ;R) NDICATES A TRADEMARK OF THE: DOW CHEMICAL_ COMPANY II ty i G n I H L G A F E T Y D A T ,A S H E E T PAGE: 2 )OW CHEMICAL_ U.S.A. MIDLAND MICHIGAN 48674 EMERGENCY PHONE: 517-636-4400 :FFECTIVE DATE : 30 JUL 85 DATE PRINTED : 1 AUG 85 PRODUCT CODE: 38322 DUCT (CONT 'D) : GARLON (R) 4 HERBICIDE MSD : 1314 � SECTION 3 REACTIVITY DATA (CONTINUED) N 'ATIBILITY: ACID, RASE, AND OXIDIZING MATERIAL. iAZARDOUE DECOMPOSITION PRODUCTS : TIITROGEN OXIDES, HYDROGEN CHLORIDE, AND PHOSGENE MAY RESULT UNDER FIRE CONDITIONS. AZARDOUS POLYMERIZATION:. WILL NOT OCCUR SECTION 4 SPILL, LEAF; , AND DISPOSAL PROCEDURES CTION TO TAKE FOR SPILLS: DIKE LARGE SPILLS. KEEP OUT OF STREAMS AND DOMESTIC WATER SUPPLIES. ABSORB SMALL SPILLS IN INERT MATERIAL SUCH AS SAND. ISPOSAL METHOD : IN CASE OF LARGE SPILLS, CONTACT THE DOW CHEMICAL - COMPANY. BURY CLEAN—UP MATERIAL FROM SMALL SPILLS IN -AN .APPROVED LA14DFILL IN ACCORDANCE WITH APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. SECTION 5: HEALTH HAZARD DATA rE : ESSENTIALLY NONIRRITATING -TO EYES. .d CONTACT : PROLONGED OR -REPEATED EXPOSURE MAY CAUSE. SKIN IRRITATION. 'I1 SORPTION : A SINGLE PROLONGED EXPOSURE IS NOT 'LI'KELY TO RESULT 11 E MATERIAL BEING ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. THE LD50 FOR SKIN ABSORPTION IN RABBITS IS ::>3980 )iG/KG. REPEATED SKIN ABSORPTION MAY RESULT IN ABSORPTION OF HARMFUL AMOUNTS, GESTION: SINGLE DOSE ORAL TOXICITY :IS LOW. THE .ORAL- LD50 •FOR MALE RATS IS 2460 MG/KG. IF ASPIRATED (LIQ+UID ENTERS THE LUNG) , MAY CAUSE LUNG DAMAGE OR EVEN DEATH DUE TO CHEMICAL PNEUMONIA, A CONDITION CAUSED BY PETROLEUM AND PETROLEUM—LIKE SOLVENTS. -IALAT*ION: EXCESSIVE EXPOSURE MAY CAUSE IRRITATION 1*0 UPPER RESPIRATORY IRACT. SIGNS AND SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE CENTRAL NERVOUS iYSTEM EFFECTS (DUE TO KEROSENE) . _. >TEMIC & OTHER EFFECTS: REPEATED EXCESSIVE EXPOSURES MAY CAUSE LIVER, ;IDNEY OR BLOOD EFFECT'S. DID NOT CAUSE CANCER IN LONG—TERM ANIMAL . l'UDIES. BIRTH DEFECTS ARE UNLIKELY. EXPOSURES HAVING NO EFFECT ON THE {OTHER SHOULD HAVE NO EFFECT ON THE FETUS. DID NOT CAUSE FIRTH DEFECTS N ANIMALS; OTHER EFFECTS WE_F;E SEEN IN THE FETUS ONLY AT DOSES WHICH AUSED TOXIC EFFECTS TO THE MOTHER. THE ACTIVE INGREDIENT IN THIS ORMULATION HAS BEEN SHOWN IN ANIMALS. NOT TO INTERFERE WITH REPRODUCTION; OWE:VER, 2—BUTOXYETHANOL HAS REPORTEDLY PRODUCED TESTICULAR ATROPHY IN AlS AFTER ORAL ADMINISTRATION ONLY. RESULTS OF IN VITRO ( 'TEST TUBE' ) TAGENICITY TESTS HAVE BEEN NEGATIVE. RESULTS OF MUTAGENICITY TESTS IN NI'" - HAVE PEEN NEGATIVE. NTjnuL'D ON PAGE3 ) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY M A T E R I A L S A F E T Y D A T A S H E E T PAGE : 3 AEMICAL_ U.S.A. MIDLAND MICHIGAN 48674 EMERGENCY PHONE: 517-636-4400 ECTIVE -DAT-E : 30 JUL 85 DATE PRINTED : 1 AUG 85 PRODUCT CODE: 38322 , IICT (CONT 'D) : GARLON (R) 4 HERBICIDE MSD : 1314 SECTION 6 FIRST AID E IRRIGATE IMMEDIATELY WITH WATER FOR AT LEAST 5 MINUTES. SKIN : WASH OFF IN FLOWING WATER OR 'SHOWER. INGESTION : DO NOT INDUCE VOMITING. CALL A PHYSICIAN AND/OR TRANSPORT TO EMERGENCY FACILITY IMMEDIATELY. INHALATION : REMOVE TO FRESH AIR IF EFFECTS OCCUR. CONSULT A PHYSICIAN. NOTE TO PHYSICIAN : THE DECISION OF WHETHER TO INDUCE VOMITING OR NOT SHOULD BE MADE BY AN ATTENDING, PHYSICIAN. IF LAVAGE IS PERFORMED, SUGGEST ENDOTRACHEAL AND/OR ESOPHAGEAL CONTROL. DANGER FROM LUNG ASPIRATION MUST BE WEIGHED AGAINST TOXICITY WHEN CONSIDERING EMPTYING THE STOMACH. NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. SECTION 7 SPECIAL HANDLING INFORMATION EXPOSURE GUIDELINE(S) : DOW INDUSTRIAL HYGIENE GUIDE IS 10 MG/M3 FOR TRICLOPYR. DOW INDUSTRIAL HYGIENE GUIDE IS 10 MG/M3 FOR KEROSENE. V;_'ff, IL'ATION : LOCAL EXHAUST VENTILATION MAY BE NECESSARY FOR SOME n"I'ATIONS. ;E_. _.,ATORY PROTECTION : ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR CERTAIN OPERATIONS, USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR OR PESTICIDE CARTRIDGE. 'ROTECTIVE CLOTHING : FOR BRIEF CONTACT, NO PRECAUTIONS OTHER THAN CLEAN BODY-COVERING CLOTHING SHOULD BE NEEDED. USE GLOVES WHICH ARE PERMEATION RESISTANT WHEN PROLONGED OR FREQUENTLY REPEATED CONTACT COULD OCCUR. EXAMPLES OF EFFECTIVE PROTECTIVE CLOTHING MATERIALS ARE NEOPRENE, NITRILE BUTADIENE RUBBER, AND VITON. YE PROTECTION : USE SAFETY GLASSES. SECTION 8 SPECIAL PRECAUTIONS AND ADDITIONAL INFORMATION RECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE : . KEEP OUT OF REACH OF CHILDREN. DO NOT USE NEAR HEAT OR OPEN FLAME. AVOID C014TACT WITH EYES, SKIN OR CLOTHING . DO NOT SHIP OR STORE WITH FOOD, FEEDS, DRUGS, OR CLOTHING. DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL. )DITIONAL 1147 u,-;;;h;iCN : REVISED INGREDIENTS AND SECTIONS 1 , 2, 3, 4, 5, 7, AND 8. :Oi LIED ON PAGE 4 > i) ICATEt A TRADEMARK OF THE DOW CHEMICAL COMPANY M A T E •R I A' L S A F E T Y . D A T A S H- E E To PAGE:' 4 lW CHEMICAL.'U.'S.A. MIDLAND :MICHIGAN 48674 EMERGENCY PHONE: 517—L36-4400 'FECTIVE DATE:' 30 JUL" 85 DATE PRINTED : 1 AUG-85 • '' PRODUCT CODE: 38322 — —• )UCT (CONT 'D) : GARLON (R) 4 HERBICIDE - MSD : 1314 LAST F'AGE -- :) QlCA' TES A TRADEMARK OF THE DOW CHEMICAL COMPANY IE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT .NO WARRANTY, 'PRESSED OR IMPLIED, IS MADE. CONSULT THE DOW CHEMICAL COMPANY R FURTHER INFORMATION. ' . ` C Date:October 15, 1985 1 Supersedes: March 15, 1979 BANVELO HERSIC,,DE Material Safety Data Sheet The informatic n provided herein. is a li cabl ! .Fp a an. If G' BANVELO HERBICIDE y 'f l as marufaclired byrfcr Velsical Chemical Ccrpera-ton, Velsicol Chemical Corporation Product/Material BANVEL`0HERSICIDE Manufacturer, Vetsicol Chemical Corporation Address 341 East Chi*Street,Chicago,Illinois 6051', EMERGENCY PHONE 3121670-45CO L Product Information Trade Name BANVELOF;ERB1CIDE,BANVEL 0 4S and BANVEL04WS Synonyms None known Ac'ive Ingredient Dimethylamine sait cf cicar,.ca Chemical Family Substituted benzoic ac:d Chemical Formula Mixture CAS Registry Number 2300-66-5(Active Ingredient; DO T Hazard Class Not regulat-ed /I. Health/SafetyAlert WARNING HARkIFUL IF SWALLO';/ED. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. III. First Aid Procedures Eye Flush eyes with tap water fcr at least 15 minutes. Consult an cpthalmo;og;st. Skin Nash with mild soap and water. Rinse with copious amounts of water. Launder clothing thoroughly before reuse. Ingestion Drink 1 or 2 glasses of water. Induce vomiting by touching back of throat with finger or b!urt object. Do not induce vomiting or give anything by mouth to an urc-onscious person.. Consult u physician. Inhalation Remove to fresh air. Apply artificial respiration + if necessary. Cor-suit a pnysici3n. IN ALL CASES OF EMERGENCY CONTACT A PHYSMA,`/. Page 2 of 4 BANVEL®XE -RIrCr1E IV. Note to FySician Treatment is symptomatic. For ingestion,lavage stomach with tap water. Instill 30 gm activated charcoal in 3-4 oz of water. Catharsis with 15 gm sodium sulfate in 6-8 oz of water. V. Fire&Ezp osr'on Inlormaticn Explosive Limits Lower. Not applicable Upper. Not applicable Flammability Non-flammable Flash Point No flash point noticed up to 20011F Extinguishing Media Water spray,foam,dry chemical,CO? Special Protective Equipment In case of severe fire involving dicamba sclution, protective,:lothing and self-contained breathing apparatus should be wom. Special Fire Fighting Procedures Use water to keep fire exposed containers cool. At first opportunity,remove from fire. Products of Combustion May yield steam,dicamba amine salt,HCI, organochloride products,oxides of nitrogen, carbon monoxide. Unusual Fire and Explosion Hazards Drums may burst as a result of steam being generated. Vl. Spill Ccntrol& Cleanup Steps to be taken Contain spill and absorb with clay granules, sawdust or equivalent. Co!lect and place in suitable container for disposal. Area can be washed down with water and detergent to remove remaining herbicide. DO NOT ALLOW WASHINGS IN SEWER. Absorbents Clay granules,sawdust or dirt Counteractants Not applicable Incompatables None known Reportable Quantity 1000 Its.of dicarrba { • �t i \ Pa e304 9 P.ANVEL HEP.BlCIDE V11. Product/Waste Disposal Incinerate rod p uctrNaste at a U.S.E?Apermittedwaste incinerator. I VI11. Special Precautions Storage Keep in an area suitable for pesticide storage. Store in a cool,ventilated area away from seed, fertilizers,insectiddesorfungicides. Keep away from children,wildlife,domestic animals, and pets. IX. Health Hazard Information Primary Route(s)of Entry Oral: No Inhalation: Yes Dermal/Eye: Yes Carcinogen as determined by: NTP: No IARC: No I OSHA:No Signs and Symptoms of Acute Overexposure Nonspecific. Symptoms may include exhaustion,muscular spasms,urinary incontinence,dyspnea and cyanosis. Severe eye damage may occur. Skin irritation may occur. Acute Toxicity: Oral The acute oral toxicity(LDco)in rats has been reported to be 2529 rrgt}cg. Dermal The acute dermal toxicity(LD50)in rabbits has been reported to be>2000 mg/kg. Inhalation The acLge inhalation toxicity(LD50)in rats has been reported to be>200 mgliter(nominal concentration)for a 4-hour exposure. Other Toxicological Information Skin Irritation: Mildly to moderately irr„ating to the skin of rabbits but not a primary ski„ irritant. Eye Irritation: Extremely irritating and ray be corrosive to the eyes of rabbits. Other Repeated high levels of dermal exposure to rabbits has resulted in skin irritation and toxicity. The liver,kidney and lung appe::r to be the most sensitive organs affected fro,;, repeated oral,dermal,and inhalation exposures in experimental animals. C Page 4 or 4 BAIWELZ HERBICIDE Health Hazard Information(cunt) Other(continued) Dicamba,the active ingredient in BANVELO HERBICIDE,has been studied extensively to determine potential health effects. Animal experimentation with dcamba has not demon- strated any carcinogenic,teratogenic or other reproductive effects with the exception of slightly reduced fetal body weights and post- implantation losses reported at the Maximum Tolerated Dose level. The preponderance of experimental data suggests dicamba is net a X. Recommended General mutagen. Precautions Personal Protective Equipment q pment Under normal conditions of use,respiratory protection is not required. In cases where inhalation is likely,a MSHANIOSH approved respirator for pesticides is recommended. in cases where eye and skin contact are likely, use of chemical safety goggles,impermeable XI. Product Information- 9bVes,and clean,body-covering clothing are Hazardous Ingredients recommended. NFPA Rating Health: 1,Fire: 0, Reactivity:0, ; Special Properties: None Exposure Limits OSHA PEL, Not established ACGIH TLV: Not established HIOSH Limit: Not established Hazardous Ingredient(s) Dimethylamine salt of dicamba(3,6-dichtoro-4- (As defined by OSHA) anisic acid),48.2%;TLV: Not established Dimethylamine salt of related ac:ds,120%;TLV: Not established X11. Physical and Chemical Information. Dimethylamine,17%;TLV: 10 ppm Appearance and Odor Amber solution,mild amine odor Molecular Weight Not applicable Boiling Point 212"F Melting Point Not determined Vapor Pressure 18 mmHg as water@ 68° Vapor Density >1.0(Air=1) Specific Gravity 1.190 @a 21°C(H20=1) Solubility Miscible in water Evaporation Rate Unknown Stability Stable Reactivity Not applicable Decomposition Products None Xlll. Regulatory Status Regulated by EPA under FIFRA,Clean WaterAct and CERCL4(Superfun . The inlamJAOn "sensed heeein, wh,10 not guamn.'eed, was dared by te<'r►cay knowfaCseath,�ersc++nel and to a bast c/our luxes+ axsrate. It a rot nfernded 17 ba all i x4uslve and�9 manner and cm,uans of usa and Aanclrrt may mvo vs oV er oraddand t c to best Cf aya i+ 1 n and Da-: Cctober 15,1985 Supersedes: January 20,1sat WEEDI'd4STER1,-ER91C10E Material Safety Data Sheet The infonnacen crc:ded herein is applicable only b ++� WEEOPAASIE," Z;Rsicl[)E i I d as manufac:�red tplcr Velsi=l Chemical Cor,>oraCen. Velsicol Chemical Corporation Prpduct/Material WE=DMAS,- .1) ci61CIGE Manufacturer Velsicol Chem,Cai Corcorat,' n Address 341 East Chio S;, ,Chicago, Illinois 6061; EMERGENCY PHONE 312/670-4500 L Prccru&,,Irformat,cn Trade Name WEEDMAS T E-,-')HERSICIDE Synonyms WEEDMAS T== Active-Ingredient DMA Salt cf cCz,,.ha CMA Sait of 2,4-D Chemical Famiiy Mixture of;uh:,tiutedCniorinatedE✓enzc;C acid and phercxvacetic acid. Chernical Formula Mixture CAS Registry Number 2300-66-5(DPA.A Sat of dicamba) 2008-39-1 V,s.Sax'of 2.4-D) COT Hazard Class Not recuia: ll. HealthlSafetyAlert CAUTICN MAY 6E HARMFUL IF EATEN OR SWALLOWED. AVOID CONTACT - - - WITH SKIP, EYES AND CLOTHING. 111. FirstA;cl Procec'ures Eye Flush eyes:vith tap water for at!eas,15 minutes. Cep;;;;an opthalmclogist. Skin Wash with ri!d soap and water. nirsE 1:i;h c=pious arncur•,ts of,eater. Launder C!oii.inG thoroughly beicre ruse. Ingestion Drink 1 or 2 glares of;eater. Induce v b �,uchir Y.•^ g�ac!t..f ti^,rcat:with firceror;,;�;,; oC,ect. Do pet:rd,'Ca vcm3irg crgive anyrhi^g by rrc;.-t`:o an unconscious�er� Consuit a Physician. • Inhalation Ferrlcve tc fresh;air Accl if necessary. Y artificial reSFirton Ccrsuit a physcian. 'IN ALL CASES OF E"ME:RGENCY CONTACT A PHYSICIAN. i Page 2 of 4 WE'EDMASTr�jZ HEq&C',DE IV. Note to Pysiclan '1 Treatment is symptomatic. For ingestion,lavage stomach with tap water. Instill 30 gm activated charcoal in 3-4 oz of water. Catharsis with 15 gm sodium sulfate in 6-8 cz of water. V. Fire&Exploslcn information Fxplosive Limits Lcwer. Notapplica-cte Upper: Not applicable Flammabili;;r Ncn-;iarns;,abla Fiash Point. Cc es not flash : Extinguishing Media Water spray,foam,drychen.cal,CO2 Special Protective Equipment in case of severe fire,protective clothing and seif-contained breathing apparatus sh,oufd be worn. Special Fire Fighting Procedures If the provided container is intact,wet down w'th water to prevent overheating. Al first opportunity remove from fire. Products of Combustion May yield steam,dicamba amine salt,2,4-D amine salt, NCI,organcchlcride products. Oxides of nitrogen,carbon monoxide. Unusual F1ro and Exploslcn Hazsrdz. Drums may burst as a result of steam being generated. Vl. Spill Control & Cleanup Steps to be taken Contain spill and absorb witth c!av grarules, sawdust,or ecuivalenL Collect and place in suitable container for disposal. Area can be washed down with water and detergent to remove remaining herbicide. DO NOT ALLOW WASHINGS IN SEWERS. Absorbents Clay granules,sawdust,ordi;t Ccunteractants Nct applicable lncompatables Ncne known a Reportable Cuantity 1 COO its,cf dicamba and/or 1010 Its.of 2,4-D CPape 3&4 WEEDMASTERZ HEPBICIDE Vll. Product/Waste Disposal Incinerate producthvaste at a U.S.EPA permitted waste incinerator. VIIi. Special Precautions t - Storage Keep in an area suitable for pesticide storage. Store in a cool,ventilated area away from seed, fertilizers,insecticides or fungicides. Keep away from children,wildlife,domestic animals, and pets. iX. Health Hazard In(crmation Primary Route(s)of Entry Oral: No Inhalation: Yes Dermal/Eye: Yes Carcinogen as determined by: NTP: No IARC: No OSHA: No Signs and Symptoms of Acute Overexposure Nonspecific. Symptoms may include exhaustion,muscuiar spasms,muscular weakness,urinary incontinence,dyspnea and cyanosis. Acute Toxicity-: Oral -The acute oral toxicity(LD50)in rats has been reported to be>5,000 mgikg. Dermal The acute dermal toxicity(LD50)in rabbits has been reported to be>20,000 mg/kg. inhalation The acute inhalation toxicity(LD50)in rats has - been reported to be>20.3 mc✓lher(4 hour - exposure). Other Toxicological Information Skin Irritation: Minimally irritating to the skin. - •Eye irritation: Minimally irritating to the eye. ' Other Dicamba,one of he active ingredients in WEEDMASTERHERBICIDE,has been studied extensively to determine potential health effects. Animal experimentation with dicamba has not demonstrated arty carcinogenic,teratogenic or other reproductive effects with the exception of slightly reduced fetal body weights and post- implantation losses reported at the Maximum Tolerated Dose level. The preponderance of experimental data suggests dicamba is not a mutagen. I Page 4 of 4 WEpU4S7ERZ - HERB!C1DE Health Hazard Information(cant) t Other(continued) 2,4-D,another active ingredierrt in WEEDMASTERO HER BICIDE,has also been studied extensively. Results of animal experimentation have demonstrated irritation of the stomach and some liver and kidney injury from repeated dose exposure. Peripheral neuritus has been reported from heavy occupational exposure. X. Recommended General Precautions Personal Protective Equipment Under normal conditions of use,respiratory protection is not required. In cases where inhalation is likely,a MSHA/NIOSH approved respirator for pesticides is recommended. In cases where eye and skin 03Mact are likely, use of chemical safety goggles,impermeable Xl. Product Information- gloves,and clean,body-covering clothing are Hazardous Ingredients recommended. NFPA Rating Health: 1,Fire: 0, Reactivity:o, Special Properties: None Exposure Limits OSHA PEL: Not established ACG1H TLV: Not established NIOSH Limit: Not established Hazardous Ingredients) Dimethylamine Salt of Dicar„ba (12.40%) (As defined by OSHA) Dimethylamine Salt of Related Acids (3.1%) Dimethylamine Salt of 2,4-D (35.71/6) TLVs have not been stablished Xll. Physical and Chemical the above hazardous ingredients farany of Information Appearance and Odor Amber solution mild amine odor Molecular Weight Not applicable Boiling Point 212°F(water) Melting Point Not applicable Vapor Pressure -18 mm Hg r7e g80 F Vapor Density >1 Specific Gravity 1.172 @ 200C(1-120-1) Solubility Miscible Evaporation Rate Not known Stability Stable Reactivity Not applicable Decomposition Products None known Xlll. P,egulatoryStatus Regulated by EPA under FIFRA,Clean WaterAci, RCRA and CERCLA (Superfund). The in1*- Uall�jn presenrd herein, w1�7e tact � was gtecared br 1Fd7n,cw/l kncwJ@d--abti Pws mef and bale best cr cur k v arsrale. !t is rnt ntenced b bw all incrsivs ar.c�e marvrer and�01-Vns cl use and hand.,ng may overve QfW aadditional¢nsideranons. eqs;s :vs and r1 —i 1 Union Carbide Agricultural Products Company, Inc. g rr � j ,O"MATERIAL SAFETY DATA SHEET DATE: 11/23/85 PAGE: 1 of 4 Each customer should study this Material Safety Data Sheet and beco-ie aware of the Product hazards., Reference works or personnel who are expert on _ ventilation, toxicology, and fire prevention may have to be consulted to adequately utilize the data contained in this Material Safety Data Sheet. To promote safe handling, each Customer should (1) notify its employees, agents, and contractors of the information on this Material Safety Data -Sheet, and any Product hazards and safety information, (2) furnish a copy of this Material Safety Data Sheet to each- of its customers for the Product, and (3) request such customers to notify their employees and customers for the Product of the information on this Material Safety Data Sheet and any Product hazards and safety information. I. IDENTIFICATION PRODUCT NAME : WEEDARO 64 BROADLEAF HERBICIDE CHEMICAL NAME . 2,4-Dichlorophenoxyacetic acid, dimethylamine salt CHEMICAL FAMILY . Phenoxy FORMULA : C8H6C1203•C2H7N MOLECULAR WEIGHT : 266.12 SYNONYMS : None CAS NUMBER : 2003-39-1 i CAS NAME : Acetic acid, (2,4-dichlorophenoxy)- i compound with N-methylmethaneamine (1:1) II. PHYSICAL DATA BOILING POINT Unknown SPECIFIC GRAVITY 1.161 (Water = 1) APPEARANCE AND ODOR : Clear brown to black liquid with charEcteristic odor EMERGENCY PHONE NUMBER I 1-800-822-4357 ` This number is avail days, nights, weekends, a i Y 9 and holidays. UNION CARBIDE AGRICULTURAL PRODUCTS COMPANY, INC. P.O. Box 12014 • T.W. Alexander Drive Research Triangle Park, NC 27709 (pion �--� Carbide Union Carbide Agricultural Products Company, Inc. OMATERIAL SAFETY DATA SHEET PRODUCT NAME: WEEDAR 64 BRO ADLEAF HER3ICIE CAT_: 11/23/85 PAGE: 2 of 4 II. PHYSICAL DATA (�ONTI`;U�C) FREEEZING POINT . -61C (22°F) - VAPOR DENSITY . (Air = 1) Un-no.,in VAPOR PRESSURE . Unknown SOLUBILITY IN WATER : (% by wt.) lOC' EVAPORATION RATE . (Butyl Ace -,-"* cetate * 1) >1 III. HAZARDOUS MATERIAL CV TLV (Units) HAZ.=.RO 2,4-0, dimethylamine 46.8 salt None established Eyes byOSHA or ACGIH I'/. FIXt AN cf _OS:GY HAZARD UAiA EXTINGUISHING MEDIA . Not Vy111 LJUJrIbI e. Use .ri v a pr priate extin uishing media for material that �, is supolyine fuel . FLA.u.,.ABLE LIMITS IN AIR LF, : None FLASH POINT (Method) None L'L: None SPECIAL FIRE FIGHTING PROCEDURES Wear protective *:clo..�;,n a,. and use self- conta;ned breathing ap ,aratus. UNUSUAL FIRE AND EXPLOSION HAZARDS Material will not supply fuel to a fire. However, if involved in a fire, its products of decorposition can be hazardous. V. HEALTH HAZA.RO GA1A PERMISSIBLE EXPOSURE LIMIT None established by OSHA or ACS:H TOXICOLOGY DATA LDJO oral rat ik ( ) mg, x 1, 15 i :a ACUTE EFFECTS OF OVER EXPOSURE SWALLCWING . Slightly toxic SKIN ABSORPTION Slightly toxic I`iIALATION None expected _ SK J CONTACT Minimally irritating + EYE CONTACT Causes severe eye irritation; causes eye damaee Cn ion Carbide — Union Carbide Agricultural Products Company, Inc. Z7MATERIAL SAFETY DATA SHEET J( PRODUCT NAME: WEEDAR 64 BROACLEAF HERBICIDE DATE: 11/23/85 PAGE: 3 of 4 V. HEALTH HAZARD CATA CONTINUED _ CHRONIC EFFECTS OF OVER EXPOSU'?E None known i OTHER HEALTH HAZARDS None known I EMERGENCY AND FIRST AID PROCEDURES SWALLOWING Induce vomitine. Follow with water or milk. See medical attention. SKIN Wash with scap and water. Remov e and wash contaminated clothing before reuse. INHALATION . Remove to fresh air. EYES : Wash immediately with running minutes. Get medical attention.water for a: least 15 NOTES TO PHYSICIAN . This product will cause tic n and the eyes and no time should los��in�washin damage to thorouchly. _ 9 Y VI. REhCTIViTY CATA STABILITY Stable INCOMPATIBILITY Avoid strong oxidizants' (materials to avoid); HAZARDOUS COMBUSTION OR TI Noxious fumes possible upon expcsure to heat DECOMPOSION PRODUCTS HAZARDOUS POLYMERTZATION Will not occur Union �ar3i:ie Union Carbide Agricultural Products Company Inc. ,Z7NIATERIAL SAFETY .DATA SHEET 7PROCUCTWEEDAR 64 GROACLEAF HER= ;,iuE CATE: 11/23/35 PAGE: 4 of 4 `ail. SPILL Cn L�.;.K PROCEDURES STEPS TO GE TAKEN I= MATERIAL IS RELE-ASED OR SPILLED Dike large spills. Absorb small spills on inert material s.:c., as sand cr vermiculite. Wear appropriate personal protective equipment WASTE DISPOSAL METHOD Dispose in an approved landfill fol1C'rlinC all aoolicable federal , State, and local regulations. YIIi. SPECIAL PRO-ECTiGN INFORMATION RESPIRATORY PROTECTIClV NiOSH/MSNA approved respirator for pesticide mists t VENT1LAT1G'+ -Mechanical (general) Ye.:.ci I i�3tiCn PROTC:TiVE GL�V=S Neoprene cr other impervious gloves�: g e s EYE PROTEr-Ti011; Chemical SaT2tf Q1aSS2S, faCa Shield OTHER PROTE:7711c Protective clothing, eye bath, safety chewer EQUIPMENT Ix. SPECIAL FREC.tiUTIONS PRECAUTICNS TO BE TAKEN IN HANDLING AND STORING Co not store near food, feedstuff, fertilizers, seeds insecticides, _fungicides, or other pesticides. ' OTHER PRECAUTIONS Read and follow label instructions. The opinions expressed herein are those c' qualified experts within Union Carbide Acric:iltural Products Company, inc. We believe that the contained herein is current as of the da*_ of this Safely Data I s Material Sa,ely Data Sheet. Because the use of this information and these opinions and the conditions of use of the Product are not within the control of Union Carbide Agricul turd i P-cc4uc-s CC;30aR i t' 1 y+ Inc. , is 'he user S CLJIiZ3t�On t0 C2ter.ui.i2 the CCndltiCnS Of Sa'_ use of the product. 0104j tea;b Monsanto MATERIAL SAFETY DATA A A Page 1 of 4 ✓ MONSANTO COMPANY MONSANTO PRODUCT NAME 800 N. LINDBERGH BLVD. ��® ST. LOUTS, MO. 63167 Emergency Phone No. HERBf C f n� (Call Collect) 1 D/ 314-69"000 PRODUCT IDENTIFICATION Synonyms: None Chemical Name: Not Applicable, Formulated Product Active Ingredient: 'Isopropylamine salt of Giyphosate . . . . . . . . . . . . ... . . . . . . . . . . . . . Inert Ingredients: . . .. . . . . . . . . . . . . . . . . . . . . . . . . .. . . ............. .. . . . . . . . . . . . . .59.0% 1C0.0°o 'Contains 480 grams per liter or 4 pounds of the active i ingredient isoprcpylamine salt of N-(phosphonomethyl) - glycine per U.S. gallon. Equivalent to 356 grams per liter or 3 pounds per U.S. gallon of the add, glyphosate. CAS Reg. No.: Not Applicable, Formulated Prcduct CAS Reg. No. i Active Ingredient: 38641-94-0 EPA Reg. No.: 524-308-AA DOT Shipping Name: Not Applicable _ r DOT Hazard Class' > D I.D. No.: Not Applicable m DOT Label(s): Not Applicable Hazardous Substance(s)/ RO(s): Not Applicable U.S. Surface Freight Classification: Weed Killing Compound, N.O.I.B.N. WARNING STATEMENTS Keep out of reach of children. WARNING! ZL '~ CAUSES EYE IRRITATION. HARMFUL IF SWALLOWED. See Additional Comments section for Physical or Chemical Hazards. PRECAUTIONARY MEASURES Do not get in eyes, on skin or on clothing. i Avoid contamination of seed, feed and foodstu.fs. t EMERGENCY AND FIRST AID PROCEDURES , FIRST AID: IF 1N EYES, immediately flush with plenty of water for at ;east 15 minutes. Call a physi- I clan. IF ON SKIN, flush with water. Wash clothing before reuse. f, m nto MATERIAL SAFETY DATA P OCCUPATIONAL CONTROL PROCEDURES age 2 of 4 Eye Protectlon: During mixing or pouring operations or other activities in which eye contact with undiluted,Roundup' herbicide is likely to occur, splash goggles should be worn. Skin Protectlon: In case of skin contact, wash exposed area thoroughly. In cases in which pro- longed or repeated skin contact with Roundup herbicide may occur, long- sleeved shirt, long pants and rubber or plastic gloves are recommended. Clothing soaked with Roundup solution should be promptly removed and laundered before reuse. In manufacturing and prccassing operations, the use of a face shield is recom-mended when handling undiluted Roundup herbicide in a pressurized syster-i where equipment failure might result in facial contact with liquid solash or aero- sol spray. Respiratory Protection: Respiratory protection is not required for normal use and handling. Durinc periods of abnormal exposure to heavy spray or mist, use a NIOSH accrcved dusumist respirator. Ventilation: No special precautions recommended. Airborne Exposure Limits: Product: ROUNDUP herbicide— 100% by wt. OSHA PEiJTWA and ACGiH TLV,TWAIS'—,EL not established. FIRE PROTECTION INFORMATION Flash Point (TCC): > 200F. Water-based fcrmularicn, Non-Fiammat Alen-Ccmeustici�—.Extinguishing Media: In case of FIRE, use water spray, foam, dry che: gal or Special Firefighting a Procedures: None. Unusual Fire And I Explosion Hazards: None. 4 PHYSIOLOGICAL EFFECTS SUMMARY - - Oral LDSo (Rat). 5400 mg'kg, practically non-toxic Dermal LD5.) (Rabbit): > 5000 mg/'kg, practically non-toxic - Eye Irritation (Rabbit): (FHSA) Score = 18.4 on a scale - Skin Irritation (Rabbit): (FHSA) Score = 4.3 on a scale off8.0, moderately irritating Inhalation LCSo (Rat): 3.28 m911 for 4 hour aerosol exposure, slightly to--'� irritating Tests on the biologically active ingredient in this formulation gl ch <Q not cause any mutagenic, carcinogenic, teratocenic (birth defec:y;,advers reproductive ate) showed that lychanges,sate dc neurotoxic effects. LU LL PHYSICAL DATA Q Appearanca: Clear, viscous amber-coiored solution. Odor: Practically odorless to slight amine-like odor. 7H: 4 8 pecific Gravity ('Hater.- 1): 1.17 4 OnSanto MATERIAL SAFETY DMATA REACTIVITY DATA Page 3 of 4 Stability: Stable for at least 5 years under normal conditions of warehouse Q storage. Heated facilities are not required. Incompatibility: Non-corrosive to stainless steel, aluminum, polyethylene, plastic, fiberglass. Corrosive to mild steel, galvanized steel and zinc. This product or spray solutions of this product react with such containers and tanks to produce hydrogen gas which may form a highly combus- tible gas mixture. This gas mixture could flash er explode if ignited by open flame, spark or other ignition sources. Hazardous Decomposition Products: None Hazardous Polymerization: Does not occur. The product can react with ca;.,stic (basic) materials i to liberate heat. This is not polymerization, but rather a chemical neutralization in an acid-base reaction. SPILL, LEAK & DIS POSAL INFORMATION Open dumping is prohibited. This product, spray mixture or rinsate that cannot be used or chemically reprocessed should be dis- posed of in a landfill approved for pesticides. Triple rinse container and offer for recycling, recenditioninc-or disposal-in approved landfill. > Consult federal, state or Iccal-disposal authorities_fcr additional cr-alternative r=ruirerr,ents. i '^ Avoid skin and eye contact—see Occupational Ccntrol Procedures. Soak up small amounts with absorbent days (kitty litter, oil dri, etc.). I I Sweep or scoop up spilled material and dispose of in approved landfill. Wash down surfaces.Lleors, truck beds, streets, etc.) with detergent-and water solution. - v D ADDITIONAL COMMENTS � Environmental Toxicity Information: I 96-hr TL:�O 6luegill: 14 mg/I, slightly toxic 96-hr TL5o Carp: 3.9 ppm, moderately toxic c ...6 - hr TL.. Tr out:.,0 11 mg;I, slightly toxic i o 96-hr LC50 Catfish: 16 mg/l, slightly toxic c 96-hr LC50 Crayfish: > 1000 ppm, practically ncn-toxic 96-hr LC F Min ! 50 Fathead new: 9.4 mg�l, moderately toxic 48-hr LC50 Daphnia: 5.3 mg/I, moderately toxic I 1 Carp contained in a static pond were unaffected at an c exposure to an aerial application of ROUNDUP her-ici'time during the „0-day ceser�atien period by analyses indicated that clyphosate will not bioaccumulate. a the intended use level. Tissue residue Physical or Chemical Hazards: Spray solutions of this product should be mixer', stored and applied only in stainless steel, aluminum, polyethylene, plastic and fiberclass containers. j DO NOT MIX, STORE OR APPLY T HIS PRODUCT OR SPRAY SOLUTFONS OF Ti41S PRODUCT IN GALVANIZED STEEL OR UNLINED STEEL (EXCEPT STAINLESS STEEL) CONTAINERS OR SPRAY TANKS. i